DOI QR코드

DOI QR Code

A Prediction on the Flammability Limits of Biodiesel Fuel in the High Temperature and Pressure Conditions

고온·고압 조건에서 바이오디젤의 가연한계 예측

  • 임영찬 (공주대학교 기계공학과 대학원) ;
  • 정준우 (공주대학교 기계공학과 대학원) ;
  • 서현규 (공주대학교 기계자동차공학부)
  • Received : 2019.08.23
  • Accepted : 2019.10.21
  • Published : 2019.12.30

Abstract

This numerical study was analyzed to predict the flammability limits of biodiesel and diesel fuels in the high temperature and pressure conditions. To achieve this, the biodiesel fuel was simulated with the chemical species of n-heptane (n-C7H16), methyl decanoate (C11H22O2), and methyl-9-decenoate (C11H20O2), and the diesel fuel was substituted the chemical species of n-heptane. The closed 0-D homogeneous reactor model which was employed the 1100 K of ambient temperature and 35 atm of ambient pressure was used for the simulation of constant volume combustion, and the equivalence ratio was changed from 0.3 to 2.5 conditions. In addition, a comparative analysis study was conducted with the results of HCCI engine simulation and flammability limits according to the changes of equivalence ratio. The results of combustion temperature, pressure, and ignition delay were increased when the equivalence ratio elevated from 0.3 to 1.3 conditions because the increase in fuel oxidation rate affects the chemical reaction of the overall combustion process. Furthermore, the CO and NOX production under the rich combustion conditions are considered to have a trade off relationship since the OH radicals and O2 chemical species are greatly affected the CO and NOX production and oxidation processes.

Keywords

References

  1. J. P. Cha, S. H. Park, C. S. Lee, S. W. Park, "Study on Spray and Exhaust Emission Characteristics of DME-Biodiesel Blended Fuel in Compression Ignition Engine", Trans. Korean Soc. Mech. Eng. B, Vol. 35, No. 1, 2011, pp. 67-73.
  2. S. H. Park, S. H. Yoon, J. P. Cha, C. S. Lee, "Mixing effects of biogas and dimethyl ether (DME) on combustion and emission characteristics of DME fueled high-speed diesel engine", Energy, Vol. 66, 2014, pp. 413-422. https://doi.org/10.1016/j.energy.2014.02.007
  3. H. K. Suh, C. S. Lee, "A review on atomization and exhaust emissions of a biodiesel-fueled compression ignition engine", Renewable and Sustainable Energy Reviews, Vol. 58, 2016, pp. 1601-1620. https://doi.org/10.1016/j.rser.2015.12.329
  4. A. Zehni, R. Khoshbakhti Saray, K. Poorghasemi, "Numerical comparison of PCCI combustion and emission of diesel and biodiesel fuels at low load conditions using 3D-CFD models coupled with chemical kinetics", Applied Thermal Engineering, Vol. 110, 2017, pp. 1483-1499. https://doi.org/10.1016/j.applthermaleng.2016.09.056
  5. H. J. Kim, K. S. Lee, C. S. Lee, "A study on the reduction of exhaust emissions through HCCI combustion by using a narrow spray angle and advanced injection timing in a DME engine", Fuel Processing Technology, Vol. 92, 2011, pp. 1756-1763. https://doi.org/10.1016/j.fuproc.2011.04.024
  6. Y. Putrasari, N. Jamsran, O. T. Lim, "An investigation on the DME HCCI autoignition under EGR and boosted operation", Fuel, Vol. 200, 2017, pp. 447-457. https://doi.org/10.1016/j.fuel.2017.03.074
  7. A. Nalgundwar, B. Paul, S. K. Sharma, "Comparison of performance and emissions characteristics of DI CI engine fueled with dual biodiesel blends of palm and jatropha", Fuel, Vol. 173, 2016, pp. 172-179. https://doi.org/10.1016/j.fuel.2016.01.022
  8. G. Singh, A. P. Singh, A. K. Agarwal, "Experimental investigations of combustion, performance and emission characterization of biodiesel fuelled HCCI engine using external mixture formation technique", Sustainable Energy Technologies and Assessments, Vol. 6, 2014, pp. 116-128. https://doi.org/10.1016/j.seta.2014.01.002
  9. P. Kumar, A. Rehman, "Bio-diesel in homogeneous charge compression ignition (HCCI) combustion", Renewable and Sustainable Energy Reviews, Vol. 56, 2016, pp. 536-550. https://doi.org/10.1016/j.rser.2015.11.088
  10. J. A. Velez Godino, F. J. Jimenez-Espadafor Aguilar, M. Torres Garcia, "Simulation of HCCI combustion in aircooled off-road engines fuelled with diesel and biodiesel", Journal of the Energy Institute, Vol. 91, 2018, pp. 549-562. https://doi.org/10.1016/j.joei.2017.04.002
  11. O. Herbinet, W. J. Pitz, C. K. Westbrook, "Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate", Combustion and Flame, Vol. 157, 2010, pp. 893-908. https://doi.org/10.1016/j.combustflame.2009.10.013
  12. Y. C. Lim, H. K. Suh and S. H. Yoon, "Prediction of Biodiesel Homogeneous Combustion and Flammability Limits in Compression Ignition Condition", Trans. Korean Soc. Mech. Eng. B, Vol. 42, No. 11, 2018, pp. 711-719. https://doi.org/10.3795/ksme-b.2018.42.11.711
  13. Y. C. Lim, H. K. Suh, "Study on the Combustion Chemical Reaction of Biodiesel Fuel for the Improvement of Compression Ignition Combustion Performance", ASME 2017 Internal Combustion Engine Division Fall Technical Conference, 2017, ICEF 2017-3565.
  14. Y. C. Lim, J. W. Jung, H. K. Suh, "Homogeneous Combustion Characteristics of Surrogate Fuels in Compression Ignition Conditions", Asia-Pacific Conference on Combustion, 2019, ASPACC2019-1350.
  15. J. H. Song, K. J. Kang, S. H. Ryu, G. M. Choi and D. J. Kim, "Observation on the Ignition Delay Time of Cool and Thermal Flame of n-heptane/alcohol Blended Fuel at Low Temperature Combustion Regime", J. Korean Soc. Combust., Vol. 18, No. 4, 2013, pp. 12-20. https://doi.org/10.15231/jksc.2013.18.4.012
  16. H. J. Curran, "Developing detailed chemical kinetic mechanisms for fuel combustion", Proceedings of the Combustion Institute, Vol. 37, 2019, pp. 57-81. https://doi.org/10.1016/j.proci.2018.06.054
  17. J. W. Jung, Y. C. Lim, H. K. Suh, "A Study on the $NO_X$ Formation Characteristics and Detailed Chemical Reaction Pathways of Biodiesel in the Various Ambient Conditions", J. Korean Soc. Combust., Vol. 22, No. 1, 2018, pp. 1-8. https://doi.org/10.15231/jksc.2017.22.1.001