• 제목/요약/키워드: Full cell

검색결과 1,039건 처리시간 0.034초

Mitigating Metal-dissolution in a High-voltage 15 wt% Si-Graphite‖Li-rich Layered Oxide Full-Cell Utilizing Fluorinated Dual-Additives

  • Kim, Jaeram;Kwak, Sehyun;Pham, Hieu Quang;Jo, Hyuntak;Jeon, Do-Man;Yang, A-Reum;Song, Seung-Wan
    • Journal of Electrochemical Science and Technology
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    • 제13권2호
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    • pp.269-278
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    • 2022
  • Utilization of high-voltage electrolyte additive(s) at a small fraction is a cost-effective strategy for a good solid electrolyte interphase (SEI) formation and performance improvement of a lithium-rich layered oxide-based high-energy lithium-ion cell by avoiding the occurrence of metal-dissolution that is one of the failure modes. To mitigate metal-dissolution, we explored fluorinated dual-additives of fluoroethylene carbonate (FEC) and di(2,2,2-trifluoroethyl)carbonate (DFDEC) for building-up of a good SEI in a 4.7 V full-cell that consists of high-capacity silicon-graphite composite (15 wt% Si/C/CF/C-graphite) anode and Li1.13Mn0.463Ni0.203Co0.203O2 (LMNC) cathode. The full-cell including optimum fractions of dual-additives shows increased capacity to 228 mAhg-1 at 0.2C and improved performance from the one in the base electrolyte. Surface analysis results find that the SEI stabilization of LMNC cathode induced by dual-additives leads to a suppression of soluble Mn2+-O formation at cathode surface, mitigating metal-dissolution event and crack formation as well as structural degradation. The SEI and structure of Si/C/CF/C-graphite anode is also stabilized by the effects of dual-additives, contributing to performance improvement. The data give insight into a basic understanding of cathode-electrolyte and anode-electrolyte interfacial processes and cathode-anode interaction that are critical factors affecting full-cell performance.

Full Size PDP Development with SDR Structure for Improved Luminance and Low Power Consumption

  • Yoo, Min-Sun;Yoon, Cha-Keun;Lee, Kwang-Sik;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.53-56
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    • 2002
  • Samsung's newly developed high luminance efficiency 42" VGA plasma display panel is introduced. A new discharge cell structure, SDR (Segmented electrode in Delta color arrayed Rectangular subpixel) has been applied to a full size panel for the first time. In this paper, we describe how this new discharge cell structure for high efficiency is integrated to an energy saving plasma display with better picture quality.

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슁글드 모듈 제작을 위한 고효율 실리콘 태양전지의 레이저 스크라이빙에 의한 영향 (Effect of Laser Scribing in High Efficiency Crystal Photovoltaic Cells to Produce Shingled Photovoltaic Module)

  • 이성은;박지수;오원제;이재형
    • 한국전기전자재료학회논문지
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    • 제33권4호
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    • pp.291-296
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    • 2020
  • The high power of a shingled photovoltaic module can be attributed to its low cell-to-module loss. The production of high power modules in limited area requires high efficiency solar cells. Shingled photovoltaic modules can be made by divided solar cells, which can be produced by the laser scribing process. After dividing the 21% PERC cell using laser scribing, the efficiency decreased by approximately 0.35%. However, there was no change in the efficiency of the solar cell having relatively lower efficiency, because the laser scribing process induce higher heat damages in solar cells with high efficiency. To prove this phenomena, the J0 (leakage current density) of each cell was analyzed. It was found that the J0 of 21% PERC increased about 17 times between full and divided solar cell. However, the J0 of 20.2% PERC increased only about 2.5 times between full and divided solar cell.

A COMPUTATIONAL MODEL FOR OSMOSIS PHENOMENA OF CELLS THROUGH SEMI-PERMEABLE MEMBRANES

  • Kim, Im-Bunm;Ha, Tae-Young;Sheen, Dong-Woo
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제13권2호
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    • pp.123-140
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    • 2009
  • The effect of a solute concentration difference on the osmotic transport of water through the semi-permeable membrane of a simple cell model is investigated. So far, most studies on osmotic phenomena are described by simple diffusion-type equations ignoring all fluid motion or described by Stokes flow. In our work, as the governing equations, we consider the coupled full Navier-Stokes equations which describe the fluid motion and the full transport equation that takes into account of convection and diffusion effects. A two dimensional finite difference model has been developed to simulate the velocity field, concentration field, and semi-permeable membrane movement. It is shown that the cell swells to regions of lower solute concentration due to the uneven water flux through the semi-permeable membrane. The simulation is applied on a red blood cell geometry and the relevant results are presented.

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Fabrication of a Full-Scale Pilot Model of a Cost-Effective Sodium Nickel-Iron Chloride Battery Over 40 Ah

  • Lee, Dong-Geun;Ahn, Byeong-Min;Ahn, Cheol-Woo;Choi, Joon-Hwan;Lee, Dae-Han;Lim, Sung-Ki
    • Journal of Electrochemical Science and Technology
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    • 제12권4호
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    • pp.398-405
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    • 2021
  • To fabricate a full-scale pilot model of the cost-effective Na-(Ni,Fe)Cl2 cell, a Na-beta-alumina solid electrolyte (BASE) was developed by applying a one-step synthesis cum sintering process as an alternative to the conventional solid-state reaction process. Also, Fe metal powder, which is cheaper than Ni, was mixed with Ni metal powder, and was used for cathode material to reduce the cost of raw material. As a result, we then developed a prototype Na-(Ni,Fe)Cl2 cell. Consequently, the Ni content in the Na-(Ni,Fe)Cl2 cell is decreased to approximately (20 to 50) wt.%. The #1 prototype cell (dimensions: 34 mm × 34 mm × 235 mm) showed a cell capacity of 15.9 Ah, and 160.3 mAh g-1 (per the Ni-Fe composite), while the #2 prototype cell (dimensions: 50 mm × 50 mm × 335 mm) showed a cell capacity of 49.4 Ah, and 153.2 mAh g-1 at the 2nd cycle.