• Title/Summary/Keyword: Free fraction

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The Effects of Insoluble Polymers on Water Stability of Carbon Fiber Reinforced Polymer-MDF Cementitious Composites (불용성 폴리머가 탄소섬유 보강 Polymer-MDF 시멘트 복합재료의 기계적 특성에 미치는 영향)

  • 김태진;박춘근
    • Composites Research
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    • v.12 no.3
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    • pp.84-90
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    • 1999
  • High alumina cement(HAC) and polyvinyl alcohol(PVA) based macro-defect-free(MDF) cement composites were reinforced using short carbon fibers, 3mm in length, 1-4% in weight fraction and insoluble polymers such as polyurethane, epoxy, phenol resin, in order to increase mechanical properties and water stability. The specimens were manufactured by the low heat-press(warmpress) method. In addition, the interface and the cross-linking reaction of cement and polymers was also studied by the SEM and TEM. Flexural strength of HAC/PVA based MDF cementitious composites was proportionally decreased with increasing fiber contents due to the undensified structure around fibers. The flexural strength of insoluble polymer added specimen was decreased with increasing fiber contents, while water stability was dramatically improved. Epoxy resin added specimen showed the highest strength with increasing fiber contents, compared with other specimens. The water stability of fiber content 4% added specimen immersed in water presented about 95%, 87% at 3 and 7 days immersed in water, respectively. The interfacial adhesive strength of fiber-matrix was very much improved due to cross linking reaction of polymer and metal ions of cement. Tensile strength of insoluble polymers added composites as linearly increased with increasing the fiber contents. The epoxy resin added specimen also showed highest tensile strength. The 4% fiber added specimen presented 30~80% higher strength than controlled specimen.

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Patterns of Failure According to Radiation Treatment Technique in the Parotid Gland Cancer (이하선암의 술후 방사선치료시 방사선치료 방법에 따른 치료 실패 양상 분석)

  • Lee Sang-Wook;Lee Chang-Geol;Keum Ki-Chang;Park Cheong-Soo;Choi Eun-Chang;Shin Hyun-Soo;Chu Sung-Sil;Lee Suk;Cho Kwang-Hwan;Suh Chang-Ok;Kim Gwi-Eon
    • Korean Journal of Head & Neck Oncology
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    • v.16 no.2
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    • pp.167-171
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    • 2000
  • Objectives: To compare the outcomes of treatment with a focus on the effectiveness of the two primary techniques of radiation used for treating parotid gland malignancies. Materials and Methods: A retrospective analysis of 70 patients with parotid gland cancer treated between 1981-1997. Radiation was delivered through an ipsilateral field of high energy electron and photon in 37 patients(52.9%). Two wedge paired photon was used to treat in 33 patients(47.1%). The median dose was 60 Gy, typically delivered at 1.8-2.0Gy per fraction. The median follow-up times for surviving patients was 60 months. Results: The overall and disease free 5 year survival rates were 71.6% and 69.5%, respectively. Wedge paired photon and photon-electron treatment disease tree 5 year survival rates were 61.1% and 80.5%, respectively. Overall local failure rate was 18.6%. Local failure rate of wedge paired photon technique was higher than that of mixed beam technique. Late complication rate was 37.1%, but most of them were mild grade. Conclusion: Techniques of radiation were associated with local control. The technique of using an ipsilateral field encompassing the parotid bed and treated with high energy electrons often mixed photons was effective with minimal severe late toxicity. To irradiate deep sited tumors, we consider 3-D conformal treatment plan for well encompassing the target volume.

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Hydrolysis of Agricultural Residues and Kraft Pulps by Xylanolytic Enzymes from Alkaliphilic Bacillus sp. Strain BK

  • Kaewintajuk Kusuma;Chon Gil-Hyong;Lee Jin-Sang;Kongkiattikajorn Jirasak;Ratanakhanokchai Khanok;Kyu Khin Lay;Lee John-Hwa;Roh Min-Suk;Choi Yun-Young;Park Hyun;Lee Yun-Sik
    • Journal of Microbiology and Biotechnology
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    • v.16 no.8
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    • pp.1255-1261
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    • 2006
  • An alkaliphilic bacterium, Bacillus sp. strain BK, was found to produce extracellular cellulase-free xylanolytic enzymes with xylan-binding activity. Since the pellet-bound xylanase is eluted with 2% TEA from the pellet of the culture, they contain a xylan-binding region that is stronger than the xylan-binding xylanase of the extracellular enzyme. The xylanases had a different molecular weight and xylan-binding ability. The enzyme activity of xylanase in the extracellular fraction was 6 times higher than in the pellet-bound enzyme. Among the enzymes, xylanase had the highest enzyme activity. When Bacillus sp. strain BK was grown in pH 10.5 alkaline medium containing xylan as the sole carbon source, the bacterium produced xylanase, arabinofuranosidase, acetyl esterase, and $\beta$-xylosidase with specific activities of 1.23, 0.11, 0.06, and 0.04 unit per mg of protein, respectively. However, there was no cellulase activity detected in the crude enzyme preparation. The hydrolysis of agricultural residues and kraft pulps by the xylanolytic enzymes was examined at 50$^{\circ}C$ and pH 7.0. The rate of xylan hydrolysis in com hull was higher than those of sugarcane bagasse, rice straw, com cop, rice husk, and rice bran. In contrast, the rate of xylan hydrolysis in sugarcane pulp was 2.01 and 3.52 times higher than those of eucalyptus and pine pulp, respectively. In conclusion, this enzyme can be used to hydrolyze xylan in agricultural residues and kraft pulps to breach and regenerate paper from recycled environmental resources.

Interpretation of Protein Feed Degradation Pattern in Ruminant Using an Omasal Digesta Sampling Technique (제 3위 소화액 채취기법을 이용한 반추위 단백질 사료 분해 패턴 측정법의 고찰)

  • 최창원;백경훈;강수원;이병석;오영균;김경훈
    • Journal of Animal Science and Technology
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    • v.48 no.4
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    • pp.541-554
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    • 2006
  • Present review is to introduce an omasal sampling technique in rumen proteolysis and to consider some information on the omasal sampling technique with particular emphasis on methodological aspects. Use of the omasal sampling technique provides a new opportunity for accurate estimation of rumen metabolism with overcoming limitations of previous in vivo, in vitro and/or in situ methods. The potential advantages of the present technique compared with post-ruminal sampling techniques include following points; 1) only rumen cannulated animals are required, 2) less endogenous nitrogen (N) is contaminated in omasal digesta and 3) omasal digesta are devoid of exposure to acid peptide hydrolysis occurring in the abomasum. Estimates of soluble non-ammonia N (SNAN) in omasal digesta indicate that the assumptions underlying the in situ method that rapidly degradable N fraction can be degraded at an infinite rate and only insoluble dietary N escapes the rumen may be not valid. Quatitatively higher peptide concentration rather than free amino acid and soluble protein in escapable SNAN suggests that hydrolysis of peptide to amino acid may be the rate-limiting step in rumen proteolysis.

In vitro Inhibitory Effect of Colored Rice Bran Extracts Carcinogenicity (유색미 쌀겨추출물의 in vitro의 발암 억제효과)

  • Kang, Mi-Young;Nam, Seok-Hyun
    • Applied Biological Chemistry
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    • v.40 no.4
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    • pp.307-312
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    • 1997
  • As a preliminary experiment to investigate the antitumor activity of colored rice in vivo, inhibitory effect of solvent extracts from colored rice brans on DNA strand scission and tumor promotion was examined in vitro. Two colored rice cultivars, Sanghaehyanghyulla and Suwon 415 were compared with Chuchung as a control. The antimutagenic activity of each rice cultivars increased in order of Chuchung

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Evaluation of Filter-Adsorber(F/A) Process for Removal of Disinfection By-products(DBPs) (소독부산물 제어를 위한 실공정 F/A 운영에 관한 고찰)

  • Kim, Seong-Su;Lee, Kyung-Hyuk;Lim, Jae-Lim;Chae, Seon-Ha;Kang, Byeong-Soo;Moon, Pil-Joong;Ahn, Hyo-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.10
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    • pp.1035-1042
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    • 2005
  • Granular Activated Carbon(GAC) is widely used in drinking water treatment. At S and B Water Treatment Plant, GAC is used in place of granular media in conventional rapid filters(GAC Filter-Adsorber) for removal of Disinfection By-products(DBPs). The primary focus of this study is on the performance of existing filter-adsorber, and their operation. It was found that F/A process removed turbidity as effective as sand system. The ratio of Hydrophobic DOM (HPO) and hydrophilic DOM (HPI) fraction in the raw water at S and B WTP was similar. Filter Adsorber presented earlier DOC breakthrough and steady state condition which was contributed by biodegradation during operation period. The removal efficiency of DBPs were used to evaluate the filter performance. The DBPs concentration of F/A treated water was below treatment goal level (THM < $80\;{\mu}g/L$, HAA < $60{\mu}g/L$). The removal efficiency of THM decreased rapidly during operation period. However, HAA were removed steadily regardless of the influent concentration of HAA. These results indicate that the removal of THM depend upon the adsorption mechanism while the removal of HAA depend upon biodegradation as well as adsorption. The decrease of adsorption capacity and characteristic value of GAC may be attributed to the effect of high organic loading, residual free chlorine, coagulants, manganese oxidants and frequently backwashing. This study has confirmed that Filter adsorber process can be considered as effective alternatives for the removal of DBPs, especially HAA.

Analysis of Occupational Disease Caused by Oral Health Behavior of Some Dental Hygiene Students (일부 치위생과 학생의 구강건강행위와 구강병 발생요인 간의 관계)

  • Lim, Soon-Hwan;Hwang, Ji-Min
    • The Journal of the Korea Contents Association
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    • v.18 no.3
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    • pp.256-264
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    • 2018
  • The purpose of this study was to investigate the relationship between oral health behaviors and the results of the oral dysentery test for dental hygienists and students at Gyeonggi - do and Chungcheongnam - do. Self - filling questionnaires and oral diseases. The following conclusions were obtained. The most common toothbrushing frequency was three times a day (60.2%), and the most dominant frequency of eating between meals was once or less(49.7%). The most common snack that they had was stickiness-free sweetened food(66.5%), and the type of beverage that they had the most was sweetened beverages(49.7%). The average stimulated saliva flow rate was 9.41ml, and they got a mean of 9.52 in the buffering capacity of saliva. The average glucose clearance time was a mean of 12.02. When they took a streptococcus mutans colony count test, 80.1 percent belonged to the low-risk group(<$10^5$), and 82.6 percent belonged to the low-risk group(<$10^5$) when a lactobacillus test was conducted. There was a positive correlation between the irritant saliva fraction and the non-irritating saliva and saliva buffering ability. In the fluoride application experience, the glucose retention time was 10.66 minutes and the fluoride application experience was 13.33 minutes. (P = .008). The importance of oral health, which is directly linked to general health, should be emphasized in order to improve the quality of life as well as the life expectancy. For oral health, which is directly linked to systemic health, it is necessary to provide opportunities for oral health education that can be easily accessed by the public, and to continuously develop and provide oral health care programs for a lifetime.

LASER SURFACE ANNEALING FOR IMPROVING HYDROGEN EMBRlTTLEMENT RESISTANCE OF AGED INCONEL 718: EVALUATION OF THE EFFECTS OF PRECIPITATES

  • Liu, Liufa;Tanaka, Katsumi;Hirose, Akio;Kobayashi, Kojiro F.
    • Proceedings of the KWS Conference
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    • 2002.10a
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    • pp.570-576
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    • 2002
  • Application of the aged Inconel 718 in hydrogen environment is seriously restraint by its high hydrogen embrittlement (HE) sensitivity. m previous researches, we have suggested the possibility and applicability of the laser surface annealing (LSA) process in improving the HE resistance of this alloy. Sequentially, a study on the effects of the precipitates in the Inconel 718 on its HE sensitivity was conducted in this research. Firstly, flat bar specimens were heat-treated to obtain various kinds of precipitation microstructures concerning the ${\gamma}$" phase and the 6 phase. Hydrogen was charged into the specimen by a cathodic charging process. The loss in reduction of area (RA) caused by hydrogen charging was used to assess the HE sensitivity. The HE sensitivity of the alloy was lowered with decreasing the volume fraction of ${\gamma}$". Moreover, it was possible to increase the HE resistance of the aged alloy by dissolving the $\delta$ phase, keeping the strength at the same level as that of the common aged alloy. Thus, we concluded that both the $\delta$ phase and the ${\gamma}$" phase affected the HE sensitivity of Inconel 718. Next, two kinds of notch tensile specimens were fabricated, one kind having $\delta$ phase and the other having no $\delta$ phase. All these specimens were aged via the same aging heat treatment process. The LSA process annealed a thin layer of the notch bottom of each specimen. One specimen of each kind was charged with hydrogen by the cathodic hydrogen charging process. Loss in the notch tensile strength (NTS) caused by hydrogen was used to evaluate the HE sensitivity. It was found that while the HE sensitivity of conventionally aged Inconel 718 was decreased by the LSA process, the HE sensitivity of the $\delta$-free aged Inconel 718 could further be decreased. Therefore, for applications in hydrogen environments, it is possible to fabricate alloys with both good HE resistance and high strength by controlling the precipitation conditions, and to improve HE resistance further via applying the LSA process.

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[ $SiO_2$ ] Effect on the Electrochemical Properties of Polymeric Gel Electrolytes Reinforced with Glass Fiber Cloth ($SiO_2$가 유리섬유로 보강된 고분자 겔 전해질의 전기 화학적 특성에 미치는 영향)

  • Park Ho Cheol;Kim Sang Heon;Chun Jong Han;Kim Dong Won;Ko Jang Myoun
    • Journal of the Korean Electrochemical Society
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    • v.4 no.1
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    • pp.6-9
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    • 2001
  • [ $SiO_2$ ] effect on the electrochemical properties of polymeric gel electrolytes(PGEs) reinforced with glass fiber cloth(GFC) was investigated . PGEs were composed of polyacrylronitrile(PAN), poly(vinylidenefluoride-co-hexafluoropropylene) (P(VdF-co-HFP)), $LiClO_4$ and three kind of plasticizer(ethylene carbonate, dietyl carbonate, propylene carbonate). $SiO_2$ was added to PGEs in the weight fraction of 10, 20, $30\%$ respectively. PGEs containing $SiO_2$ showed conductivity of over $10^{-3}S/cm\;at\;23^{\circ}C$ and electrochemical stability window to 4.8V. In the impedance spectra of the cells, which were constructed by lithium metals as electrodes, interfacial resistance increased due to growth of passivation layer during storage time and remarkable difference was not observed with content of $SiO_2$. In the impedance spectra of the lithium ion polymer batteries consisted of $LiClO_2$ and mesophase pitch-based carbon fiber(MCF), ohmic cell resistance of $SiO_2-free$ PGE was changed continuously with number of cycle, but those of $SiO_2-dispersed$ PGEs were not. Discharge capacity of the PGE containing $20wt\%\;SiO_2$ showed 132 mAh/g at 0.2C rate and $85\%$ of discharge capacity was retained at 2C rate.

Thickness Effect on the Compressive Strength of T800/924C Carbon Fibre-Epoxy Laminates (T800/924C 탄소-에폭시 복합재판의 압축강도에 대한 두께 효과)

  • Lee, J.;C. Kong;C. Soutis
    • Composites Research
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    • v.17 no.4
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    • pp.7-17
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    • 2004
  • In this study, the effect of laminate thickness on the compressive behaviour of composite materials is investigated through systematic experimental work using the stacking sequences, $[O_4]_{ns},{\;}[45/0/-45/90]_{ns}$ and $[45_n/0_n/-45_n/90_n]_s$ (n=2 to 8). Parameters such as fibre volume fraction, void content, fibre waviness and interlaminar stresses, influencing compressive strength with increasing laminate thickness are also studied experimentally and theoretically. Furthermore the stacking sequence effects on failure strength of multidirectional laminates are examined. For this purpose, two different scaling techniques are used; (1) ply-level technique $[45_n/0_n/-45_n/90_n]s$ and (2) sublaminate level technique $[45/0/-45/90]_{ns}$. An apparent thickness effect existes in the lay-up with blocked plies, i.e. unidirectional specimens ($[O_4]_{ns}) and ply-level scaled multidirectional specimens ($[45_n/0_n/-45_n/90_n]_s$). Fibre waviness and void content are found to be main parameters contributing to the thickness effect on the compressive failure strength. However, the compressive strength of the sublaminate level scaled specimens ($[45/0/-45/90]_{ns}$) is almost unaffected regardless of the specimen thickness (since ply thickness remains constant). From the investigation of the stacking sequence effect, the strength values obtained from the sublaminate level scaled specimens are slightly higher than those obtained from the ply level scaled specimens. The reason for this effect is explained by the fibre waviness, void content, free edge effect and stress redistribution in blocked $0^{\circ}$ plies and unblocked $0^{\circ}$ plies. The measured failure strengths are compared with the predicted values.