• Title/Summary/Keyword: Gap-filling material

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Measuring thermal conductivity and water suction for variably saturated bentonite

  • Yoon, Seok;Kim, Geon-Young
    • Nuclear Engineering and Technology
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    • v.53 no.3
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    • pp.1041-1048
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    • 2021
  • An engineered barrier system (EBS) for the disposal of high-level radioactive waste (HLW) is composed of a disposal canister with spent fuel, a buffer material, a gap-filling material, and a backfill material. As the buffer is located in the empty space between the disposal canisters and the surrounding rock mass, it prevents the inflow of groundwater and retards the spill of radionuclides from the disposal canister. Due to the fact that the buffer gradually becomes saturated over a long time period, it is especially important to investigate its thermal-hydro-mechanical-chemical (THMC) properties considering variations of saturated condition. Therefore, this paper suggests a new method of measuring thermal conductivity and water suction for single compacted bentonite at various levels of saturation. This paper also highlights a convenient method of saturating compacted bentonite. The proposed method was verified with a previous method by comparing thermal conductivity and water suction with respect to water content. The relative error between the thermal conductivity and water suction values obtained through the proposed method and the previous method was determined as within 5% for compacted bentonite with a given water content.

COMPARISON OF THE SEALING ABILITY OF VARIOUS ROOT CANAL FILLING TECHNIQUES (근관충전방법에 따른 폐쇄효과의 비교)

  • Lee, Dong-Kyoung;Yoon, Soo-Han;Bae, Kwang-Shik
    • Restorative Dentistry and Endodontics
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    • v.23 no.1
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    • pp.346-356
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    • 1998
  • The purpose of this study was to evaluate the sealing ability of various canal filling methods. Palatal roots of ninety extracted human maxillary molar teeth were resected at cementoenamel junction. Eighty of them were randomly assigned to four experimental groups, ten were served as positive and negative controls. All canals were prepared to # 40 using Profile. Experimental groups were obturated by lateral condensation technique, Thermafil technique, Continuous Wave of Condensation Technique, and down-pack & back-fill technique of Obtura-II, each with root canal sealer. Control groups were not obturated. Teeth were immersed in resorcinol-formaldehyde resin for 5 days at $4^{\circ}C$, and the resin was allowed to polymerize completely for 4 days at room temperature. Teeth were then ground horizontally at 1.5mm(level 1), 2.5mm(level 2), 3.5 mm(level 3) from the anatomical apex and examined with a stereomicroscope at ${\times}40$ magnification. The gap between the canal wall and the filling material, which was filled with the resin, was measured at each of the three levels. Each ratio of leakage was obtained by calculating the ratio of the area of the resin to the total area of the canal and was analyzed statistically (Rank-sum test). The results were as follows : 1. At the level 1, there was the greatest leakage in the Thermafil group and Obtura-II group, and the difference between the Obtura-II group and Continuous Wave of Condensation Technique group was statistically significant(p<0.05). 2. At the level 2, there was the least leakage in the Continuous Wave of Condensation Technique group, but there was no statistically significant difference between each group (p>0.05). 3. At the level 3, there was no statistically significant difference between each group(p>0.05).

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Mechanism Study of Flowable Oxide Process for Sur-100nm Shallow Trench Isolation

  • Kim, Dae-Kyoung;Jang, Hae-Gyu;Lee, Hun;In, Ki-Chul;Choi, Doo-Hwan;Chae, Hee-Yeop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.68-68
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    • 2011
  • As feature size is smaller, new technology are needed in semiconductor factory such as gap-fill technology for sub 100nm, development of ALD equipment for Cu barrier/seed, oxide trench etcher technology for 25 nm and beyond, development of high throughput Cu CMP equipment for 30nm and development of poly etcher for 25 nm and so on. We are focus on gap-fill technology for sub-30nm. There are many problems, which are leaning, over-hang, void, micro-pore, delaminate, thickness limitation, squeeze-in, squeeze-out and thinning phenomenon in sub-30 nm gap fill. New gap-fill processes, which are viscous oxide-SOD (spin on dielectric), O3-TEOS, NF3 Based HDP and Flowable oxide have been attempting to overcome these problems. Some groups investigated SOD process. Because gap-fill performance of SOD is best and process parameter is simple. Nevertheless these advantages, SOD processes have some problems. First, material cost is high. Second, density of SOD is too low. Therefore annealing and curing process certainly necessary to get hard density film. On the other hand, film density by Flowable oxide process is higher than film density by SOD process. Therefore, we are focus on Flowable oxide. In this work, dielectric film were deposited by PECVD with TSA(Trisilylamine - N(SiH3)3) and NH3. To get flow-ability, the effect of plasma treatment was investigated as function of O2 plasma power. QMS (quadruple mass spectrometry) and FTIR was used to analysis mechanism. Gap-filling performance and flow ability was confirmed by various patterns.

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Preform Design Technique by Tracing the Material Deformation Behavior (재료의 변형거동 추적을 통한 예비형상 설계)

  • Hong J. T.;Park C. H.;Lee S. R.;Yang D. Y.
    • Transactions of Materials Processing
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    • v.13 no.6 s.70
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    • pp.503-508
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    • 2004
  • Preform design techniques have been investigated to reduce die wear and forming load and to improve material flow, filling ratio, etc. In hot forging processes, a thin deformed part of a workpiece, known as a flash, is formed in the narrow gap between the upper and lower tools. Although designers make tools that generate a flash intentionally in order to improve flow properties, excessive flash increases die wear and forming load. Therefore, it is necessary to make a preform shape that can reduce the excessive flash without changing flow properties. In this paper, a new preform design technique is proposed to reduce the excessive flash in a metal forging process. After a finite element simulation of the process is carried out with an initial billet, the flow of material in the flash region is traced from the final shape to the initial billet. The region belonging to the flash is then easily found in the initial billet. The finite element simulation is then carried out again with the modified billet from which the selected region has been removed. In several iterations of this technique, the optimal preform shape that minimizes the amount of flash without changing the forgeability can be obtained.

Thermal conductivity prediction model for compacted bentonites considering temperature variations

  • Yoon, Seok;Kim, Min-Jun;Park, Seunghun;Kim, Geon-Young
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3359-3366
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    • 2021
  • An engineered barrier system (EBS) for the deep geological disposal of high-level radioactive waste (HLW) is composed of a disposal canister, buffer material, gap-filling material, and backfill material. As the buffer fills the empty space between the disposal canisters and the near-field rock mass, heat energy from the canisters is released to the surrounding buffer material. It is vital that this heat energy is rapidly dissipated to the near-field rock mass, and thus the thermal conductivity of the buffer is a key parameter to consider when evaluating the safety of the overall disposal system. Therefore, to take into consideration the sizeable amount of heat being released from such canisters, this study investigated the thermal conductivity of Korean compacted bentonites and its variation within a temperature range of 25 ℃ to 80-90 ℃. As a result, thermal conductivity increased by 5-20% as the temperature increased. Furthermore, temperature had a greater effect under higher degrees of saturation and a lower impact under higher dry densities. This study also conducted a regression analysis with 147 sets of data to estimate the thermal conductivity of the compacted bentonite considering the initial dry density, water content, and variations in temperature. Furthermore, the Kriging method was adopted to establish an uncertainty metamodel of thermal conductivity to verify the regression model. The R2 value of the regression model was 0.925, and the regression model and metamodel showed similar results.

Thermal Management on 3D Stacked IC (3차원 적층 반도체에서의 열관리)

  • Kim, Sungdong
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.2
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    • pp.5-9
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    • 2015
  • Thermal management becomes serious in 3D stacked IC because of higher heat flux, increased power generation, extreme hot spot, etc. In this paper, we reviewed the recent developments of thermal management for 3D stacked IC which is a promising candidate to keep Moore's law continue. According to experimental and numerical simulation results, Cu TSV affected heat dissipation in a thin chip due to its high thermal conductivity and could be used as an efficient heat dissipation path. Other parameters like bumps, gap filling material also had effects on heat transfer between stacked ICs. Thermal aware circuit design was briefly discussed as well.

Influence of defective sites in Pt/C catalysts on the anode of direct methanol fuel cell and their role in CO poisoning: a first-principles study

  • Kwon, Soonchul;Lee, Seung Geol
    • Carbon letters
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    • v.16 no.3
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    • pp.198-202
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    • 2015
  • Carbon-supported Pt catalyst systems containing defect adsorption sites on the anode of direct methanol fuel cells were investigated, to elucidate the mechanisms of H2 dissociation and carbon monoxide (CO) poisoning. Density functional theory calculations were carried out to determine the effect of defect sites located neighboring to or distant from the Pt catalyst on H2 and CO adsorption properties, based on electronic properties such as adsorption energy and electronic band gap. Interestingly, the presence of neighboring defect sites led to a reduction of H2 dissociation and CO poisoning due to atomic Pt filling the defect sites. At distant sites, H2 dissociation was active on Pt, but CO filled the defect sites to form carbon π-π bonds, thus enhancing the oxidation of the carbon surface. It should be noted that defect sites can cause CO poisoning, thereby deactivating the anode gradually.

Numerical Analysis of One Drop Filling Process with Photo-definable Spacer

  • Lee, Woo-Shik;Yoo, Gi-Chun;Jeon, Baek-Kyun;Kim, Choong-Sik;Kim, Ki-Taek
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.500-503
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    • 2002
  • In this paper, we demonstrate the deformation of TFT-LCD panel using numerical analysis based on the finite element method. To make better uniform cell gap and less stress at a photo-definable spacer (spacer), we have investigated process and design factors such as amount of liquid crystal (LC), spacer density, area, height, and material property. Furthermore we optimized design factors and achieved the robust design through the simulation.

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Performance Evaluation of a New Buried Expansion Joint (새로운 매설형 신축이음장치의 성능 평가)

  • Hong, Seong-Hyeop;Park, Sang-Yeol;Jwa, Yong-Hyun
    • International Journal of Highway Engineering
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    • v.12 no.3
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    • pp.27-35
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    • 2010
  • Asphalt Plug Joint(APJ) is an buried expansion joint that enabling the smooth connection of expansion gap and road pavement by filling the gap with bituminous mixture of 20% bitumen and 80% aggregate by weight, so it secures evenness and expansion or contraction using the material's properties. Although APJ is designed to have a 6-7 year lifecycle, there are some cases where it is damaged within the first six months. This early damage cause traffic congestion due to frequent repair works, and social cost exceeding the installation cost of the joint. So, in this research, we have developed a new system of Buried Folding Lattice Joint(BFLJ) which can overcome the disadvantages of APJ, and have analyzed and compared it's performance with the conventional APJ through experiment with specimens. As a result of the experiment, APJ had crack formation on both ends of the gap plate, spreading to the surface of the expansion joint. With this result, we can conclude that the reason for early damage is the tension failure due to the concentration of strain in the asphalt mixture along the end of gap plate and the debonding along the joint section. In contrast, the newly developed BFLJ induced even transformation in the joint by applying moving stud and high performance material, and resolved APJ's disadvantage of strain concentration. Therefore, it could be seen that the newly developed BFLJ could overcome the disadvantages of APJ and prevent early damage.

Influence of frequency and duty ratio on electro-optical characteristics in AC-PDP (AC-PDP에서의 주파수 및 duty비의 영향에 따른 전기광학적 특성)

  • Kim, T.Y.;Cho, T.S.;Ahn, J.C.;Choi, M.C.;Jeoung, J.M.;Leem, J.Y.;Jeoung, Y.H.;Kim, S.S.;Chong, M.W.;Choi, S.H.;Kim, S.B.;Ko, J.J.;Cho, K.S.;Choi, E.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04a
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    • pp.139-142
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    • 2000
  • Influence of frequency and duty ratio on electro-optical characteristics are experimentally investigated in surface AC plasma display panels(AC-PDPs) by using the VDS(Versitile Driving Simulator)., in which electrode gap and width are 100 ${\mu}m$ and 260 ${\mu}m$, respectively. The filling gas is Ne-Xe gas mixture, and total pressure 400 Torr. It is found that the response time gets to be fast from 450 ns to 150 ns as pulse-off time of the sustain pulse decreases from 2 ${\mu}s$ to 0.2 ${\mu}s$. Also it is found that the IR(Infra Red) intensity and the luminous decreases as pulse-off time of the sustain pulse increases from 0.2 ${\mu}s$ to 2 ${\mu}s$.

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