• Title/Summary/Keyword: Fuel substitution

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Prediction of Critical Heat Flux in Fuel Assemblies Using a CHF Table Method

  • Chun, Tae-Hyun;Hwang, Dae-Hyun;Bang, Je-Geon;Baek, Won-Pil;Chang, Soon-Heung
    • Proceedings of the Korean Nuclear Society Conference
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    • 1997.10a
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    • pp.534-539
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    • 1997
  • A CHF table method has been assessed in this study for rod bundle CHF predictions. At the conceptual design stage for a new reactor, a general critical heat flux (CHF) prediction method with a wide applicable range and reasonable accuracy is essential to the thermal-hydraulic design and safety analysis. In many aspects, a CHF table method (i.e., the use of a round tube CHF table with appropriate bundle correction factors) can be a promising way to fulfill this need. So the assessment of the CHF table method has been performed with the bundle CHF data relevant to pressurized water reactors (PWRs). For comparison purposes, W-3R and EPRI-1 were also applied to the same data base. Data analysis has been conducted with the subchannel code COBRA-IV-I. The CHF table method shows the best predictions based on the direct substitution method. Improvements of the bundle correction factors, especially for the spacer grid and cold wall effects, are desirable for better predictions. Though the present assessment is somewhat limited in both fuel geometries and operating conditions, the CHF table method clearly shows potential to be a general CHF predictor.

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Organic-inorganic Nano Composite Membranes of Sulfonated Poly(Ether Sulfone-ketone) Copolymer and $SiO_2$ for Fuel Cell Application

  • Lee, Dong-Hoon;Park, Hye-Suk;Seo, Dong-Wan;Kim, Whan-Gi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.487-488
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    • 2006
  • Novel bisphenol-based wholly aromatic poly(ether sulfone-ketone) copolymer containing pendant sulfonate groups were prepared by direct aromatic nucleophilic substitution polycondensation of 4,4-difluorobenzophenone, 2,2'-disodiumsulfonyl-4,4'-fluorophenylsulfone (40mole% of bisphenol A) and bisphenol A. Polymerization proceeded quantitatively to high molecular weight in N-methyl-2-pyrrolidinone at $180^{\circ}C$. Organic-inorganic composite membranes were obtained by mixing organic polymers with hydrophilic $SiO_2$ (ca. 20nm) obtained by sol-gel process. The polymer and a series of composite membranes were studied by FT-IR, $^1HNMR$, differential scanning calorimetry (DSC) and thermal stability. The proton conductivity as a function of temperature decreased as $SiO_2$ content increased, but methanol permeability decreased. The nano composite membranes were found to posse all requisite properties; Ion exchange capacity (1.2meq./g), glass transition temperatures $(164-183\;^{\circ}C)$, and low affinity towards methanol $(4.63-1.08{\times}10^{-7}\;cm^2/S)$.

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Safety margin and fuel cycle period enhancements of VVER-1000 nuclear reactor using water/silver nanofluid

  • Saadati, Hassan;Hadad, Kamal;Rabiee, Ataollah
    • Nuclear Engineering and Technology
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    • v.50 no.5
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    • pp.639-647
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    • 2018
  • In this study, the effects of selecting water/silver nanofluid as both a coolant and a reactivity controller during the first operating cycle of a light water nuclear reactor are investigated. To achieve this, coupled neutronic-thermo-hydraulic analysis is employed to simulate the reactor core. A detailed VVER1000/446 reactor core is modeled in monte carlo code (MCNP), and the model is verified using the porous media approach. Results show that the maximum required level of silver nanoparticles is 1.3 Vol.% at the beginning of the cycle; this value drops to zero at the end of cycle. Due to substitution of water/boric acid with water/Ag nanofluid, reactor operation time at maximum power extends to 357.3 days, and the energy generation increases by about 27.3%. The higher negative coolant temperature coefficient of reactivity in the presence of nanofluid in comparison with the water/boric acid indicates that the reactor is inherently safer. Considering the safety margins in the presence of the nanofluid, minimum departure from nucleate boiling ratio is calculated to be 2.16 (recommendation is 1.75).

A Numerical Study on the Structural Stability Optimization of the Core Components of a 17cc Automotive Compressor (17cc급 자동차용 압축기 핵심부품의 구조 안정성에 관한 수치적 연구)

  • Yang, Yong-Kun;Wu, Yu-Ting;Qin, Zhen;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.5
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    • pp.69-75
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    • 2021
  • Fuel economy has always been a major issue for the automotive industry due to environmental concerns. In particular, it is known that only 5-20% of the energy generated in a car that mainly uses an internal combustion engine is converted to increase fuel efficiency, many methods have been proposed. Among these methods, weight reduction is most commonly used because it is the simplest and cheapest. Weight is always the main reason for energy consumption, therefore, reducing weight is the best way to increase fuel efficiency while simultaneously saving on material costs. To reduce the weight of a compressor, material substitution is used. However, aluminum (a lighter metal substitute) is more fragile than steel, therefore, structural stability must be verified through testing. In this paper, we performed a 3D analysis to investigate whether aluminum can be used without compromising structural stability. Our investigation included static analysis and thermal analysis. As a result, we found that an aluminum swash plate can be safely applied on a shaft instead of steel; it reduces weight while maintaining stability that is equal to or better than steel.

Characteristics of Sr0.92Y0.08Ti1-xVxO3-δ (x = 0.01, 0.04, 0.07, 0.12) Anode for Using H2S Containing Fuel in Solid Oxide Fuel Cells (H2S를 포함하는 연료를 사용하기 위한 고체산화물 연료전지용 Sr0.92Y0.08Ti1-xVxO3-δ 연료극 특성)

  • Jang, Geun Young;Kim, Jun Ho;Mo, Su In;Park, Gwang Seon;Yun, Jeong Woo
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.557-564
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    • 2021
  • Sr0.92Y0.08Ti1-xVxO3-δ (SYTV) with perovskite structure was investigated as an alternative anode to utilize H2S containing fuels in solid oxide fuel cells. To improve the electrochemical performance of Sr0.92Y0.08TiO3-δ (SYT), vanadium(V) was substituted to titanium(Ti) at the B-site of the SYT perovskites. The SYTV synthesized by the Pechini method was chemically compatible with the YSZ electrolyte without additional by-products formation under the cell fabricating conditions. As increasing V substitution amounts, the oxygen vacancies increased, resulting to increasing ionic conductivity of the anode. The cell performance in pure H2 at 850 ℃ is 19.30 mW/cm2 and 34.87 mW/cm2 for a 1 mol.% and 7 mol.% of V substituted anodes, respectively. The cell performance using H2 fuel containing 1000 ppm of H2S at 850 ℃ was 23.37 mW/cm2 and 73.11 mW/cm2 for a 1 mol.% and 7 mol.% of V substituted anodes, respectively.

Studies of Co-Fe based perovskite cathodes with fixed A-site cations (중 저온형 고체 산화물 연료전지를 Co-Mn 계열의 페로브스카이트 구조의 공기극에 관한 연구)

  • Park, Kwang-Jin;Kim, Jung-Hyun;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.364-367
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    • 2006
  • The decrease of polarization resistance in cathode is the key point for intermediate temperature SOFC(Solid Oxide Fuel Cell). In this study, the Influence of Co substitution in B-site at perovskite PSCM (Pr0.3Sr0.7CoxMn(1-x)) was investigated. The PSCM series exhibits excellent MIEC(Mixed ionic Electronic Conductor) properties. The ASR(Area Specific Resistance) of PSCM3773 was $0.174{\Omega}cm^2\;at\;700^{\circ}C$. The activation energy of PSCM3773 was also lower than other compositions of PSCM. The ASR values were increased gradually during the thermal cycling test of PSCM37773 due to the delamination between electrolyte and cathode materials.

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Analysis on Economic Feasibility of Electric Night Storage Heat Pump as a Substitution of a Heater (심야전기보일러 대체 Heat Pump의 경제성 분석)

  • JUNG, H.;JO, J.Y.;Lee, C.H.
    • Journal of the Korean Society of Mechanical Technology
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    • v.13 no.3
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    • pp.119-124
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    • 2011
  • Electric night storage heater was introduced and disseminated for power grid balancing and efficient management of power generation facility. But fuel cost for heating has been increased rapidly while the cost of electricity increased slightly. This abnormal rate system caused peak load in winter at last. To solve this problem, application of an air source heat pump was suggested. In the study, the effect of replacing night heater by heat pump and the economics were analysed. In addition the expectation of prospect of heat pump penetration was simulated based on surveyed and investigated data. As a result, fund supporting as well as institutional backing was needed for effective propagation and return of investment.

First-Principles Study on Thermodynamic Stability of UO2 with He Gas Incorporation via Alpha-Decay

  • Kwon, Choa;Lee, Kwanpyung;Han, Byungchan
    • Korean Chemical Engineering Research
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    • v.57 no.3
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    • pp.368-371
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    • 2019
  • Using first principles calculations we investigated the thermomechanical stability of spent nuclear fuels (SNF), especially how mechanical properties of $UO_2$, such as, bulk, shear and Young's moduli and Poisson's ratio vary through alpha-decay of U into Th with generation of He gas. Our results indicate that substitution of U by Th through alpha decay ($U_{1-x}Th_xO_2$) does not significantly affect the stability of the grain in a fuel matrix. In addition, we studied the transport properties of He in and boundaries of the $U_{1-x}Th_xO_2$ grain. Helium preferentially resides at the grain boundaries through diffusion. Our study can contribute to substantial reduction of environmentally risk and enhancement of our sustainability by safe control of radioactive materials.

Green Infrastructure Types and Effects for Climate Change (기후변화 대응을 위한 녹색기반시설의 유형과 효과)

  • Kim, Seung Hyun
    • Journal of Climate Change Research
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    • v.2 no.3
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    • pp.191-201
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    • 2011
  • This study investigates how green infrastructure, including natural and open space such as forests, rivers, parks, and streets, could effectively counteract climate change in terms of mitigation and adaption, respectively. As a result, green infrastructure, such as forests, parks, vegetable gardens, roof gardens, pedestrian walkways, bike lanes, etc, could effectively mitigate climate change: 1) Carbon storage and sequestration; 2) Fossil fuel substitution; 3) Material substitution; 4) Food production 5) Reducing the need to travel by car. Secondly, green infrastructure, such as rivers, tree-lined streets, farmland, wetlands, dunes, wind ways, etc, could adapt to climate change: 1) Managing high temperatures; 2) Managing water supply; 3) Managing ravine flooding; 4) Managing costal flooding; 5) Managing surface water; 6) Reducing soil erosion; 7) Helping other species to adapt.

A Study on Combustion and Emission Characteristics of a Diesel Engine Fuelled with Pyrolysis Oil-Ethanol and Pilot Diesel (바이오원유-에탄올/파일럿 디젤유 이종연료 혼소를 통한 디젤엔진의 연소 및 배출가스 특성에 관한 연구)

  • Kim, Min-Jae;Lee, Seok-Hwan;Cho, Jeong-Kwon;Yoon, Jun-Kyu;Lim, Jong-Han
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.420-427
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    • 2017
  • Recently, the depletion of fossil fuels, global warming and environmental pollution have emerged as a worldwide problem, and studies of new renewable energy sources have been progressed. Among the many renewable energy sources, the use of bio fuel has the potential to displace fossil fuels due to low price, easy to handle, and the abundant sources. Pyrolysis oil (PO) derived from waste wood and sawdust is considered an alternative fuel for use in diesel engines. On the other hand, PO is limited to diesel engines because of its low cetane number, high viscosity, high acidity, and low energy density. Therefore, to improve its poor properties, PO was mixed with alcohol fuels, such as ethanol. Early mixing with ethanol has the benefit of improving the storage and handling properties of the PO. Furthermore, a PO-ethanol blended fuel was injected separately, which can be fired through pilot-injected diesel in a dual-injection diesel engine. The experimental results showed that the substitution of diesel with blended fuel increases the amount of HC and CO, but reduces the NOx and PM significantly.