• Mass Spectrometry Letters
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• v.9 no.4
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• pp.91-94
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• 2018

Bilin tetrapyrroles are metabolic products of the breakdown of porphyrins within a species. In the case of mammals, these bilins are formed by the catabolism of heme and can be utilized as either biomarkers in disease or as an indicator of human waste contamination. Although a small subset of bilin tandem mass spectrometry reports exist, limited data is available in online databases for their fragmentation. The use of fragmentation data is important for metabolomics analyses to determine the identity of compounds detected within a sample. Therefore, in this study, the fragmentation of bilins generated by positive ion mode electrospray ionization is examined by collision-induced dissociation (CID) as a function of collision energy on an FT-ICR MS. The use of the FT-ICR MS allows for high mass accuracy measurements, and thus the formulas of resultant product ions can be ascertained. Based on our observations, fragmentation behavior for hemin, biliverdin and its dimethyl ester, phycocyanobilin, bilirubin, bilirubin conjugate, mesobilirubin, urobilin, and stercobilin are discussed in the context of the molecular structure and collision energy. This report provides insight into the identification of structures within this class of molecules for untargeted analyses.

• KSII Transactions on Internet and Information Systems (TIIS)
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• v.13 no.2
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• pp.1080-1099
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• 2019

A better tradeoff between robustness and invisibility will be realized by using the just noticeable (JND) model into the quantization-based watermarking scheme. The JND model is usually used to describe the perception characteristics of human visual systems (HVS). According to the research of cognitive science, HVS can adaptively extract the structure features of an image. However, the existing JND models in the watermarking scheme do not consider the structure features. Therefore, a novel JND model is proposed, which includes three aspects: contrast sensitivity function, luminance adaptation, and contrast masking (CM). In this model, the CM effect is modeled by analyzing the direction features and texture complexity, which meets the human visual perception characteristics and matches well with the spread transform dither modulation (STDM) watermarking framework by employing a new method to measure edge intensity. Compared with the other existing JND models, the proposed JND model based on structural regularity is more efficient and applicable in the STDM watermarking scheme. In terms of the experimental results, the proposed scheme performs better than the other watermarking scheme based on the existing JND models.

• Wind and Structures
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• v.31 no.6
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• pp.561-573
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• 2020

Unsteady self-excited forces are commonly represented by parametric models such as rational functions. However, this requires complex multiparametric nonlinear fitting, which can be a challenging task that requires know-how. This paper explores the alternative nonparametric modeling of unsteady self-excited forces based on relations between flutter derivatives. By exploiting the properties of the transfer function of linear causal systems, we show that damping and stiffness aerodynamic derivatives are related by the Hilbert transform. This property is utilized to develop exact simplified expressions, where it is only necessary to consider the frequency dependency of either the aeroelastic damping or stiffness terms but not both simultaneously. This approach is useful if the experimental data on aerodynamic derivatives that are related to the damping are deemed more accurate than the data that are related to the stiffness or vice versa. The proposed numerical models are evaluated with numerical examples and with data from wind tunnel experiments. The presented method can evaluate any continuous fitted table of interpolation functions of various types, which are independently fitted to aeroelastic damping and stiffness terms. The results demonstrate that the proposed methodology performs well. The relations between the flutter derivatives can be used to enhance the understanding of experimental modeling of aerodynamic self-excited forces for bridge decks.

• Bulletin of the Korean Chemical Society
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• v.13 no.3
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• pp.230-235
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• 1992

The conformational analysis has been done for catecholamines (dopamine, norepinephrine, and epinephrine) in the cationic and di-anionic states. The species responsible for adsorption on silver metal surface is anionic deprotonated at hydroxyl groups of catechol moiety, i.e., di-anionic states of catecholamines. This was deduced from Fourier-transform Raman spectra of sodium salts of catecholamines. High resolution proton NMR (400 MHz) spectra of catecholamines in basic and neutral $D_2O$ solution show that the conformations of norepinephrine and epinephrine in the di-anionic states are preferred in gauche, but not for dopamine in the di-anionic state. However the energy difference between trans and gauche of catecholamines in the protonated cationic states is small enough to rotate freely through C-C bond in ethylamine moiety. The conformational calculations using an empirical potential function and the hydration shell model (a program CONBIO) show consistent with above experimental results. The calculations suggest that the species of catecholamines adsorbed on silver metal surface would be in favor of the gauche conformations.

• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.285-290
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• 1999

In the present paper, we report a molecular dynamics (MD) simulation study for the structure and dynamics of H+ ions in non-rigid dehydrated H12-A zeolite framework at 298.15 K, using the same method we used in our previous studies of rigid and non-rigid zeolite-A frameworks. It is found that two different structures appear, depending on the choice of the Lennard-Jones parameter (σ) for the H+ ion, as is also observed in the study of rigid dehydrated H12-A zeolite framework, but the ranges of σ are different for the two structures. It is also found that some of the H+ ions exchanged their sites without changing the number of H+ ions at each site. The agreement between experimental and calculated structural parameters for non-rigid dehydrated H12-A zeolite is generally quite good. The calculated IR spectrum by Fourier transform of the total dipole moment auto-correlation function shows two major peaks, one around 2700 cm-1 and the other around 7000 cm-1. The former appears in the calculated IR spectra of non-rigid zeolite-A framework only system and the latter remains unexplained except, perhaps, as an indication of a new formation of a vibrational mode of the framework due to the adsorption of the H+ ions.

• Structural Monitoring and Maintenance
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• v.7 no.4
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• pp.283-294
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• 2020

In this paper, an adaptive MEMD based modal identification technique for linear time-invariant systems is proposed employing multiple vibration measurements. Traditional empirical mode decomposition (EMD) suffers from mode-mixing during sifting operations to identify intrinsic mode functions (IMF). MEMD performs better in this context as it considers multi-channel data and projects them into a n-dimensional hypercube to evaluate the IMFs. Using this technique, modal parameters of the structural system are identified. It is observed that MEMD has superior performance compared to its traditional counterpart. However, it still suffers from mild mode-mixing in higher modes where the energy contents are low. To avoid this problem, an adaptive filtering scheme is proposed to decompose the interfering modes. The Proposed modified scheme is then applied to vibrations of a reinforced concrete road bridge. Results presented in this study show that the proposed MEMD based approach coupled with the filtering technique can effectively identify the parameters of the dominant modes present in the structural response with a significant level of accuracy.

• Journal of radiological science and technology
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• v.44 no.4
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• pp.375-380
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• 2021

This study aim was quantitative assessment of MTFs of spectrum of the square wave chart images and Coltman chart images for 0°, 1.7°, 2.2°, 2.9°, 4.1° by using chart method. In general device was AccuRay-650 (DK Medical System, Korea) used, indirect flat panel detector(FPD) Aero (Konica, Japan) used and MATLAB R2019a (MathWorks, USA) used. The result of comparison for each angle of MTF the edge image was highest quantitatively value for MTF finding of showed the best value of 0.1 based on the frequency of 3.5 mm^-1, value of 0.1 based on the square wave was frequency of 3.0 mm^-1 and value of 0.1 based on the Coltman transform was frequency of 2.4 mm^-1. In this study it was significant that the methodology of the international Electro-technical Commission was applied mutandis by using the Fujita method within 2~3°.

• Journal of Korea Multimedia Society
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• v.24 no.8
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• pp.1076-1089
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• 2021

Among the currently used knowledge-based authentication methods for smartphones, text and graphic-based authentication methods, such as PIN and pattern methods, use a display unit and a touch function of the display unit for input/output of secret information. Recently released smartphone form factors are trying to transform into various forms, away from the conventional bar and slate types because of the material change of the display unit used in the existing smartphone and the increased flexibility of the display unit. However, as mentioned in the study of D. Choi [1], the structural change of the display unit may directly or indirectly affect the authentication method using the display unit as the main input/output device for confidential information, resulting in unexpected security vulnerabilities. In this paper, we analyze the security vulnerabilities of the current mobile user authentication methods that is applied atypical form factor. According to the analysis results, it seems that the existing display-dependent mobile user authentication methods do not consider emerging security threats at all. Furthermore, it is easily affected by changes in the form factor of smartphones. Finally, we propose countermeasures for security vulnerabilities expected when applying conventional authentication methods to atypical form factor-based smartphones.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.1
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• pp.41-48
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• 2022

Vehicle vibration was introduced in the time and frequency domains using fast Fourier transform (FFT) analysis. In particular, a vibration mode analysis and characteristics of the frequency response function (FRF) in a sport utility vehicle (SUV) passing over a bump barrier at different speeds was performed systematically. The response behavior of the theoretical acceleration was obtained using a numerical method applied to the forced vibration model. The amplitude and frequency of the external force on the vehicle cause various power spectra with individual intrinsic system frequencies. In this regard, several modes of power spectra were acquired from the spectra and are discussed in this paper. The proposed technique can be used for monitoring the acceleration in a vehicle passing over a bump barrier. To acquire acceleration signals, various experimental runs were performed using the SUV. These acceleration signals were then used to acquire the FRF and to conduct mode analysis. The vehicle characteristics according to the vehicle condition were analyzed using FRF. In addition, the vehicle structural system and bump passing frequencies were discriminated based on their power spectra and other FRF spectra.

• Geomechanics and Engineering
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• v.29 no.1
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• pp.53-63
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• 2022

Simplified analytical solutions are developed for the dynamic analyses of an axially loaded pile foundation embedded in a transverse-isotropic, fluid-filled, poro-visco-elastic soil with rigid substratum. The pile is modeled as a viscoelastic Rayleigh-Love rod, while the surrounding soil is regarded as a transversely isotropic, liquid-saturated, viscoelastic, porous medium of which the mechanical behavior is represented by the Boer's poroelastic media model and the fractional derivative model. Upon the separation of variables, the frequency-domain responses for the impedance function of the pile top, and the vertical displacement and the axial force along the pile shaft are gained. Then by virtue of the convolution theorem and the inverse Fourier transform, the time-domain velocity response of the pile head is derived. The presented solutions are validated, compared to the existing solution, the finite element model (FEM) results, and the field test data. Parametric analyses are made to show the effect of the soil anisotropy and the excitation frequency on the pile-soil dynamic responses.