• Title/Summary/Keyword: Free molecular flow

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Analysis of rarefied compressible boundary layers in transition regime (천이영역의 희박기체 압축성 경계층 해석)

  • Choe, Seo-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.4
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    • pp.509-517
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    • 1997
  • Results of flat plate compressible boundary layer calculation, based on discrete formulation of DSMC method, are presented in low Mach number and low Knudsen number range. The free stream is a uniform flow of pure nitrogen at various Mach numbers in low pressures (i.e. rarefied gas). Complete thermal accommodation and diffuse molecular reflections are used as the wall boundary condition, replacing unreal no-slip condition used in continuum calculations. In the discrete formulation of DSMC method, there is no need to use ad hoc assumptions on transport properties like viscosity and thermal conductivity, instead viscosity is calculated from values of other field variables (velocity and shear stress). Also the results are compared with existing self-similar continuum solutions. In all Mach number cases computed, velocity slip is most pronounced in regions near the leading edge where continuum formulation renders the solution singular. As the boundary layer develops further downstream, velocity slips asymptote to values that are between 10 to 20% of the magnitude of free stream velocity. When the free stream number density is reduced, so the gas more rarefied, the velocity slip increases as expected.

Preparation and Electrochemical Applications of Pore-filled Ion-exchange Membranes with Well-adjusted Cross-linking Degrees: Part I. All Vanadium Redox Flow Battery (가교도가 조절된 세공충진 이온교환막의 제조 및 전기화학적 응용: Part I. 전 바나듐 레독스 흐름전지)

  • Lee, Ji-Eun;Park, Ye-Rin;Kim, Do-Hyeong;Kang, Moon-Sung
    • Membrane Journal
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    • v.27 no.5
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    • pp.406-414
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    • 2017
  • In this study, we have developed pore-filled ion-exchange membranes (PFIEMs) filled with ionomer in a thin polyethylene porous film (thickness = $25{\mu}m$) and investigated the charge-discharge characteristics of the all vanadium redox flow battery (VRFB) employing them. Especially, the degree of crosslinking and free volume of the PFIEMs were appropriately controlled to produce ion-exchange membranes exhibiting both the low membrane resistance and low vanadium permeability by mixing crosslinking agents having different molecular size. As a result, the prepared PFIEMs exhibited excellent electrochemical properties which are comparable to those of the commercial membranes. Also, it was confirmed through the experiments of vanadium ion permeability and VRFB performance evaluation that the PFIEMs showed low vanadium ion permeability and high charge-discharge efficiency in comparison with the commercial membrane despite their thin film thickness.

Tethered DNA shear dynamics in the flow gradient plane: application to double tethering

  • Lueth, Christopher A.;Shaqfeh, Eric S.G.
    • Korea-Australia Rheology Journal
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    • v.19 no.3
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    • pp.141-146
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    • 2007
  • We examine the wall contact of a $3\;{\mu}m$ tethered DNA chain's free end under shear with a focus on developing schemes for double-tethering in the application of making scaffolds for molecular wires. At this scale our results are found to be highly dependent on small length scale rigidity. Chain-end-wall contact frequency, mean fractional extension deficit upon contact, and standard deviation in extension upon contact are examined for scaling with dimensionless flow strength, Wi. Predictions made using a one dimensional approximation to the Smoluchowski equation for a dumbbell and three dimensional dumbbell simulations produce extension deficit, standard deviation, and frequency scaling exponents of -1/3, -1/3, and 2/3, respectively whereas more fine-grained Kratky-Porod (KP) simulations produce scaling exponents of -0.48, -0.42, and 0.76. The contact frequency scaling of 2/3 is derived from the known results regarding cyclic dynamics Analytical scaling predictions are in agreement with those previously proposed for ${\lambda}-DNA$. [Ladoux and Doyle, 2000, Doyle et al., 2000]. Our results suggest that the differences between the dumbbell and the KP model are associated with the addition of chain discretization and the correct bending potential in the latter. These scaling results will aide future exploration in double tethering of DNA to a surface.

Cashew Nut Oil: Extraction, Chromatographic and Rheological Characterisation.

  • Vincent Okechuwku ANIDIOBU;Chioma Oluchi ANIDIOBU
    • The Korean Journal of Food & Health Convergence
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    • v.9 no.4
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    • pp.11-18
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    • 2023
  • Oil was extracted from cashew nuts. The physicochemical parameters of the oil were determined. A chromatographic assay of the oil was carried out using Gas Chromatography-Mass Spectrometry. Seventeen compounds were detected: Phenol, Phenol 2-methyl-, Cyclohexene 4, 4-dimethyl-, m-Fluoro-2-diazoacetophenone 4-dimethyl-, Tetradecanoic acid, Phenol 4-octyl-, n-Hexadecanoic acid. Others are 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Hexadecanoic acid methyl ester, Methyl stearate, Dodecanoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid methyl ester, 9, 12, 15-Octadecatrienoic acid (Z, Z, Z)-, Oleic acid, Octadecanoic acid, Tetracosanoic acid and 9-Octadecenoic acid methyl ester. Among the components are omega three and omega six essential free fatty acids. The rheological profiling and flow properties of cashew nut oil were determined using a Programmable Rheometer. Cashew nut oil exhibits slight dilatant behaviour at the low end of shear rate. The long chain and high molecular weight of its constituents controlled its rheology. Long-chained 9-Octadecenoic acid methyl ester, 9, 12-Octadecadienoic acid (Z, Z) - methyl ester, Tetracosanoic acid and methyl stearate, coupled with their high molecular weights are responsible for the shear thickening effect observed. Two models, Carreau-Yasuda and Ostwald-de Waele Power Law were employed to fit the rheological data. The Carreau-Yasuda model followed well the data.

Efficiency Analysis of Thermal Transpiration According to Knudsen Number for Application to Micro-propulsion System (마이크로 추진장치에 적용을 위한 누센수에 따른 열적발산원리의 효율분석)

  • Jung, Sung-Chul;Huh, Hwan-Il
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.36 no.5
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    • pp.483-490
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    • 2008
  • Minimization of nozzle induces many flow losses in micro-propulsion system. In this study, we studied about thermal transpiration based micro propulsion system to overcome these losses. Thermal transpiration device(Knudsen pump) having no moving parts can self-pump the gaseous propellant by temperature gradient only (cold to hot). We designed, fabricated the Knudsen pump and analyzed pressure gradient efficiency of membrane according to Knudsen number under vacuum condition. Experimental results showed that thick membranes are more effective than thin membranes in transition flow regime, and pressure gradient efficiency according to Knudsen number is increased to maximum 82% apart from membrane thickness in free molecular regime.

The Effect on Performance of Disk-type Drag Pump Channel-type (원판형 드래그펌프 채널형상의 성능에 미치는 영향)

  • Kwon, Myoung-Keun;Lee, Seung-Jae;Hwang, Young-Kyu
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.816-821
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    • 2003
  • The pumping characteristics of a disk-type drag pump (DTDP) from free molecular flow region to the slip flow region are calculated by the direct simulation Monte Carlo (DSMC) method. In this study, the pumping performance is studied numerically for several channel depths. The interaction between molecules is modeled by variable hard-sphere (VHS). The no time counter method is used as a collision sampling technique. The clearance between rotor and stator is considered an effect on performance. Spiral channels are cut on both upper and lower sides of rotating disks, and stationary disks are planar. A three-dimensional DSMC method for the analysis of steady rarefied flows in a single-stage DTDP has been developed. Velocity and density fields were obtained by the DSMC simulation in the rotor. The present experimental data in the outlet pressure range of $7.5{\times}10^{-3}{\sim}4$ Torr were compared with the DSMC results in the single-stage DTDP. Comparison between the experimental data and DSMC results showed good agreement.

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Mechanical Dilation of the Recipient Vessel with the DeBakey Vascular Dilator in Lower Extremity Reconstruction: A Report of Two Cases

  • Min-Gi Seo;Tae-Gon Kim
    • Archives of Plastic Surgery
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    • v.50 no.3
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    • pp.311-314
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    • 2023
  • In lower extremity reconstruction, the recipient vessel often requires long-range mechanical dilation because of extensive vasospasm or plaque formation induced by concomitant atherosclerosis. While a forceps dilator can be used to manipulate and dilate vessels approximately 1 cm from their end, a DeBakey vascular dilator can dilate long-range vessels. The authors successfully performed free flap reconstruction of the lower extremity using the DeBakey vascular dilator. Of the two patients who underwent lower extremity reconstruction, one had extensive vasospasm, and the other had plaques in the recipient arteries. Irrigation with 4% lidocaine and dilation of the lumen with a forceps dilator were insufficient to restore the normal arterial blood flow. Instead, a DeBakey vascular dilator with a 1-mm diameter tip was gently inserted into the lumen. Then, to overcome vessel resistance, the dilator gently advanced approximately 10 cm to dilate the recipient artery. Normal arterial blood flow was gushed out after dilating the vessel lumen using a DeBakey vascular dilator. The vascular anastomosis was performed, and intravenous heparin 5000 IU was administered immediately after anastomosis. Prophylactic low-molecular-weight-heparin (Clexane, 1 mg/kg) was administered subcutaneously to both patients for 14 days. The reconstructed flap survived without necrosis in either patient.

Effects of Gas-surface Interaction Models on Spacecraft Aerodynamics

  • Khlopkov, Yuri Ivanovich;Chernyshev, Sergey Leonidovich;Myint, Zay Yar Myo;Khlopkov, Anton Yurievich
    • International Journal of Aeronautical and Space Sciences
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    • v.17 no.1
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    • pp.1-7
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    • 2016
  • The influence of boundary condition of the bodies with gas flows is one of the most important problems in high-altitude aerodynamics. In this paper presents the results of the calculation of aerodynamic characteristics of aerospace vehicle using Monte-Carlo method based on three different gas-surface interaction models - Maxwell model, Cercignani-Lampis-Lord (CLL) model and Lennard-Jones (LJ) potential. These models are very sensitive for force and moment coefficients of aerospace vehicle in the hypersonic free molecular flow. The models, method and results can be used for new generation aerospace vehicle design.

Pressure Dependence of the Viscosity of Toluene (톨루엔의 점성도에 대한 압력 의존성)

  • Kim, Jeong Rim
    • Journal of the Korean Chemical Society
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    • v.43 no.3
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    • pp.251-256
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    • 1999
  • Viscosities of toluene were experimentally determined by the falling-ball method at several temperatures and pressures to investigate the pressure and temperature dependence of the viscosity of toluene. With the shear stress of the viscous flow of toluene, the shear free energy, the shear entropy, and the shear enthalpy were defined to discuss the variations of the shear thermodynamic properties with pressure. The effect of temperature and pressure on the shear thermodynamic properties obtained experimentally can be explained by means of the molecular thermal agitation due to temperature incleasing and the steric effect of the closed molecules of to Iuene due to pressure elevation.

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Property Control in a Continuous MMA Polymerization Reactor using EKF based Nonlinear Model Predictive Controller

  • Ahn, Sung-Mo;Park, Myung-June;Rhee, Hyun-Ku
    • 제어로봇시스템학회:학술대회논문집
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    • 1998.10a
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    • pp.468-473
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    • 1998
  • A mathematical model was developed for a continuous re-actor in which free radical polymerization of methyl methacrylate (MMA) occurred. Elementary reactions considered in this study were initiation, propagation, termination, and chain transfers to monomer and solvent. The reactor model took into account the density change of the reactor contents and the gel effect. A control system was designed for a continuous reactor using extended Kalman filter (EKF) based non-linear model predictive controller (NLMPC) to control the conversion and the weight average molecular weight of the polymer product. Control input variables were the jacket inlet temperature and the feed flow rate. For the purpose of validation of the control strategy, on-line digital control experiments were conducted with densitometer and viscometer for the measurement of the polymer properties. Despite the com-plex and nonlinear features of the polymerization reaction system, the EKF based NLMPC performed quite satisfactorily for the property control of the continuous polymerization reactor.

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