• Title/Summary/Keyword: Free carbon

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Free vibration analysis of chiral double-walled carbon nanotube embedded in an elastic medium using non-local elasticity theory and Euler Bernoulli beam model

  • Dihaj, Ahmed;Zidour, Mohamed;Meradjah, Mustapha;Rakrak, Kaddour;Heireche, Houari;Chemi, Awda
    • Structural Engineering and Mechanics
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    • v.65 no.3
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    • pp.335-342
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    • 2018
  • The transverse free vibration of chiral double-walled carbon nanotube (DWCNTs) embedded in elastic medium is modeled by the non-local elasticity theory and Euler Bernoulli beam model. The governing equations are derived and the solutions of frequency are obtained. According to this study, the vibrational mode number, the small-scale coefficient, the Winkler parameter and chirality of double-walled carbon nanotube on the frequency ratio (xN) of the (DWCNTs) are studied and discussed. The new features of the vibration behavior of (DWCNTs) embedded in an elastic medium and the present solutions can be used for the static and dynamic analyses of double-walled carbon nanotubes.

탄소섬유 복합재료 보오링바의 Chatter 특성에 관한 연구

  • 김형철;김기수;함승덕;이대길;남궁석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1991.04a
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    • pp.22-31
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    • 1991
  • Machining with boring bars frequently induce chatter vibration because of the low stiffness and damping of cantilever shape of boring bars. To increase stiffness and damping, a carbon fiber epoxy composite boring bar was designed, manufactured and tested. The natural frequency of the carbon fiber epoxy composite boring bar in the free-free end condition was incerased more than 50% over that of the steel boring bar, and the damping of the carbon fiber epoxy composite boring bar was also increased 450%. The fundamental natural frequency of the carbon fiber epoxycomposite boring bar in the cantilever beam condition was found to be increased 20-30% over that of the steel boring bar in overhang length range 140-200mm. In machining S45C tapered workpieces, the limit of the overhang length of the steel boring bar was about 170mm in cutting speed 140m/min.

A Study on The Electrochemical Behavior of CF/Al Composite in Aqueous Solutions (수용액 중 탄소섬유/알루미늄 복합재의 전기화학적 거동에 관한 연구)

  • Nam, Yun-Gyeong;Mun, Seong-Mo;Jeong, Yong-Su;Sin, Seung-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2011.05a
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    • pp.158-159
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    • 2011
  • In this work, The electrochemical behavior of CF/Al composite was investigated at constant current densities in aqueous solutions. The surface and cross section of PEO-treated CF/Al were observed using SEM, EDS and OM. The CF/Al composite contains carbon fibers of about 40 Vol.% with 5~7 um diameter and 100~150 um length. The carbon fibers appeared to b removed by anodic oxidation in sulfuric acid solution, leaving a carbon-fiber free zone in the surface region. Anodic oxide films were formed in the carbon-free region by plasma electrolytic oxidation(PEO) method in alkaline solutions.

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Electromagnetic Shielding Characteristics of Polyaniline and Its Mixtures (폴리아닐린과 그 혼합물의 전자기파 차폐특성)

  • 박종수;임인호;최병수
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.12 no.2
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    • pp.293-298
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    • 2001
  • EB-NMP free standing film is manufactured from NMP solution of polyaniline(emeraldine base EB). Also ES(emeraldine salt EB . HCl) film is manufactured by doping of EB-NMP film with 1 mole HCI aqueous solution. And EB-mixture films containing conductor(carbon black, graphite, Ag etc.) are prepared, In this study, electromagnetic interference shielding efficiency(EMI SE) of ES free standing film ($\sigma$=5 S/cm, t=0.14mm) is 23~25 dB in the frequency range of 10 MHz~1 GHz. ES-mixture(carbon black, graphite, Ag etc.) films, polyaniline film doped camphorsulfonic acid(CSA) show higher EMI SE(30~34 dB, 36~42 dB, 44~52 dB, 34~43 dB) property than that of ES free standing film, respectively.

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Effects of Electrochemical Oxidation of Carbon Fibers on Mechanical Interfacial Properties of Carbon Fibers-reinforced Polarized-Polypropylene Matrix Composites (전기화학적 산화처리가 탄소섬유/극성화된 폴리프로필렌 복합재의 기계적 계면 특성에 미치는 영향)

  • Kim, Hyun-Il;Choi, Woong-Ki;Oh, Sang-Yub;An, Kay-Hyeok;Kim, Byung-Joo
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.476-482
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    • 2013
  • In this work, the effects of electrochemical oxidation of carbon fiber surfaces on mechanical interfacial properties of carbon fibers-reinforced polarized-polypropylene matrix composites were studied with various current densities during the treatments. Surface properties of the fibers before and after treatments were observed by SEM, AFM, XPS, and contact angle measurements. Mechanical interfacial properties of the composites were measured in terms of critical stress intensity factor ($K_{IC}$). From the results it was found that $O_{1s}$ peaks of the fiber surfaces were strengthened after electrochemical oxidation which led to the enhancement of surface free energy of the fiber, resulting in good mechanical performance of the composites. It can be concluded that electrochemical oxidation of the carbon fiber surfaces can control the interfacial adhesion between the carbon fibers and polarized-polypropylene in this composites system.

Enhancing the Mechanical Properties of Z-Spring by Implementing CF&GF Hybrid Prepreg Lamination Patterns (CF&GF Hybrid Prepreg 적층 패턴에 따른 Z-Spring의 기계적 물성 향상에 관한 연구)

  • Kim, Jeong-Keun;Choi, Sun-Ho;Kim, Young-Keun;Kim, Hong-Gun;Kwac, Lee-Gu
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.20 no.3
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    • pp.53-59
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    • 2021
  • In vibration-free vehicles such as limousine buses, the vibration is minimized by installing an air spring instead of the leaf spring used in the existing freight cars to prevent the damage to the loaded cargo from shocks generated during movement. In the existing vehicles, steel structures support the air spring system. This study was aimed at replacing the steel structures used in the Z-spring by carbon fiber and glass fiber reinforced plastics. In addition, the mechanical properties (elastic modulus, tensile strength, and shear strength) of carbon fiber and glass fiber prepreg were derived using specimens molded with the corresponding prepreg. The final goal was to develop a material lighter than the conventional steel material but with enhanced mechanical properties. Although the CF prepreg exhibited excellent mechanical properties, the production cost was extremely high. To overcome this limitation, hybrid composites with GF prepreg were examined, which are expected to be promising future materials.

Morphological optimization of process parameters of randomly oriented carbon/carbon composite

  • Raunija, Thakur Sudesh Kumar;Manwatkar, Sushant Krunal;Sharma, Sharad Chandra;Verma, Anil
    • Carbon letters
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    • v.15 no.1
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    • pp.25-31
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    • 2014
  • A microstructure analysis is carried out to optimize the process parameters of a randomly oriented discrete length hybrid carbon fiber reinforced carbon matrix composite. The composite is fabricated by moulding of a slurry into a preform, followed by hot-pressing and carbonization. Heating rates of 0.1, 0.2, 0.3, 0.5, 1, and $3.3^{\circ}C/min$ and pressures of 5, 10, 15, and 20 MPa are applied during hot-pressing. Matrix precursor to reinforcement weight ratios of 70:30, 50:50, and 30:70 are also considered. A microstructure analysis of the carbon/carbon compacts is performed for each variant. Higher heating rates give bloated compacts whereas low heating rates give bloating-free, fine microstructure compacts. The compacts fabricated at higher pressure have displayed side oozing of molten pitch and discrete length carbon fibers. The microstructure of the compacts fabricated at low pressure shows a lack of densification. The compacts with low matrix precursor to reinforcement weight ratios have insufficient bonding agent to bind the reinforcement whereas the higher matrix precursor to reinforcement weight ratio results in a plaster-like structure. Based on the microstructure analysis, a heating rate of $0.2^{\circ}C/min$, pressure of 15 MPa, and a matrix precursor to reinforcement ratio of 50:50 are found to be optimum w.r.t attaining bloating-free densification and processing time.

Photocatalytic Degradation of E. coli and S. aureus by Multi Walled Carbon Nanotubes

  • Sharon, Madhuri;Datta, Suprama;Shah, Sejal;Sharon, Mahesh War;Soga, T.;Afre, Rakesh
    • Carbon letters
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    • v.8 no.3
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    • pp.184-190
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    • 2007
  • Carbon Nano Tubes could be either metallic or semi-conducting in nature, depending on their diameter. Its photocatalytic behavior has given an impetus to use it as an anti-microbial agent. More than 95% Escherichia coli and Staphylococcus aureus bacteria got killed when exposed to Carbon Nano Tubes for 30 minutes in presence of sunlight. Carbon Nano Tubes are supposed to have smooth surface on to which it accumulates positive charges when exposed to light. The surface that is non illuminated has negative charge. At the cellular level microorganisms produce negative charges on the cell membrane, Therefore damaging effect of multi walled carbon nano tubes (exposed to light) on the microorganisms is possible. In this paper, photo catalytic killing of microbes by multi walled carbon nano tubes is reported. Killing was due to damage in the cell membrane, as seen in SEM micrographs. Moreover biochemical analysis of membrane as well as total cellular proteins by SDS PAGE showed that there was denaturation of membrane proteins as well as total proteins of both the microbes studied. The killed microbes that showed a decrease in number of protein bands (i.e. due to breaking down of proteins) also showed an increase in level of free amino acids in microbes. This further confirmed that proteins got denatured or broken down into shorter units of amino acids. Increased level of free amino acids was recorded in both the microbes treated with multi walled carbon nano tubes and sunlight.

Carbon-free Hydrogen Production Using Membrane Reactors (막촉매반응기를 이용한 수소생산)

  • Do, Si-Hyun;Roh, Ji Soo;Park, Ho Bum
    • Membrane Journal
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    • v.28 no.5
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    • pp.297-306
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    • 2018
  • This review focused carbon-free hydrogen productions from ammonia decomposition including inorganic membranes, catalysts and the presently studied reactor configurations. It also contains general information about hydrogen productions from hydrocarbons as hydrogen carriers. A Pd-based membrane (e.g. a porous ceramic or porous metallic support with a thin selective layer of Pd alloy) shows its efficiency to produce the high purity hydrogen. Ru-based catalysts consisted of Ru, support, and promoter are the efficient catalysts for ammonia decomposition. Packed bed membrane reactor (PBMR), Fluidized bed membrane reactor (FBMR), and membrane micro-reactor have been studied mainly for the optimization and the improvement of mass transfer limitation. Various types of reactors, which contain various combinations of hydrogen-selective membranes (i.e. Pd-based membranes) and catalysts (i.e. Ru-based catalysts) including catalytic membrane reactor, have been studied for carbon-free hydrogen production to achieve high ammonia conversion and high hydrogen flux and purity.

Using an equivalent continuum model for 3D dynamic analysis of nanocomposite plates

  • Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.20 no.3
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    • pp.623-649
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    • 2016
  • Most of the early studies on plates vibration are focused on two-dimensional theories, these theories reduce the dimensions of problems from three to two by introducing some assumptions in mathematical modeling leading to simpler expressions and derivation of solutions. However, these simplifications inherently bring errors and therefore may lead to unreliable results for relatively thick plates. The main objective of this research paper is to present 3-D elasticity solution for free vibration analysis of continuously graded carbon nanotube-reinforced (CGCNTR) rectangular plates resting on two-parameter elastic foundations. The volume fractions of oriented, straight single-walled carbon nanotubes (SWCNTs) are assumed to be graded in the thickness direction. In this study, an equivalent continuum model based on the Eshelby-Mori-Tanaka approach is employed to estimate the effective constitutive law of the elastic isotropic medium (matrix) with oriented, straight carbon nanotubes (CNTs). The proposed rectangular plates have two opposite edges simply supported, while all possible combinations of free, simply supported and clamped boundary conditions are applied to the other two edges. The formulations are based on the three-dimensional elasticity theory. A semi-analytical approach composed of differential quadrature method (DQM) and series solution is adopted to solve the equations of motion. The fast rate of convergence of the method is demonstrated and comparison studies are carried out to establish its very high accuracy and versatility. The 2-D differential quadrature method as an efficient and accurate numerical tool is used to discretize the governing equations and to implement the boundary conditions. The convergence of the method is demonstrated and to validate the results, comparisons are made between the present results and results reported by well-known references for special cases treated before, have confirmed accuracy and efficiency of the present approach. The novelty of the present work is to exploit Eshelby-Mori-Tanaka approach in order to reveal the impacts of the volume fractions of oriented CNTs, different CNTs distributions, various coefficients of foundation and different combinations of free, simply supported and clamped boundary conditions on the vibrational characteristics of CGCNTR rectangular plates. The new results can be used as benchmark solutions for future researches.