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Facile synthesis of nanostructured n-type SiGe alloys with enhanced thermoelectric performance using rapid solidification employing melt spinning followed by spark plasma sintering

  • Vishwakarma, Avinash;Bathula, Sivaiah;Chauhan, Nagendra S.;Bhardwaj, Ruchi;Gahtori, Bhasker;Srivastava, Avanish K.;Dhar, Ajay
    • Current Applied Physics
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    • v.18 no.12
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    • pp.1540-1545
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    • 2018
  • SiGe alloy is widely used thermoelectric materials for high temperature thermoelectric generator applications. However, its high thermoelectric performance has been thus far realized only in alloys synthesized employing mechanical alloying techniques, which are time-consuming and employ several materials processing steps. In the current study, for the first time, we report an enhanced thermoelectric figure-of-merit (ZT) ~ 1.1 at $900^{\circ}C$ in ntype $Si_{80}Ge_{20}$ nano-alloys, synthesized using a facile and up-scalable methodology consisting of rapid solidification at high optimized cooling rate ${\sim}3.4{\times}10^7K/s$, employing melt spinning followed by spark plasma sintering of the resulting nano-crystalline melt-spun ribbons. This enhancement in ZT > 20% over its bulk counterpart, owes its origin to the nano-crystalline microstructure formed at high cooling rates, which results in crystallite size ~7 nm leading to high density of grain boundaries, which scatter heat-carrying phonons. This abundant scattering resulted in a very low thermal conductivity ${\sim}2.1Wm^{-1}K^{-1}$, which corresponds to ~50% reduction over its bulk counterpart and is amongst the lowest reported thus far in n-type SiGe alloys. The synthesized samples were characterized using X-ray diffraction, scanning electron microscopy and transmission electron microscopy, based on which the enhancement in their thermoelectric performance has been discussed.

Magnetic field imperfections of in-vacuum undulator on PLS-II beam dynamics

  • Chunjarean, Somjai;Hwan, Shin-Seung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.359-359
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    • 2011
  • Many research applications in basic sciences and biology such as protein crystallography require hard x-rays in the range of 3-20 keV with high brightness. A medium energy storage ring as PLS-II with a beam energy of 3 GeV can meet such high photon energies. In-vacuum undulators (IVU) with a period length of 20 mm and a peak field of 0.97 T are used in the PLS-II ring to produce such X-rays in the fundamental or higher harmonics. Due to the many poles and high fields, insertion devices like wigglers and undulators have a significant impact on the stability of the electron beam with potential degradation of beam quality and life time. Therefore, nonlinear fields must be determined by measurement and evaluated as to their impact on beam stability. Specifically, transverse field roll-off can be a serious detriment to injection in top-up mode and must be corrected. We use magnetic field measurement data to evaluated beam stability by tracking particles using an explicit symplectic integrator in both, transverse and longitudinal planes.

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Magnetic Microstructures and Corrosion Behaviors of Nd-Fe-B-Ti-C Alloy by Ga Doping

  • Wu, Qiong;Zhang, Pengyue;Ge, Hongliang;Yan, Aru;Li, Dongyun
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.240-244
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    • 2013
  • The influences of Gallium doping on the magnetic microstructures and corrosion behaviors of Nd-Fe-B-Ti-C alloys are investigated. The cooling rate for obtaining fully amorphous structure is raised, and the glassforming ability is improved by the Ga addition. The High Resolution Transmission Electron Microscopy image shows that the ${\alpha}$-Fe and $Fe_3B$ soft magnetic phases become granular surrounded by the $Nd_2Fe_{14}B$ hard magnetic phase. The rms and $({\Delta}{\varphi})_{rms}$ value of Nd-Fe-B-Ti-C nanocomposite alloy thick ribbons in the typical topographic and magnetic force images detected by Magnetic Force Microscopy(MFM) decreases with 0.5 at% Ga addition. The corrosion resistances of $Nd_9Fe_{73}B_{12.6}C_{1.4}Ti_{4-x}Ga_x$ (x = 0, 0.5, 1) alloys are enhanced by the Ga addition. It can be attributed to the formation of more amorphous phases in the Ga doped samples.

The Spin-Rotation Interaction of the Proton and the Fluorine Nucleus in the Tetrahedral Spherical Top Molecules

  • Lee, Sang-Soo;Ozier, Irving;Ramsey, N.F.
    • Nuclear Engineering and Technology
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    • v.5 no.1
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    • pp.38-43
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    • 1973
  • The spin-rotation constants of the proton and tile fluorine nucleus in C $H_4$, Si $H_4$, Ge $H_4$, C $F_4$, Si $F_4$ and Ge $F_4$ were determined experimentally by the molecular beam magnetic resonance method. From the Hamiltonian and the high field approximation, the quantized energy level is given by the following equation. W $m_{I}$ $m_{J}$=- $g_{I}$ $m_{I}$H- $g_{J}$ $m_{J}$H- $C_{av}$ $m_{I}$ $m_{J}$, where $c_{av}$ is one third of the trace of the C tensor. In the nuclear resonance experiment, the proton and the fluorine nuclear resonance curves consist of many unresolved lines given by v=- $g_{J}$H- $C_{av}$ $m_{I}$, and a Gaussian approximation is made to correlate $c_{av}$ to the experimentally obtained half-width of the resonance curve. In the rotational resonance experiment, the five resonance peaks as predicted by v=- $g_{I}$H- $c_{av}$ $m_{I}$, $m_{I}$=0, $\pm$1 and $\pm$2, were all observed. The magnitude of car was determined by measuring the frequency distance between two adjacent peaks. The sign of $c_{av}$ was determined by the side peak suppression technique. The technique is described, and the sign and magnitude of the spin-rotation constant cav are summarized as following: for C $H_4$ -10.3$\pm$0.4tHz(from the rotational resonance), for SiH +3.71$\pm$0.08kHz(from the nuclear resonance), for Ge $H_4$+3.79$\pm$0.13kHz(from the nuclear resonance), for C $F_4$, -6.81$\pm$0.08kHz(from the rotational resonance), for Si $F_4$, -2.46$\pm$0.06kHz(from the rotational resonance), and finally for Ge $F_4$-1.84$\pm$0.04kHz(from the rotational resonance).onal resonance).esonance).

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Structure and Magnetic Properties of Cr2O3/CrO2 Nanoparticles Prepared by Reactive Laser Ablation and Oxidation under High Pressure of Oxygen

  • Si, P.Z.;Wang, X.L.;Xiao, X.F.;Chen, H.J.;Liu, X.Y.;Jiang, L.;Liu, J.J.;Jiao, Z.W.;Ge, H.L.
    • Journal of Magnetics
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    • v.20 no.3
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    • pp.211-214
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    • 2015
  • $Cr_2O_3$ nanoparticles were prepared via one-step reactive laser ablation of Cr in oxygen. The metastable $CrO_2$ phase was obtained through the subsequent oxidation of $Cr_2O_3$ nanoparticles under $O_2$ with gas pressures of up to 40 MPa. The as-prepared $Cr_2O_3$ nanoparticles are spherical or rectangular in shape with sizes ranging from 20 nm to 50 nm. High oxygen pressure annealing is effective in producing meta-stable $CrO_2$ from as-dried $Cr_2O_3$ nanoparticles, and the $Cr_2O_3$ nanoparticles exhibit a weak ferromagnetic behavior with an exchange bias of up to 11 mT that can be ascribed to the interfacial exchange coupling between uncompensated surface spins and the antiferromagnetic core. The $Cr_2O_3/CrO_2$ nanoparticles exhibit an enhanced saturation magnetization and a reduced exchange bias with an increasing faction of $CrO_2$ due to the elimination of uncompensated surface spins over the $Cr_2O_3$ nanoparticles when exposed to a high pressure of $O_2$ and/or possible phase segregation that results in a smaller grain size for both $Cr_2O_3$ and $CrO_2$.

SED modelling of broadband emission in the pulsar wind nebula 3C 58

  • Kim, Seungjong;An, Hongjun
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.55.1-55.1
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    • 2019
  • We investigate broadband emission properties of the pulsar wind nebula (PWN) 3C 58 using a spectral energy distribution (SED) model. We attempt to match simultaneously the broadband SED and spatial variations and emission about 3C 58 in X-ray band. We further the model to explain a possible far-IR feature of which a hint is recently suggested in 3C 58: a small bump at ~10^11 GHz in the PLANCK and Herschel band. While external dust emission may easily explain the observed bump, it may be internal emission of PWNe implying an another additional population of particles. Although significance for the bump in 3C 58 is not higher than other PWNe, here we explore possible origins of the IR bump using the emission model and find that a population of electrons with GeV energies can explain the bump. If it is produced in the PWN, it may provide new insights into particle acceleration and flows in PWNe.

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SYMMETRIC SOLUTIONS FOR A FOURTH-ORDER MULTI-POINT BOUNDARY VALUE PROBLEMS WITH ONE-DIMENSIONAL $p$-LAPLACIAN AT RESONANCE

  • Yang, Aijun;Wang, Helin
    • Journal of applied mathematics & informatics
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    • v.30 no.1_2
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    • pp.161-171
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    • 2012
  • We consider the fourth-order differential equation with one-dimensional $p$-Laplacian (${\phi}_p(x^{\prime\prime}(t)))^{\prime\prime}=f(t,x(t),x^{\prime}(t),x^{\prime\prime}(t)$) a.e. $t{\in}[0,1]$, subject to the boundary conditions $x^{\prime\prime}}(0)=0$, $({\phi}_p(x^{\prime\prime}(t)))^{\prime}{\mid}_{t=0}=0$, $x(0)={\sum}_{i=1}^n{\mu}_ix({\xi}_i)$, $x(t)=x(1-t)$, $t{\in}[0,1]$, where ${\phi}_p(s)={\mid}s{\mid}^{p-2}s$, $p$ > 1, 0 < ${\xi}_1$ < ${\xi}_2$ < ${\cdots}$ < ${\xi}_n$ < $\frac{1}{2}$, ${\mu}_i{\in}\mathbb{R}$, $i=1$, 2, ${\cdots}$, $n$, ${\sum}_{i=1}^n{\mu}_i=1$ and $f:[0,1]{\times}\mathbb{R}^3{\rightarrow}\mathbb{R}$ is a $L^1$-Carath$\acute{e}$odory function with $f(t,u,v,w)=f(1-t,u,-v,w)$ for $(t,u,v,w){\in}[0,1]{\times}\mathbb{R}^3$. We obtain the existence of at least one nonconstant symmetric solution by applying an extension of Mawhin's continuation theorem due to Ge. Furthermore, an example is given to illustrate the results.

Predicting the Digestible Energy of Rapeseed Meal from Its Chemical Composition in Growing-finishing Pigs

  • Zhang, T.;Liu, L.;Piao, X.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.3
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    • pp.375-381
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    • 2012
  • Two experiments were conducted to establish a digestible energy (DE) content prediction model of rapeseed meal for growing-finishing pig based on rapeseed meal's chemical composition. In experiment 1, observed linear relationships between the determined DE content of 22 rapeseed meal calibration samples and proximate nutrients, gross energy (GE) and neutral detergent fiber (NDF) were used to develop the DE prediction model. In experiment 2, 4 samples of rapeseed meal selected at random from the primary rapeseed growing regions of China were used for testing the accuracy of DE prediction models. The results indicated that the DE was negatively correlated with NDF (r = -0.86) and acid detergent fiber (ADF) (r = -0.73) contents, and moderately correlated with gross energy (GE; r = 0.56) content in rapeseed meal calibration samples. In contrast, no significant correlations were found for crude protein, ether extract, crude fiber and ash contents. According to the regression analysis, NDF or both NDF and GE were found to be useful for the DE prediction models. Two prediction models: DE = 16.775-0.147${\times}$NDF ($R^2$ = 0.73) and DE = 11.848-0.131${\times}$NDF+0.231${\times}$GE ($R^2$ = 0.76) were obtained. The maximum absolute difference between the in vivo DE determinations and the predicted DE values was 0.62 MJ/kg and the relative difference was 5.21%. Therefore, it was concluded that, for growing-finishing pigs, these two prediction models could be used to predict the DE content of rapeseed meal with acceptable accuracy.

Exploring the Extra Component in the Gamma-ray Emission of the New Redback Candidate 3FGL J2039.6-5618

  • Ng, Cho-Wing;Cheng, Kwong-Sang;Takata, Jumpei
    • Journal of Astronomy and Space Sciences
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    • v.33 no.2
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    • pp.93-99
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    • 2016
  • A redback system is a binary system composed of a pulsar and a main sequence star. The inverse Compton (IC) scattering between the stellar soft photons and the relativistic pulsar wind will generate orbital-modulating GeV photons. We look for these IC emissions from redback systems. A multi-wavelength observation of an unassociated gamma-ray source, 3FGL J2039.6-5618, by Salvetti et al. (2015) detected an orbital modulation with a period of 0.2 days in both X-ray and optical cases. They suggested 3FGL J2039.6-5618 to be a new redback candidate. We analyzed the gamma-ray emission of 3FGL J2039.6-5618 using the data from the Fermi large area telescope (Fermi-LAT) and obtained the spectrum in different orbital phases. We propose that the spectrum has orbital dependency and estimate the characteristic energy of the IC emission from the stellar-pulsar wind interaction.

Investigation of the Jets of the Blazar 3C 279 with Korean VLBI Network (KVN) 22-129 GHz Observations

  • Yoo, Sungmin;Lee, Sang-Sung;Kim, Sang-Hyun;An, Hongjun
    • Journal of Astronomy and Space Sciences
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    • v.38 no.4
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    • pp.193-202
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    • 2021
  • We present analysis results of Korean VLBI Network (KVN) four-band data for the highly variable blazar 3C 279. We measured the 22, 43, 86, and 129 GHz flux densities and spectral indices of the source using contemporaneous data taken over 5.6 years. We used the discrete correlation function to investigate correlations between the radio emission properties and those measured in the optical (2 × 1014 - 1.5 × 1015 Hz), X-ray (0.3-10 keV), and gamma-ray (0.1-300 GeV) bands. We found a significant correlation between the radio spectral index and gamma-ray flux without a time delay and interpreted the correlation using an extended jet scenario for blazar emission.