• Title/Summary/Keyword: GOx

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Study on Combustion Characteristic of GOx/PE Hybrid Rocket According to Port Diameter (GOx/PE 하이브리드 로켓의 포트 직경에 따른 연소특성 연구)

  • Choi, Jae-Sung;Huh, Hwan-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.692-693
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    • 2010
  • In this study, we analyze the combustion characteristic of GOx/PE hybrid rocket, by changing port diameter of the propellant. To study combustion characteristics of hybrid rocket, GOx is used for oxidizer and PolyEthylene is used for solid propellant. Regression rate and O/F ratio of the rocket is measured and presented.

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Preliminary Study of Thrust Control for Hybrid Rockets (하이브리드 로켓의 추력제어 기법에 대한 기초연구)

  • Yun, Dong-Ik;Kang, Wan-Kyu;Lee, Young-Woo;Lee, Jong-Lyul;Huh, Hwan-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.257-260
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    • 2008
  • In order to control thrust of propulsion system, we built the 50 Newton level PE-GOx hybrid rocket, and changed the mass flow rate of GOx. From the preliminary experiential results, we could see possibility of controlling thrust of hybrid rockets by controlling mass flow rate of GOx.

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Improvement in Enzyme Immobilization of Polypyrrole Enzyme Electrode using Radical Transfer (Radical Transfer 반응을 이용한 Polypyrrole 효소전극의 효소고정화 향상)

  • Kim, Hyun-Cheol;Cho, Young-Jai;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04b
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    • pp.100-103
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    • 2000
  • In the case of immobilizing of glucose oxidase into polypyrrole (PPy) using electrosynthesis, the glucose oxidase (GOx) forms a coordinate bond with the polymers backbone. However, because of intrinsic insulation and net-chain of the enzyme, the charge transfer and mass transport are obstructed during the film growth. Therefore, the film growth is dull. We synthesized the enzyme electrode by electropolymerization added some organic solvent. A formative seeds of film growth is delayed by adding ethanol. The delay is induced by radical transfer between ethanol and pyrrole monomer. The radical transfer shares the contribution of dopant between electrolyte anion and GOx polyanion. This may lead to increase amount of immobilized the enzyme in PPy. For the UV absorption spectra of synthetic solution before synthesis and after, in the case of ethanol added, the optical density was slightly decreased for the GOx peaks. It suggests amount of GOx in the solution was decreased and amount of GOx in the film was increased. We established qualitatively that amount of immobilization can be improved by adding a little ethanol in the synthetic solution. It is due to radical transfer reaction. The radical transfer shares the contribution of dopant between small and fast electrolyte anion and big and slow GOx polyanion.

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Correlative Production of Mn-Peroxidase and Glucose Oxidase Depending on the Culture Condition of Schizopora paradoxa (좀구멍버섯균의 배양조건에 따른 Mn-Peroxidase와 Glucose Oxidase의 생성조절)

  • Lee, Sang-Yoon;Shin, Hyeon-Dong;Kim, Kyu-Joong
    • The Korean Journal of Mycology
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    • v.22 no.4
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    • pp.325-331
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    • 1994
  • White-rot fungus, Schizopora paradoxa did not produce Mn-peroxidase and glucose oxidase without manganese. But, in high concentration of manganese (40 ppm), the activities of both enzymes were higher than those in basal concentration of manganese (11.15 ppm). Unlike the activities of the enzymes, mycelial mass was the same level as the control culture (11.15 ppm manganese) through out the culture period, depending on the concentration of manganese. The same experiments were carried out for the effect of copper and veratryl alcohol added to the culture. The results were not consistent dependent on the concentration of copper and veratryl alcohol, respectively. The involvement of cAMP in the correlative production of MNP and GOX was investigated. In this study, addition of atropine to the culture resulted in a concomitant inhibition of production of MNP and GOX, depending on the concentration of inhibitor added.

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A Study on the Combustion Characteristic in End-Burning Hybrid Propulsion System using $GN_2O$/PE ($GN_2O$/PE를 사용한 End-Burning 하이브리드 추진 시스템의 연소 특성 연구)

  • Woo, Kyoung-Jin;Moon, Keun-Hwan;Oh, Ji-Sung;Lee, Jung-Pyo;Moon, Hee-Jang;Sung, Hong-Gye;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.484-488
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    • 2010
  • In this study, combustion experiments of the End-Burning Hybrid Propulsion System using $GN_2O$(Gas Nitrous oxide)/HDPE were performed and the results were compared to those of the combustion experiments using GOX/HDPE. The regression rate of the solid fuel using $GN_2O$ is lower than that of the solid fuel using GOX since oxidizer inlet velocity of $GN_2O$ is lower than that of GOX. However, in case of using $GN_2O$, the characteristic velocity is higher than those of the GOX. The combustion chamber pressure and thrust were relatively kept constant during combustion.

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Improvement on Enzyme Immobilization in Polypyrrole-Glucose Oxidase Enzyme Electrode using Organic Solvent Additive I. Ultraviolet Spectroscopic Analyses (유기용매 첨가에 따른 Polypyrrole-Glucose Oxidase 효소전극의 효소고정화 향상 I. 자외선 분광분석)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.7
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    • pp.615-620
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    • 2002
  • In the case of immobilizing of glucose oxidase into polypyrrole (PPy) using electrosynthesis, the glucose oxidise (GOx) forms a coordinate bond with the polymers backbone. However, because of intrinsic insulation and net-chain of the enzyme, the charge transfer and mass transport are obstructed during the film growth. Therefore, the film growth is dull. We synthesized enzyme electrodes by electropolymerization added some organic solvent, such as ethanol and tetrahydrofuran (THF). The formative seeds of film growth was delayed by adding ethanol. The delay was induced by radical transfer between ethanol and pyrrole monomer. The radical transfer reactions shared the contribution of dopants between electrolyte anion and GOx polyanion. This led to increase amount of immobilized the enzyme in PPy. For the UV absorption spectra of synthetic solution before synthesis and after, in the case of ethanol added, the optical density was slightly decreased for the GOx peaks. It suggests amount of GOx in the solution was decreased and amount of GOx in the film was increased.

Performance Enhancement of Biofuel Cell by Surface Modification of Glucose Oxidase using Ferrocene Carboxylic acid (페로신카르복시산을 이용한 글루코스 산화효소의 표면개질에 의한 바이오 연료전지 성능향상)

  • JI, JUNGYEON;CHRISTWARDANA, MARCELINUS;CHUNG, YONGJIN;KWON, YONGCHAI
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.526-532
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    • 2016
  • In this study, we synthesized a mediator immobilized biocatalyst([FCA/GOx]/PEI/CNT) by surface modification using ferrocene carboxylic acid(FCA), and evaluated its performance as anode catalyst for biofuel cell. Through the application of FCA on glucose oxidase (GOx), the free amine groups on the lysine residue of GOx surface reacted with carboxylic acid of FCA and make amide bond between GOx and FCA. As the result of that, the electron transfer of catalyst was increased up to 1.91 times($0.468mA{\cdot}cm^{-2}$) than the catalyst without surface modification (GOx/PEI/CNT), and high maxium power density of $1.79mA{\cdot}cm^{-2}$ was gained.

Merge Characteristic of PMMA Multi-port Hybrid Rocket (PMMA 연료를 적용한 Multi-Port 하이브리드 로켓의 포트 병합특성에 관한 연구)

  • Park, Su-Hyang;Kim, Gi-Hun;Lee, Jung-Pyo;Cho, Jung-Tae;Kim, Soo-Jong;Kim, Hak-Chul;Woo, Kyong-Jin;Moon, Hee-Jang;Sung, Hong-Gye;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.247-250
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    • 2008
  • An experimental investigation was conducted to clarify the combustion characteristics and merge characteristics of PMMA-GOX and PE-GOX hybrid motor using multi-port fuel grain configuration. The regression rate of multi-port fuel grain is higher than the regression rate of single-port fuel grain by thermal conduction and chamber pressure. The merge of multi-port has an effect on hybrid rocket performance by change of a combustion area.

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Performance Prediction Methods and Combustion Characteristics of PE-GOX Hybrid Rocket Motor : Part II, Performance Prediction Method (PE-GOX 하이브리드 모터의 연소특성 및 성능 예측 기법 : Part II, 성능 예측 기법)

  • Yoon, Chang-Jin;Song, Na-Young;You, Woo-Jun;Moon, Hee-Jang;Kim, Jin-Kon;Sung, Hong-Gye
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.271-274
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    • 2006
  • In order to predict the performance of the small-scale Polyethylene-GOX hybrid rocket motor, a typical internal ballistic model was proposed. The model adopted for the present study employed the lumped scale of chamber pressure so that the pressure-time history resulted from the present model was comparable to the test results.

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Fabrication of enzymatic biosensor based on the poly(3-thiophenecarboxylic acid-co-thiophene) polymer as electron-transfer materials

  • Kim, Soo-Yeoun;Jo, Hyeon-Jin;Choi, Seong-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.269-278
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    • 2019
  • We fabricated glucose oxidase (GOx)-modified biosensor for detection of glucose by physical immobilization of GOx after electrochemical polymerization of the conductive mixture monomers of the 3-thiophenecarboxylic acid (TCA) and thiophene (Th) onto ITO electrode in this study. We confirmed the successfully fabrication of GOx-modified biosensor via FT-IR spectroscopy, SEM, contact angle, and cyclic voltammetry. The fabricated biosensor has the detection limit of $0.1{\mu}M$, the linearity of 0.001-27 mM, and sensitivity of $38.75mAM^{-1}cm^{-2}$, respectively. The fabricated biosensor exhibits high interference effects to dopamine, ascorbic acid, and L-cysteine, respectively. From these results, the fabricated GOx-modified biosensor with long linearity and high sensitivity could be used as glucose sensor in human blood sample.