• Title/Summary/Keyword: Galvanic effect

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Corrosion behavior of Mg-(0~6)%Zn Casting Alloys in 1M NaCl Solution (1M NaCl 용액에서 Mg-(0~6)%Zn 주조 합금의 부식 거동)

  • Hwang, In-Je;Kim, Young-Jig;Jun, Joong-Hwan
    • Journal of Korea Foundry Society
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    • v.36 no.4
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    • pp.117-125
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    • 2016
  • The effects of the Zn content on the microstructure and corrosion behavior in 1M NaCl solution were investigated in Mg-(0~6)%Zn casting alloys. The MgZn phase was scarcely observed in the Mg-1%Zn alloy, while the Mg-(2~6)%Zn alloy consisted of ${\alpha}$-(Mg) and MgZn phases. With an increase in the Zn content, the amount of the MgZn phase was gradually increased. Immersion and electrochemical corrosion tests indicated that the Mg-1%Zn alloy had the lowest corrosion rate among the alloys, and a further increase in the Zn content resulted in the deterioration of the corrosion resistance. Microstructural examinations of the corroded surfaces and EIS analyses of surface corrosion films revealed that the best corrosion resistance at 1%Zn was associated with the absence of MgZn phase particles in the microstructure and the contribution of Zn element to the formation of a protective film on the surface. A micro-galvanic effect by the MgZn particles led to the increased rate of corrosion at a higher Zn content.

Development of a Novel 30 kV Solid-state Switch for Damped Oscillating Voltage Testing System

  • Hou, Zhe;Li, Hongjie;Li, Jing;Ji, Shengchang;Huang, Chenxi
    • Journal of Power Electronics
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    • v.16 no.2
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    • pp.786-797
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    • 2016
  • This paper describes the design and development of a novel semiconductor-based solid-state switch for damped oscillating voltage test system. The proposed switch is configured as two identical series-connected switch stacks, each of which comprising 10 series-connected IGBT function units. Each unit consists of one IGBT, a gate driver, and an auxiliary voltage sharing circuit. A single switch stack can block 20 kV-rated high voltage, and two stacks in series are proven applicable to 30 kV-rated high voltage. The turn-on speed of the switch is approximately 250 ns. A flyback topology-based power supply system with a front-end power factor correction is built for the drive circuit by loosely inductively coupling each unit with a ferrite core to the primary side of a power generator to obtain the advantages of galvanic isolation and compact size. After the simulation, measurement, and estimation of the parasitic effect on the gate driver, a prototype is assembled and tested under different operating regimes. Experimental results are presented to demonstrate the performance of the developed prototype.

Corrosion Fatigue Characteristics of SUS316L Steel with Ti Undercoat using Plasma Spray Method (플라즈마 스프레이방법을 이용하여 Ti 언더코트를 제작한 SUS316L강의 부식피로 특성)

  • Han, Chang-Suk;Kim, Woo-Suk
    • Korean Journal of Materials Research
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    • v.31 no.3
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    • pp.172-180
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    • 2021
  • In this study, using the plasma spray method, tensile and compression fatigue tests are performed in saline solution to examine the effect of Ti undercoat on corrosion fatigue behavior of alumina-coated specimens. The alumina-coated material using Ti in the undercoat shows better corrosion fatigue strength than the base material in the entire stress amplitude range. Fatigue cracking of UT specimens occurs in the recess formed by grit-blasting treatment and progresses toward the base metal. Subsequently, the undercoat is destroyed at a stage where the deformation of the undercoat cannot follow the crack opening displacement. The residual stress of the UT specimen has a tensile residual stress up to about 100 ㎛ below the surface of the base material; however, when the depth exceeds 100 ㎛, the residual stress becomes a compressive residual stress. In addition, the inside of the spray coating film is compressive residual stress, which contributes to improving the fatigue strength characteristics. A hardened layer due to grit-blasting treatment is formed near the surface of the UT specimen, contributing to the improvement of the fatigue strength characteristics. Since the natural potential of Ti spray coating film is slightly higher than that of the base material, it exhibits excellent corrosion resistance; however, when physiological saline intrudes, a galvanic battery is formed and the base material corrodes preferentially.

Electrochemical and Cavitation-Erosion Characteristics of Duplex Stainless Steels in Seawater Environment (해수 환경에서 듀플렉스 스테인리스강의 전기화학적 거동 및 캐비테이션 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.466-474
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    • 2021
  • A wet type scrubber for merchant vessel uses super austenitic stainless steels with pitting resistance equivalent number (PREN) of 40 or higher for operation in a harsh corrosive environment. However, it is expensive due to a high nickel content. Thus, electrochemical behavior and cavitation erosion characteristics of UNS S32750 as an alternative material were investigated. Microstructure analysis revealed fractions of ferritic and austenitic phases of 48% and 52%, respectively, confirming the existence of ferritic matrix and austenitic island. Potentiodynamic polarization test revealed damage at the interface of the two phases because of galvanic corrosion due to different chemical compositions of ferritic and austenitic phases. After a cavitation test, a compressive residual stress was formed on the material surface due to impact pressure of cavity. Surface hardness was improved by water cavitation peening effect. Hardness value was the highest at 30 ㎛ amplitude. Scanning electron microscopy revealed wave patterns due to plastic deformation caused by impact pressure of the cavity. The depth of surface damage increased with amplitude. Cavitation test revealed larger damage caused by erosion in the ferritic phase due to brittle fracture derived from different strain rate sensitivity index of FCC and BCC structures.

Effect of Welding Thermal Cycle on Microstructure and Pitting Corrosion Property of Multi-pass Weldment of Super-duplex Stainless Steel (슈퍼 듀플렉스 스테인리스강 다층용접부의 미세조직 및 공식(Pitting Corrosion)에 미치는 용접열사이클의 영향)

  • Nam, Seong-Kil;Park, Se-Jin;Na, Hye-Sung;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.28 no.4
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    • pp.18-25
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    • 2010
  • Super-duplex stainless steels (SDSS) have a good balance of mechanical property and corrosion resistance when they consist of approximately equal amount of austenite and ferrite. The SDSS needs to avoid the detrimental phases such as sigma(${\sigma}$), chi(${\chi}$), secondary austenite(${\gamma}2$), chromium carbide & nitride and to maintain the ratio of ferrite & austenite phase as well known. However, the effects of the subsequent weld thermal cycle were seldom experimentally studied on the micro-structural variation of weldment & pitting corrosion property. Therefore, the present study investigated the effect of the subsequent thermal cycle on the change of weld microstructure and pitting corrosion property at $40^{\circ}C$. The thermal history of root side was measured experimentally and the change of microstructure of weld root & the weight loss by pitting corrosion test were observed as a function of the thermal cycle of each weld layer. The ferrite contents of root weld were reduced with the subsequent weld thermal cycles. The pitting corrosion was occurred in the weld root region in case of the all pitted specimen & in the middle weld layer in some cases. And the weight loss by pitting corrosion was increased in proportional to the time exposed at high temperature of the root weld and also by the decrease of ferrite content. The subsequent weld thermal cycles destroy the phase balance of ferrite & austenite at the root weld. Conclusively, It is thought that as the more subsequent welds were added, the more the phase balance of ferrite & austenite was deviated from equality, therefore the pitting corrosion property was deteriorated by galvanic effect of the two phases and the increase of 2nd phases & grain boundary energy.

Effect of Driver's Cognitive Distraction on Driver's Physiological State and Driving Performance

  • Kim, Jun-Hoe;Lee, Woon-Sung
    • Journal of the Ergonomics Society of Korea
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    • v.31 no.2
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    • pp.371-377
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    • 2012
  • Objective: The aim of this study is to investigate effect of driver's cognitive distraction on driver's physiological state and driving performance, and then to determine parameters appropriate for detecting the cognitive distraction. Background: Driver distraction is a major cause of traffic accidents and poses a serious threat to traffic safety due to ever increasing use of in-vehicle information systems and mobile phones during driving. Cognitive distraction, among four different types of distractions, prevents a driver from processing traffic information correctly and adapting to change in surround vehicle behavior in time. However, the cognitive distraction is more difficult to detect because it normally does not involve significant change in driver behavior. Method: A full-scale driving simulator was used to create virtual driving environment and situations. Participants in the experiment drove the driving simulator in three different conditions: attentive driving with no secondary task, driving and conducting secondary task of adding numbers, and driving and conducting secondary task of conversing with an experimenter. Parameters related with driver's physiological state and driving performance were measured and analyzed for their change. Results: The experiment results show that driver's cognitive distraction, induced by secondary task of addition and conversation during driving, increased driver's cognitive workload, and indeed brought change in driver's physiological state and degraded driving performance. Conclusion: The galvanic skin response, pupil size, steering reversal rate, and driver reaction time are shown to be statistically significant for detecting cognitive distraction. The appropriate combination of these parameters will be used to detect the cognitive distraction and estimate risk of traffic accidents in real-time for a driver distraction warning system.

The Effect of Balance Control and Vestibular Function by an Aquatic Rotation Control and the Obstacle Avoidance Underwater with Hemiplegia Patients (수중에서 회전조절과 장애물 훈련이 편마비 환자의 전정기능과 균형조절에 미치는 영향)

  • Kwon, Hye-Min;Kim, Su-Hyun;Kim, Hyun-Jin;Oh, Seok;Choi, Ji-Ho;Kim, Tae-Youl
    • Journal of the Korean Academy of Clinical Electrophysiology
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    • v.8 no.1
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    • pp.43-50
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    • 2010
  • Purpose : The objective of this study is to effect of an aquatic rotation control and obstacle avoidance when conducted underwater on hemiplegia patient's balance ability and vestibular function. Methods : Twelve hemiplegia patients participated and were randomly assigned to a control group(I) with standard physical therapy and an aquatic group(II) with an aquatic rotation control, obstacle avoidance and standard physical therapy as well. The aquatic group trained using a Halliwick rotation control and obstacle avoidance through 3 times per week over 6 weeks. For all subjects, vestibular function, their balance, the change of electrooculogram (EOG), the change of accelerometer axis and torsiometer according to visual sense, vestibular sense with galvanic vestibular stimulation (GVS) or not during leg close stance were measured. Results : The EOG in the vertical and horizontal (p<0.05) were both significantly lowered. The change was significantly lower in the trajectory range of motion of trunk and spine with torsiometer when leg close stand (p<0.01) and leg close stand with GVS (p<0.01). The centre of gravity accelerated, there were reduced significantly difference X and Y axis of accelerometer during the closing of the leg without vision (p<0.05). There were reduced significantly difference X and Z axis of accelerometer during the closing of the leg with GVS (p<0.05). There were reduced significantly difference X and Z axis of accelerometer during the closing of the leg and close eyes with GVS (p<0.05). Conclusion : The balance ability, vestibular system and postural control is improved.

A Study on the Effect of Metallic Fillers and Plastic for Ionic Migration (이온마이그레이션에 대한 플라스틱과 금속첨가제의 영향 연구)

  • Jeon, Sang Soo;Kim, Ji Jung;Lee, Ho Seung
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.2
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    • pp.30-34
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    • 2021
  • Electrical failures and reliability problems of electronic components by ionic migration between adjacent device terminals have become an issue in automotive electronics. Especially unlike galvanic corrosion, ionic migration is occurred at high temperature and high humidity under applied electric field condition. Until now, although extensive studies of the ionic migrations dealing with PCBs, electrodes, and solders were reported, there is no study on the effect of insulation polymers and metallic fillers for ionic migration. In this research, therefore, ionic migration induced by the types and contents of polymers and metallic fillers, and variety conditions of temperature, humidity, and applied voltage was studied in detail. Ester and amide types of liquid crystal polymer (LCP) and poly (phthalamide) (PPA) were used as base polymers, respectively and compounded with the metallic fillers of Copper iodide (CuI), Zinc stearate (Zn-st), or Calcium stearate (Ca-st) in various compositions. The compounding polymers were fabricated in IPC-B-24 of SIR test coupon according to ISO 9455-17 with Cu electrodes for ionic migration test. While there is no change in LCP-based samples, ionic migration in PPA compounding sample with a high water absorption property was accelerated in the presence of 0.25 wt% or above of CuI at the environmental conditions of 85℃, 85% RH and 48V. The dendritic short-circuit growth of Cu caused by ionic migration between the electrodes on the surface of compounded polymers was systematically observed and analyzed by using optical microscopy and SEM (EDX).

Energy harvesting techniques for remote corrosion monitoring systems

  • Kim, Sehwan;Na, Ungjin
    • Smart Structures and Systems
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    • v.11 no.5
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    • pp.555-567
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    • 2013
  • An Remote Corrosion Monitoring (RCM) system consists of an anode with low potential, the metallic structures against corrosion, an electrode to provide reference potential, and a data-acquisition system to ensure the potential difference for anticorrosion. In more detail, the data-acquisition (DAQ) system monitors the potential difference between the metallic structures and a reference electrode to identify the correct potential level against the corrosion of the infrastructures. Then, the measured data are transmitted to a central office to remotely keep track of the status of the corrosion monitoring (CM) system. To date, the RCM system is designed to achieve low power consumption, so that it can be simply powered by batteries. However, due to memory effect and the limited number of recharge cycles, it can entail the maintenance fee or sometimes cause failure to protect the metallic structures. To address this issue, the low-overhead energy harvesting circuitry for the RCM systems has designed to replenish energy storage elements (ESEs) along with redeeming the leakage of supercapacitors. Our developed energy harvester can scavenge the ambient energy from the corrosion monitoring environments and store it as useful electrical energy for powering local data-acquisition systems. In particular, this paper considers the energy harvesting from potential difference due to galvanic corrosion between a metallic infrastructure and a permanent copper/copper sulfate reference electrode. In addition, supercapacitors are adopted as an ESE to compensate for or overcome the limitations of batteries. Experimental results show that our proposed harvesting schemes significantly reduce the overhead of the charging circuitry, which enable fully charging up to a 350-F supercapacitor under the low corrosion power of 3 mW (i.e., 1 V/3 mA).

Effect of Alloying Elements (Cu, Al, Si) on the Electrochemical Corrosion Behaviors of TWIP Steel in a 3.5 % NaCl Solution (3.5% NaCl 수용액 내 TWIP강의 부식거동에 미치는 합금원소 (Cu, Al, Si)의 영향)

  • Kim, Si-On;Hwang, Joong-Ki;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.18 no.6
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    • pp.300-311
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    • 2019
  • The corrosion behaviors of twinning-induced plasticity (TWIP) steels with different alloying elements (Cu, Al, Si) in a neutral aqueous environment were investigated in terms of the characteristics of the corrosion products formed on the steel surface. The corrosion behavior was evaluated by measuring potentiodynamic polarization test and electrochemical impedance spectroscopy. For compositional analysis of the corrosion products formed on the steel surface, an electron probe x-ray micro analyzer was also utilized. This study showed that the addition of Cu to the steel contributed to the increase in corrosion resistance to a certain extent by the presence of metallic Cu in discontinuous form at the oxide/steel interface. Compared to the case of steel with Cu, the Al-bearing specimen exhibited much higher polarization resistance and lower corrosion current by the formation of a thin Al-enriched oxide layer. On the other hand, Si addition (3.0 wt%) to the steel led to an increase in grain size, which was twice as large as that of the other specimens, resulting in a deterioration of the corrosion resistance. This was closely associated with the localized corrosion attacks along the grain boundaries by the formation of a galvanic couple with a large cathode-small anode.