• 제목/요약/키워드: GPC

검색결과 478건 처리시간 0.034초

현장 중합을 이용한 PLA(Poly L-Lactide) 수지 기반 섬유 강화 복합 재료 제조 및 GPC를 이용한 분자량 측정 (Manufacturing Fiber-Reinforced Composite Materials Based on PLA (Poly L-Lactide) Resin Using In-Situ Polymerization and Molecular Weight Measurement Using GPC)

  • 김선주;이범주;유형민
    • Design & Manufacturing
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    • 제17권3호
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    • pp.28-33
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    • 2023
  • The conventional FRP (Fiber Reinforced Plastic) manufacturing process used thermoset resins for ease of molding but faced the issue of non-recyclability. To address these shortcomings, a new process utilizing thermal plastic resin was developed. However, due to the high viscosity of thermal plastic resin, problems such as fiber deformation and a reduced fiber volume fraction occurred during the high-temperature, high-pressure process. In this study, to overcome the limitations of the conventional process, fiber-reinforced composite materials were manufactured through in-situ polymerization using PLA (Poly L-Lactide) resin in the VA-RTM (Vacuum Assistance Resin Transfer Molding) process. The fiber volume of the produced specimens was calculated, and resin impregnation and porosity were confirmed through optical microscopy. Additionally, molecular weight analysis using GPC (Gel Permission Chromatography) demonstrated improvements over the conventional process and emphasized the essential requirement of temperature control.

Roles of Combined Glypican-3 and Glutamine Synthetase in Differential Diagnosis of Hepatocellular Lesions

  • Wasfy, Rania Elsayed;Eldeen, Aliaa Atef Shams
    • Asian Pacific Journal of Cancer Prevention
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    • 제16권11호
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    • pp.4769-4775
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    • 2015
  • Background: Hepatocellular carcinoma (HCC) is the fifth most prevalent cancer and thirdly leading cause of cancer-related death worldwide. The estimated risk of hepatocellular carcinoma is 15 to 20 times as high among persons infected with HCV as it is among those who are not infected, with most of the excess risk limited to those with advanced hepatic fibrosis or cirrhosis. Glypican3 (GPC3) plays a key role in relation to signaling with growth factors, regulating the proliferative activity of cancer cells. Glutamine synthetase (GS) catalyzes the synthesis of glutamine from glutamate and ammonia in the mammalian liver. GS was suggested as a specific marker for tracing cell lineage relationships during hepatocarcinogenesis. In normal liver, GS expression is seen in pericentral hepatocytes, but not by midzonal or periportal hepatocytes. In HCC, strong and diffuse GS expression in seen in tumor cells. Results: Glypican3 immunopositvity was highly specific and sensitive indicator for hepatocellular carcinoma as well as glutamine synthetase which was found to be a sensitive and specific indicator for development of hepatocellular carcinoma when compared to cirrhosis, liver cell dyspalsia and metastatic carcinomas. Statistical analysis revealed a significant association between GPC3 and GS with tumor size (P=0.003, p=0.006, respectively). Diffuse staining significantly associated with large tumor size while, focal and mixed staining was detected more with small tumor size. Studying the relation with tumor grade also revealed significant association between diffuse GPC3 and GS staining with high tumor grade. Diffuse staining was detected in 91.7% and 100% respectively of poorly differentiated specimens and only in 33.3% and 22.2% of well differentiated specimens. Conclusions: While using GPC3 and GS to screen for premalignant hepatic lesions remains controversial, our data suggest that GPC3 and GS may be a reliable diagnostic immunomarkers to distinguish HCC from benign hepatocellular lesions. However, negative immunostaining should not exclude the diagnosis of HCC.

Performance of FRP confined and unconfined geopolymer concrete exposed to sulfate attacks

  • Alzeebaree, Radhwan;Gulsan, Mehmet Eren;Nis, Anil;Mohammedameen, Alaa;Cevik, Abdulkadir
    • Steel and Composite Structures
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    • 제29권2호
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    • pp.201-218
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    • 2018
  • In this study, the effects of magnesium sulfate on the mechanical performance and the durability of confined and unconfined geopolymer concrete (GPC) specimens were investigated. The carbon and basalt fiber reinforced polymer (FRP) fabrics with 1-layer and 3-layers were used to evaluate the performances of the specimens under static and cyclic loading in the ambient and magnesium sulfate environments. In addition, the use of FRP materials as a rehabilitation technique was also studied. For the geopolymerization process of GPC specimens, the alkaline activator has selected a mixture of sodium silicate solution ($Na_2SiO_3$) and sodium hydroxide solution (NaOH) with a ratio ($Na_2SiO_3/NaOH$) of 2.5. In addition to GPC specimens, an ordinary concrete (NC) specimens were also produced as a reference specimens and some of the GPC and NC specimens were immersed in 5% magnesium sulfate solutions. The mechanical performance and the durability of the specimens were evaluated by visual appearance, weight change, static and cyclic loading, and failure modes of the specimens under magnesium sulfate and ambient environments. In addition, the microscopic changes of the specimens due to sulfate attack were also assessed by scanning electron microscopy (SEM) to understand the macroscale behavior of the specimens. Results indicated that geopolymer specimens produced with nano-silica and fly ash showed superior performance than the NC specimens in the sulfate environment. In addition, confined specimens with FRP fabrics significantly improved the compressive strength, ductility and durability resistance of the specimens and the improvement was found higher with the increased number of FRP layers. Specimens wrapped with carbon FRP fabrics showed better mechanical performance and durability properties than the specimens wrapped with basalt FRP fabrics. Both FRP materials can be used as a rehabilitation material in the sulfate environment.

흰쥐 H-Y 항혈청을 이용한 생쥐배의 성감별에 관한 연구 (Studies on Sexing of Mouse Embryos with Rat H-Y Antisera)

  • 최화식;임경순;조병대;정진관;오성종;양보석
    • 한국가축번식학회지
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    • 제17권4호
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    • pp.305-310
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    • 1994
  • These expriments were carried out to investigate existence of H-Y antibody in the rat serum immunized against H-Y antigen from rat spleen cells and effect of H-Y antiserum on development of mouse male embryos. The results obtained were summerized as follows : 1. When mouse embryos were cultured for 48∼72 hrs in the Ham's F10 containing 16% of FBS(fetal bovine serum) or RNS(rat normal serum), percentages of embryos developed from 2, 4, 8 and 16-cell embryo to morulae were 20, 27, 94 and 100%, respectively, in FBS and 8, 7, 94 and 100%, respectively, in RNS. Eight to 16-cell embryos showed no difference in development rate between FBS adn RNS. 2. When 8∼16-cell mouse embryos were cultured for 24∼48 hrs in the Ham's F10 containing FBS, RNS+GPC(guinea pig complement) and RAS(rat antiserum)+GPC, proportions of embryos developed to the expanded blastocyst stage were 100, 82.4 and 52.1∼53.6%(ave.52.9), respectively, so that it was suggested that rat antiserum suppressed development of male embryos. 3. When 8∼16-cell mouse embryos were cultured for 24∼48 hrs in the Ham's F10 containing FBS, RNS, RNS+GPC and RAS+GPC, proportions of embryos developed to the expanded blastocyst stage were 94.5, 90.9, 82.3 and 47%, respectively, and the embryos developed in the medium containing RAS+GPC seemed to be female. These results indicated that the antisera prepared through immunized against H-Y antigen from rat spleen cell, possessed H-Y antibody which supressed development of male embryos.

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Predictive modeling of the compressive strength of bacteria-incorporated geopolymer concrete using a gene expression programming approach

  • Mansouri, Iman;Ostovari, Mobin;Awoyera, Paul O.;Hu, Jong Wan
    • Computers and Concrete
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    • 제27권4호
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    • pp.319-332
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    • 2021
  • The performance of gene expression programming (GEP) in predicting the compressive strength of bacteria-incorporated geopolymer concrete (GPC) was examined in this study. Ground-granulated blast-furnace slag (GGBS), new bacterial strains, fly ash (FA), silica fume (SF), metakaolin (MK), and manufactured sand were used as ingredients in the concrete mixture. For the geopolymer preparation, an 8 M sodium hydroxide (NaOH) solution was used, and the ambient curing temperature (28℃) was maintained for all mixtures. The ratio of sodium silicate (Na2SiO3) to NaOH was 2.33, and the ratio of alkaline liquid to binder was 0.35. Based on experimental data collected from the literature, an evolutionary-based algorithm (GEP) was proposed to develop new predictive models for estimating the compressive strength of GPC containing bacteria. Data were classified into training and testing sets to obtain a closed-form solution using GEP. Independent variables for the model were the constituent materials of GPC, such as FA, MK, SF, and Bacillus bacteria. A total of six GEP formulations were developed for predicting the compressive strength of bacteria-incorporated GPC obtained at 1, 3, 7, 28, 56, and 90 days of curing. 80% and 20% of the data were used for training and testing the models, respectively. R2 values in the range of 0.9747 and 0.9950 (including train and test dataset) were obtained for the concrete samples, which showed that GEP can be used to predict the compressive strength of GPC containing bacteria with minimal error. Moreover, the GEP models were in good agreement with the experimental datasets and were robust and reliable. The models developed could serve as a tool for concrete constructors using geopolymers within the framework of this research.

일반화부분점수 모형에 의한 디자인역량 검사 특성 분석 (An Item Characteristic Analysis of Competency Inventory for Designer via Generalized Partial Credit Mode)

  • 이대용
    • 수산해양교육연구
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    • 제27권6호
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    • pp.1546-1555
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    • 2015
  • This study was performed to analyze the item characteristics of competency inventory for designer (CID), which Gil (2011) developed for measurement of design competency. To accomplish the purpose of this study, general partial credit (GPC) model based on polytomous item response theory was applied. The findings were as follows: First, CID is a reliable instrument for measuring design competency. Second, most items of CID have low item discrimination and average item difficulty according to the GPC model. Especially, there are some problems to have low item discrimination in view of validation. To improve the goodness of CID, we will need to examine why CID has low item discrimination.

Generalized predictive control based on the parametrization of two-degree-of-freedom control systems

  • Naganawa, Akihiro;Obinata, Goro;Inooka, Hikaru
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 1995년도 Proceedings of the Korea Automation Control Conference, 10th (KACC); Seoul, Korea; 23-25 Oct. 1995
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    • pp.1-4
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    • 1995
  • We propose a new design method for a generalized predictive control (GPC) system based on the parametrization of two-degree-of freedom control systems. The objective is to design the GPC system which guarantees the stability of the control system for a perturbed plant. The design procedure of our proposed method consists of three steps. First, we design a basic controller for a nominal plant using the LQG method and parametrize a whole control system. Next, we identify the deviation between the perturbed plant and the nominal one using a closed-loop identification method and design a free parameter of parametrization to stabilize the closed-loop system. Finally, we design a feedforward controller so as to incorporate GPC technique into our controller structure. A numerical example is presented to show the effectiveness of our proposed method.

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White ledger의 오존 탈묵 기구 (Ozone Deinking Mechanism of White Ledger)

  • 원종명;노국일
    • 펄프종이기술
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    • 제33권3호
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    • pp.24-28
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    • 2001
  • The utilization of wastepaper as a papermaking raw material is everlastingly required for the environmental protection of earth. However the recycling of wastepaper for this purpose cause another problem such as the increasing of the load of wastewater treatment, lower strength properties of paper, and poor printability, etc. The interest in the development of the environmentally friendly deinking technology is increased continuously. Thus, our research team have tried to apply the ozone to the deinking of white ledger and ONP, and obtained the positive results which can be considered as an alternative method for the conventional deinking method. The purpose of this study is to investigate the mechanism of ozone deinking. Styrene acrylate and polystyrene were treated with ozone and measured the change of molecular weight with the GPC. The molecular weight distribution obtained with GPC showed only slight increase by the ozone treatment, and gel formation by the polymerization was observed. Therefore the removal of ink particles with ozone treatment seems to be facilitated by the increase of the brittleness and decrease of adhesive property.

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Investigating the long-term behavior of creep and drying shrinkage of ambient-cured geopolymer concrete

  • Asad Ullah Qazi;Ali Murtaza Rasool;Iftikhar Ahmad;Muhammad Ali;Fawad S. Niazi
    • Structural Engineering and Mechanics
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    • 제89권4호
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    • pp.335-347
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    • 2024
  • This study pioneers the exploration of creep and shrinkage behavior in ambient-cured geopolymer concrete (GPC), a vital yet under-researched area in concrete technology. Focusing on the influence of sodium hydroxide (NaOH) solution concentration, the research utilizes low calcium fly ash (Class-F) and alkaline solutions to prepare two sets of GPC. The results show distinct patterns in compressive strength development and dry shrinkage reduction, with a 14 M NaOH solution demonstrating a 26.5% lower dry shrinkage than the 16 M solution. The creep behavior indicated a high initial strain within the first 7 days, significantly influenced by curing conditions and NaOH concentration. This study contributes to the existing knowledge by providing a deeper understanding of the time-dependent properties of GPC, which is crucial for optimizing its performance in structural applications.

HP-GPC를 이용한 폴리머개질 아스팔트의 노화특성 분석 (Evaluation of Aging Characteristics of Selected PMA using HP-GPC)

  • 김광우;도영수;써지엔아미리카니안
    • 한국도로학회논문집
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    • 제6권2호
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    • pp.15-24
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    • 2004
  • 산화는 아스팔트에서 대형분자(LMS : Large Molecular Size) 양의 증가를 야기하고 바인더의 경화에 주요 원인이 되므로 바인더 산화를 저감시키면 도로 및 공항 포장의 공용수명 연장을 기대할 수 있다. 바인더 산화는 혼합물을 도로에 깔기 전에 가열된 골재와 혼합하는 동안과 아스팔트 포장이 시공된 후 공용기간 동안에 일어난다. 본 연구에서는 바인더를 단기 및 장기노화 처리 후 LMS의 양적 증가를 HP-GPC (High-Pressure Gel-Permeation Chromatography)의 자료에 근거하여 해석하였다 개질 아스팔트는 LMS의 증가율이 아스팔트의 종류에 따라 다를 지라도 단기노화 후 LMS의 20-30%증가. 장기노화 후 2배 이상의 증가를 나타냈다. 본 연구에서 개질 아스팔트의 노화특성을 관찰하기 위하여 사용된 개질제는 선행 연구에서 큰 역학적 특성 향상을 보인 LDPE(Low-Density Polyethylene)와 SBS(Styrene-Butadiene-Styrene block copolymers) 를 사용하였다. LDPE로 개질한 바인더는 단 장기노화 후 LMS의 증가 비율이 상당히 낮았다. 이와 같이 낮은 LMS의 증가는 LDPE 개질 아스팔트가 노화 처리되는 동안에 일반 아스팔트보다 덜 노화가 진행된다는 것을 의미한다 이는 아스팔트 시멘트 내에 분산된 LDPE 입자가 산화 노화작용을 방해하기 때문인 것으로 보인다.

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