• Title/Summary/Keyword: GacS

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Kinetic Studies on Physical and Chemical Activation of Phenolic Resin Chars

  • Agarwal, Damyanti;Lal, Darshan;Tripathi, V.S.;Mathur, G.N.
    • Carbon letters
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    • v.4 no.3
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    • pp.126-132
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    • 2003
  • Granular Activated Carbon (GAC) has been proven to be an excellent material for many industrial applications. A systematic study has been carried out of the kinetics of physical as well as chemical activation of phenolic resin chars. Physical activation was carried out using $CO_2$ and chemical activation using KOH as activating agent. There are number of factors which influence the rate of activation. The activation temperature and residence time at HTT varied in the range $550{\sim}1000^{\circ}C$ and $\frac{1}{2}{\sim}8$ hrs respectively. Kinetic studies show that the rate of chemical activation is 10 times faster than physical activation even at much lower temperature. Above study show that the chemical activation process is suitable to prepare granular activated carbon with very high surface area i.e.$ 2895\;m^2/g$ in short duration of time i.e. 1 to 2 hrs at lower temperature i.e. $750^{\circ}C$ from phenolic resins.

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Conserved Virulence Factors of Pseudomonas aeruginosa are Required for Killing Bacillus subtilis

  • Park Shin-Young;Heo Yun-Jeong;Choi Young-Seok;Deziel Eric;Cho You-Hee
    • Journal of Microbiology
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    • v.43 no.5
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    • pp.443-450
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    • 2005
  • The multi-host pathogen, Pseudomonas aeruginosa, possesses an extraordinary versatility which makes it capable of surviving the adverse conditions provided by environmental, host, and, presumably, competing microbial factors in its natural habitats. Here, we investigated the P. aeruginosa-Bacillus subtilis interaction in laboratory conditions and found that some P. aeruginosa strains can outcompete B. subtilis in mixed planktonic cultures. This is accompanied by the loss of B. subtilis viability. The bactericidal activity of P. aeruginosa is measured on B. subtilis plate cultures. The bactericidal activity is attenuated in pqsA, mvfR, lasR, pilB, gacA, dsbA, rpoS, and phnAB mutants. These results suggest that P. aeruginosa utilizes a subset of conserved virulence pathways in order to survive the conditions provided by its bacterial neighbors.

Identification of Nocardia seriolae by polymerase chain reaction (PCR에 의한 Nocardia seriolae의 검출)

  • Park, Myoung-Ae;Cho, Mi-Young;Kim, Myoung-Sug;Kim, Jae-Hoon;Lee, Deok-Chan
    • Journal of fish pathology
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    • v.22 no.1
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    • pp.85-90
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    • 2009
  • A method for the identification of Nocardia seriolae, the causative agent of nocardiosis in cultured fishes, using PCR was developed in the study. A PCR primer set specific to N. seriolae was designed based on 16S-23S rRNA sequence of various Nocardia species accessed in GenBank. Designed PCR primer set, Nseri-F (5'-GCA AAC TCT TCG AAC AGT CG-3') and Nseri-R (5'-GGA TAT CAG GAC TTA CCG GC-3'), amplifies the target regions of N. seriolae only, but not 4 other Nocardia species, N. asteroides, N. crassostreae, N. farcinica and N. salmonicida.

Applicability Evaluation of Two-stages and Dual Media Filtration System by the Small-scale Pilot Plant (이단이층 복합여과시스템의 소규모 파일롯 플랜트 적용성 평가)

  • Woo, Dal-Sik;Song, Si-Byum;Hwang, Byung-Gi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.4
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    • pp.857-864
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    • 2009
  • This study aimed at developing the two stage and dual filtration system. It has a sand + activated carbon layer above the underdrain system and a sand layer above the middledrain system for pretreatment. When retrofitting an old filter bed or designing a new one, this technology can substitute the existing sand filter bed without requiring a new site. In order to extend the filtering duration, the upper layer of the filter bed consists of the rapid sand filtration with large particles which pre-treats and removes coarse particles and turbidity matters. The middle layer has biological activated carbon(BAC) and granular activated carbon(GAC) to eliminate dissolved organic matters, disinfection by-products precursors etc. The lower layer consists of the sand filtration for the post filtering mode. In this study, a pilot plant of two stage and dual filtration system was operated for 4 months in the S water treatment plant in Kyounggi-Do. The stability of turbidity was maintained below 1NTU. The TOC, THMFP and HAAFP were removed about 90% by two stage and dual filtration system, which is almost 2 times higher than S WTP. From analysis result of HPC along the depth of activated carbon + sand layer at 2nd stage, microorganism was mostly not detected, however, increment of HPC was shown as it becomes deeper. It indicates that growth of microorganism is occurred at activated carbon layer.

A study on the BAC pilot plant in the Duk-san water works (덕산(德山) 정수장(淨水場)에서의 BAC Pilot plant에 관한 연구(硏究))

  • Lee, Sang-Bong;Kim, Dong-Youn;Lim, Jung-A;Lee, Won-Gwon
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.2
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    • pp.97-107
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    • 1995
  • Today a conventional water treatment system has many problems. The ozone/GAC process, sometimes termed Biological Activated Carbon(BAC), appeared to be effective for the removal of soluble organic matters in the drinking water. The water quality of Nak-dong river in Pusan, generally shows BDOC 30-40% and NBDOC 60-70%. The pilot plant installed at the Duk-san water works that was been largest treatability(1,650,000ton/day) in Pusan. A experimental water in the pilot plant made use of the water after sand-filteration. Following results are drawn from this study. Initial adsorption velocity($DOC/DOC_o/T$) in the pure adsorption of GAG had a 0.0225, it's velocity changed to 0.006 after ozone added and the optimum ozone dose ranged of $1.4-2.0mgO_3/L$. A experimental water in the pilot plant composed with humic material(78%). Humic material composed with humic acid(20%) and fulvic acid(56%), and it's rate changed to 18 and 50% respectively after ozone added. DOC constantly decreased in the EBCTs and removal efficieny in the 15min of EBCT was 45-50%. It showed the largest removal rate of BDOC in the EBCT 5 and among the season, characteristics of removal varied. The HPC distributed over $10^6-10^7CFU/cm^3$ in the bed depth and among the season, distribution of HPC were differential.

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Utilization of biofilter/photo-catalytic reactor system for the simultaneous treatment of hydrogen sulfide and toluene from waste-air

  • Lim, Kwang-Hee;Ping, Wang Zhi;Lim, Dong-Joon;Lee, Eun-Ju
    • 한국생물공학회:학술대회논문집
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    • 2005.04a
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    • pp.287-292
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    • 2005
  • Transient behavior of biofilter/photo-catalytic reactor system was observed to eliminate both hydrogen sulfide and toluene from waste air at its four sampling ports. The biofilter was packed with a equivolume mixture of granular activated carbon(GAC) and compost as packing media on which Thiobacillus sp. IW and Burkholderia cepacia G4 were inoculated and were fixed. The biofilter/photo-catalytic reactor system was run for eight stages of operation under various operating conditions. As a result the removal efficiencies of hydrogen sulfide and toluene began to decrease from 100% after the inlet loads of hydrogen sulfide and toluene surpassed ca. 100 $S-g/m^{3}/h$ and $161g/m^{3}/h$, respectively, and were rapidly decreased to 60% after the inlet loads of hydrogen sulfide and toluene were increased to 200 $S-g/m^{3}/h$ and $644g/m^{3}/h$, respectively.

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High Power Factor and High Efficiency DC-DC Converter using Single-Pulse Soft-Switching (단일 펄스 소프트 스위칭을 이용한 고역률 고효율 DC-DC 컨버터)

  • Jung, S.H.;Kwon, S.K.;Suh, K.Y.;Lee, H.W.;Gac, D.K.;Kim, Y.C.
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.1148-1150
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    • 2003
  • Power conversion system must be increased switching frequency in order to achieve a small size, a light weight and a low noise. However, the switches of converter are subjected to high switching power losses and switching stresses. As a result of those, the power system brings on a low efficiency. To improved these, a large number of soft switching topologies included a resonant circuit has been prosed. But these circuits increase number of switch in circuit and complicate sequence of switching operation. In this paper, the authors propose a high power factor and high efficiency DC-DC converter using single-pulse soft switching by partial resonant switching node. The switching devices in a prosed circuit are operated with soft switching by the partial resonant method, that is, Partial Resonant Switch Mode Power Converter. The partial resonant circuit makes use of a inductor using step up and a condenser of loss-less snubber. The result is that the switching loss is very low and the efficiency of system is high. Also the proposed converter is deemed the most suitable for high power applications where the power switching devices are used. Some simulative results on computer results are included to confirm the validity of the analytical results.

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Characteristics of Equilibrium, Kinetics and Thermodynamics for Adsorption of Disperse Yellow 3 Dye by Activated Carbon (활성탄에 의한 Disperse Yellow 3 염료의 흡착에 있어서 평형, 동력학 및 열역학적 특성)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.27 no.2
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    • pp.182-189
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    • 2021
  • The adsorption of disperse yellow 3 (DY 3) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetic and thermodynamic parameters by experimenting with initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH change experiment, the adsorption percent of DY 3 on activated carbon was highest in the acidic region, pH 3 due to electrostatic attraction between the surface of the activated carbon with positive charge and the anion (OH-) of DY 3. The adsorption equilibrium data of DY 3 fit the Langmuir isothermal adsorption equation best, and it was found that activated carbon can effectively remove DY 3 from the calculated separation factor (RL). The heat of adsorption-related constant (B) from the Temkin equation did not exceed 20 J mol-1, indicating that it is a physical adsorption process. The pseudo second order kinetic model fits well within 10.72% of the error percent in the kinetic experiments. The plots for Weber and Morris intraparticle diffusion model were divided into two straight lines. The intraparticle diffusion rate was slow because the slope of the stage 2 (intraparticle diffusion) was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was rate controlling step. The free energy change of the DY 3 adsorption by activated carbon showed negative values at 298 ~ 318 K. As the temperature increased, the spontaneity increased. The enthalpy change of the adsorption reaction of DY 3 by activated carbon was 0.65 kJ mol-1, which was an endothermic reaction, and the entropy change was 2.14 J mol-1 K-1.

Adsorption Characteristics and Thermodynamic Parameters of Acid Fuchsin on Granular Activated Carbon (입상 활성탄에 대한 Acid Fuchsin의 흡착특성과 열역학 파라미터)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.27 no.1
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    • pp.47-54
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    • 2021
  • The adsorption of Acid Fuchsin (AF) on granular activated carbon (GAC) was investigated for isothermal adsorption and kinetics and thermodynamic parameters by experimenting with the initial concentration, contact time, temperature, and pH of the dye as adsorption parameters. In the pH effect experiment, the adsorption of AF on activated carbon showed a bathtub type with increased adsorption at pH 3 and 11. The adsorption equilibrium data of AF fit well with the Freundlich isotherm model, and the calculated separation factor (1/n) value was found in which activated carbon can effectively remove AF. The pseudo-second-order kinetic model fits well within 7.88% of the error percent in the adsorption process. According to Weber and Morris's model plot, it was divided into two straight lines. The intraparticle diffusion rate was slow because the stage 2 (intraparticle diffusion) slope was smaller than that of stage 1 (boundary layer diffusion). Therefore, it was confirmed that the intraparticle diffusion was a rate-controlling step. The activation energy of AF (13.00 kJ mol-1) corresponded to the physical adsorption process (5 - 40 kJ mol-1). The free energy change of the AF adsorption by activated carbon showed negative values at 298-318 K. As the spontaneity increased with increasing temperature. The adsorption of AF was an endothermic reaction (ΔH = 22.65 kJ mol-1).