• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.293-300
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• 2006

KIER has been developing a Ru-based preferential oxidation catalysts and a novel fuel processing system to provide hydrogen rich gas to residential PEMFCs system. The catalytic activity of Ru-based catalysts was investigated at different Ru loading amount and different support structure. The obtained result indicated that 2 wt% loaded Ru-based catalyst supported on ${\alpha}-Al_2O_3$ showed high activity in low temperature range and suppressed the methanation reaction. The developed prototype fuel processor showed thermal efficiency of 78% as a HHV basis with methane conversion of 92%. CO concentration below 10 ppm in the produced gas is achieved with separate preferential oxidation unit under the condition of $[O_2]/[CO]=2.0$. The partial load operation have been carried out to test the performance of fuel processor from 40% to 80% load, showing stable methane conversion and CO concentration below 10 ppm. The durability test for the daily start-stop and 8 h operation procedure is under investigation and shows no deterioration of its performance after 50 start-stop cycles. In addition to the system design and development.

• Journal of the Korean Society of Combustion
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• v.21 no.4
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• pp.48-60
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• 2016

Experimental and numerical studies were conducted to investigate flame behaviors near flammable limits for downstream-interacting SNG-air premixed flames in a counter-flow configuration. The SNG fuel consisted of a methane, a propane, and a hydrogen with volumetric ratios of 91, 6, and 3%, respectively. The most appropriate priority for some reliable reaction mechanisms examined was given to the mechanism of UC San diego via comparison of lean extinction limits attained numerically with experimental ones. Flame stability map was presented with a functional dependencies of lower and upper methane concentrations in terms of global strain rate. The results show that, at the global strain rate of $30s^{-1}$, lean extinction boundary is slanted while rich extinction one is relatively less inclined because of the dependency of such extinction boundary shapes on deficient reactant Lewis number governed by methane mainly. Further increase of global strain rate forces both extinction boundaries to be more slanted and to be shrunk, resulting in an island of extinction boundary and subsequently one flame extinction limit. Extinction mechanisms for lean and rich, symmetric and asymmetric extinction boundary were identified and discussed via heat losses and chemical interaction.

• Journal of the Mineralogical Society of Korea
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• v.16 no.2
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• pp.171-180
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• 2003

The objective of this study is to investigate biogeochemical processes to sequester $CO_2$and metals utilizing metal-rich fly ash (MRFA). Microbial conversion of $CO_2$into sparingly soluble carbonate minerals has been studied using MRFA under different $pCO_2$and different bicarbonate concentrations. Scaling from test tube to fermentation vessels (up to 4-L) using metal-reducing bacteria and MRFA has proved successful at sequestering carbon dioxide and metals. $CO_2$sequestration via precipitation processes using MRFA may complement the process of $CO_2$capture from fossil fuel plants while potentially stabilizing fly ash wastes.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.150-153
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• 2006

Gas generator should be adopted either fuel rich or oxidizer rich combustion because of the temperature restriction to avoid any possible thermal damages to turbine blade. This study focuses to model the non-equilibrium chemical reaction of kerosene/LOx with detailed kinetics developed by Dagaut using Perfectly stirred reactor(PSR) assumption. To predict more reliable species fraction and other gas properties, Frenklach's soot model was added to Dagaut's detailed kinetics.

• Explosives and Blasting
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• v.18 no.1
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• pp.53-58
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• 2000

Thermal analysis, analysis of combustion residue and combustion characteristics measure ment such as burning rate or temperature were carried out to clarify the combustion mechanism of a tungsten- potassium perchlorate-barium chromate chromate delay powder. The results obtained are as follows. The main reaction of the delay powder of tungsten-potassium perchlorate-barium chromate is the oxidation of tungsten by potassium perchlorate. Barium chromate acts as a burning rate modifier, and the smaller the larger is the burning rate. Three types of delay composition used in this study show characteristic burning behavior. A stoichiomertric or a oxidizer-rich composition has a small linear burning rate. although it is has a large heat of combustion. On the other hand, a tungsten-excess or a fuel-rich composition with a small heat of combustion has a larger linear burning rate than the former, showing a small fractional oxidation of tungeten (below 10%) contained in the delay powder. From these results, a surface combustion mechanism is proposed for the combustion mechanism of this delay powder.

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.3
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• pp.142-148
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• 2009

The direct injection(DI) diesel engine has become a prime candidate for future transportation needs because of its high thermal efficiency. However, nitrogen oxides(NOx) increase in the local high temperature regions and particulate matter (PM) increases in the diffusion flame region within diesel combustion. Therefore, the demand for developing a suitable after treatment device has been increased. NOx absorbing catalysts are based on the concept of NOx storage and release making it possible to reduce NOx emission in net oxidizing gas conditions. This De-NOx system, called the LNT(Lean NOx Trap) catalyst, absorbs NOx in lean exhaust gas conditions and release it in rich conditions. This technology can give high NOx conversion efficiency, but the right amount of reducing agent should be supplied into the catalytic converter at the right time. In this research, a performance characteristics of LNT with a hydrogen enriched gas as a reductant was examined and strategies of controlling the injection and rich exhaust gas condition were studied. The NOx reduction efficiency is closely connected to the injection timing and duration of reductant. LNT can reduce NOx efficiently with only 1 % fuel penalty.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.97-100
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• 2011

It is critical to set up the starting sequence of liquid rocket engines because not carefully arranged process can lead the engine damages. Thus, many efforts were made to prevent the hard start at the ignition. Hypergolic fuels are frequently used to ignite LRE and TEAL, one of the hypergolic fuel is also used for kerosene-LOx LRE ignition. However, since we are still lack of experiences igniting oxygen rich preburners of the staged combustion cycle engines, it would be helpful to estimate the TEAL ignition phenomena before the actual tests.

• Journal of ILASS-Korea
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• v.24 no.4
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• pp.157-162
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• 2019

This numerical study was analyzed to predict the flammability limits of biodiesel and diesel fuels in the high temperature and pressure conditions. To achieve this, the biodiesel fuel was simulated with the chemical species of n-heptane (n-C₇H₁₆), methyl decanoate (C₁₁H₂₂O₂), and methyl-9-decenoate (C₁₁H₂₀O₂), and the diesel fuel was substituted the chemical species of n-heptane. The closed 0-D homogeneous reactor model which was employed the 1100 K of ambient temperature and 35 atm of ambient pressure was used for the simulation of constant volume combustion, and the equivalence ratio was changed from 0.3 to 2.5 conditions. In addition, a comparative analysis study was conducted with the results of HCCI engine simulation and flammability limits according to the changes of equivalence ratio. The results of combustion temperature, pressure, and ignition delay were increased when the equivalence ratio elevated from 0.3 to 1.3 conditions because the increase in fuel oxidation rate affects the chemical reaction of the overall combustion process. Furthermore, the CO and NO_X production under the rich combustion conditions are considered to have a trade off relationship since the OH radicals and O₂ chemical species are greatly affected the CO and NO_X production and oxidation processes.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.5
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• pp.125-131
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• 2018

Some propellants in a liquid rocket engine are burned in the pre-burner of a staged combustion cycle engine, resulting hot gas drives the turbine. The burned gas passing through the turbine is supplied to the combustor at high temperature and pressure. The form of the gas can be fuel rich or oxidizer rich dependent upon the mixture ratio or the engine scheme. When the cycle works at oxidizer-rich condition, the metal pipes composing the engine can be ignited or even exploded by an impact of very a small particle. In this study, we developed the powder combination and processes for an anti-oxidation coating through the analysis of various coating materials.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.3
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• pp.211-221
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• 2016

Waste salt generated from a pyro-processing for the recovery of uranium and transuranic elements has high volatility at vitrification temperature and low compatibility in conventional waste glasses. For this reason, KAERI (Korea Atomic Energy Research Institute) suggested a new method to de-chlorinate waste salt by using an inorganic composite named SAP ($SiO_2-Al_2O_3-P_2O_5$). In this study, the de-chlorination behavior of waste salt and the microstructure of consolidated form were examined by adding $B_2O_3$ and $Fe_2O_3$ to the original SAP composition. De-chlorination behavior of metal chloride waste was slightly changed with given compositions, compared with that of original SAP. In the consolidated forms, the phase separation between Si-rich phase and P-rich phase decreases with the amount of $Al_2O_3$ or $B_2O_3$ as a connecting agent between Si and P-rich phase. The results of PCT (Product Consistency Test) indicated that the leach-resistance of consolidated forms out of reference composition was lowered, even though the leach-resistance was higher than that of EA (Environmental Assessment) glass. From these results, it could be inferred that the change in the content of Al or B in U-SAP affected the microstructure and leach-resistance of consolidated form. Further studies related with correlation between composition and characteristics of wasteform are required for a better understanding.