• 대한화학회지
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• 제61권4호
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• pp.151-156
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• 2017

A simple, green and chemo-selective method for the N-benzyloxycarbonylation of amines, ${\beta}$-amino alcohols, ${\alpha}$-amino esters and sulfonamides has been developed under microwave irradiation. Good to excellent yields of the N-benzyloxycarbamates compounds were obtained in short times without any side products.

• 한국식생활문화학회지
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• 제16권2호
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• pp.118-127
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• 2001

The method of the squid safe made in Kyungsando was examined, and fermentation precess was established. The chemical composition and functional effects of the squid sikhe were examined. In the sensory evaluation, the squid sikhe made from Gampo accepted to be best for traditional Kyungsangdo squid sikhe and it is called standard sikhe. The Gampo sguid sikhe showed higher values in total sugar, free reducing sugar and nitrogen compound analysis compared to the orthers. The sugar of standard sikhe consisted of four kinds including glucose. The contents of free amino acid was increased in the order of glutamic acid, alanine, and methionine. The composition of amino acid in water or salt soluble protein of squid sikhe contained 17 kinds, and the contents was increased in order of glut amine acid, aspartic acid, and proline.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3448-3452
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• 2011

Solvent-free reduction of various aldoximes and ketoximes to the corresponding amines was performed easily and efficiently with $NaBH_4$ in the presence of $ZrCl_4$ supported on $Al_2O_3$. The reactions were carried out rapidly (within 2 min) at room temperature to afford the amines in high to excellent yields.

• Mass Spectrometry Letters
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• 제3권1호
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• pp.25-28
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• 2012

Paint Spray is developed as a direct sampling ionisation method for mass spectrometric analysis of additives in polymer-based surface coatings. The technique simply involves applying an external high voltage (5 kV) to the wetted sample placed in front of the mass spectrometer inlet and represents a much simpler ionisation technique compared to those currently available. The capabilities of Paint Spray are demonstrated herein with the detection of four commercially available hindered amine light stabilisers; TINUVIN${(R)}$770, TINUVIN${(R)}$292, TINUVIN${(R)}$123 and TINUVIN${(R)}$152 directly from thermoset polyester-based coil coatings. Paint Spray requires no sample preparation or pre-treatment and combined with its simplicity requiring no specialised equipment makes it ideal for use by non-specialists. The application of Paint Spray for industrial use has significant potential as sample collection from a coil coating production line and Paint Spray ionisation could enable fast quality control screening at high sensitivity.

• Structural Engineering and Mechanics
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• 제70권5호
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• pp.535-549
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• 2019

This study aimed to develop a high-order shear deformation theory to predict the free vibration of hybrid cross-ply laminated plates under different boundary conditions. The equations of motion for laminated hybrid rectangular plates are derived and obtained by using Hamilton's principle. The closed-form solutions of anti-symmetric cross-ply and angle-ply laminates are obtained by using Navier's solution. To assess the validity of our method, we used the finite element method. Firstly, the analytical and the numerical implementations were validated for an antisymmetric cross-ply square laminated with available results in the literature. Then, the effects of side-to-thickness ratio, aspect ratio, lamination schemes, and material properties on the fundamental frequencies for different combinations of boundary conditions of hybrid composite plates are investigated. The comparison of the analytical solutions with the corresponding finite element simulations shows the good accuracy of the proposed analytical closed form solution in predicting the fundamental frequencies of hybrid cross-ply laminated plates under different boundary conditions.

• Advances in materials Research
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• 제7권2호
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• pp.119-136
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• 2018

In this paper, static and vibration analysis for anti-symmetric cross-ply and angle- ply carbon/glass hybrid laminates rectangular composite plate are presented. In this analysis, the equations of motion for simply supported thick laminated hybrid rectangular plates are derived and obtained through the use of Hamilton's principle. The closed-form solutions of anti-symmetric cross-ply and angle- ply laminates are obtained using Navier solution. The effects of side-to-thickness ratio, aspect ratio, and lamination schemes on the fundamental frequencies loads are investigated. The study concludes that shear deformation laminate theories accurately predict the behavior of composite laminates, whereas the classical laminate theory over predicts natural frequencies. The excellent accuracy of the present analytical solution is confirmed by making some comparisons of the present results with those available in the literature. It can be concluded that the proposed theory is accurate and simple in solving the free vibration behaviors of anti-symmetric cross-ply and angle- ply hybrid laminated composite plates.

• Advances in nano research
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• 제11권6호
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• pp.621-640
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• 2021

Effect of thickness stretching on mechanical behavior of functionally graded (FG) carbon nanotubes reinforced composite (CNTRC) laminated nanoplates resting on elastic foundation is analyzed in this paper using a novel quasi 3D higher-order shear deformation theory. The key feature of this theoretical formulation is that, in addition to considering the thickness stretching effect, the number of unknowns of the displacement field is reduced to four, and which is more than five in the other models. Single-walled carbon nanotubes (SWCNTs) are the reinforced elements and are distributed with four power-law functions which are, uniform distribution, V-distribution, O-distribution and X-distribution. To cover various boundary conditions, an analytical solution is developed based on Galerkin method to solve the governing equilibrium equations by considering the nonlocal strain gradient theory. A modified two-dimensional variable Winkler elastic foundation is proposed in this study for the first time. A parametric study is executed to determine the influence of the reinforcement patterns, power-law index, nonlocal parameter, length scale parameter, thickness and aspect ratios, elastic foundation, thermal environments, and various boundary conditions on stresses, displacements, buckling loads and frequencies of the CNTRC laminated nanoplate.

• Advances in nano research
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• 제12권2호
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• pp.117-137
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• 2022

Effect of thickness stretching on free vibration, bending and buckling behavior of carbon nanotubes reinforced composite (CNTRC) laminated nanoplates rested on new variable elastic foundation is investigated in this paper using a developed four-unknown quasi-3D higher-order shear deformation theory (HSDT). The key feature of this theoretical formulation is that, in addition to considering the thickness stretching effect, the number of unknowns of the displacement field is reduced to four, and which is more than five in the other models. Two new forms of CNTs reinforcement distribution are proposed and analyzed based on cosine functions. By considering the higher-order nonlocal strain gradient theory, microstructure and length scale influences are included. Variational method is developed to derive the governing equation and Galerkin method is employed to derive an analytical solution of governing equilibrium equations. Two-dimensional variable Winkler elastic foundation is suggested in this study for the first time. A parametric study is executed to determine the impact of the reinforcement patterns, nonlocal parameter, length scale parameter, side-t-thickness ratio and aspect ratio, elastic foundation and various boundary conditions on bending, buckling and free vibration responses of the CNTRC plate.

• Advances in materials Research
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• 제12권2호
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• pp.161-177
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• 2023

This paper proposes an analytical method to investigate the free vibration behaviour of new functionally graded (FG) carbon nanotubes reinforced composite beams based on a higher-order shear deformation theory. Cosine functions represent the material gradation and material properties via the thickness. The kinematic relations of the beam are proposed according to trigonometric functions. The equilibrium equations are obtained using the virtual work principle and solved using Navier's method. A comparative evaluation of results against predictions from literature demonstrates the accuracy of the proposed analytical model. Moreover, a detailed parametric analysis checks for the sensitivity of the vibration response of FG nanobeams to nonlocal length scale, strain gradient microstructure-scale, material distribution and geometry.

• The Journal of Advanced Prosthodontics
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• 제7권5호
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• pp.386-391
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• 2015

PURPOSE. The purpose of this preliminary study was to investigate the effects of adding 4,4'-bis(N,N-diethylamino) benzophenone (DEABP) as a co-initiator to a binary photoinitiating system (camphorquinone-amine) to analyze on the degree of conversion (DC) of a light-cured resin for dental 3D printing. MATERIALS AND METHODS. Cylindrical specimens (N=60, n=30 per group, ${\phi}5mm{\times}1mm$) were fabricated using bisphenol A glycerolate dimethacrylate (BisGMA) both with and without DEABP. The freshly mixed resins were exposed to light in a custom-made closed chamber with nine light-emitting diode lamps (wavelength: 405 nm; power: $840mW/cm^2$) for polymerization at each incidence of light-irradiation at 10, 30, 60, 180, and 300 seconds, while five specimens at a time were evaluated at each given irradiation point. Fourier-transform infrared (FTIR) spectroscopy was used to measure the DC values of the resins. Two-way analysis of variance and the Duncan post hoc test were used to analyze statistically significant differences between the groups and given times (${\alpha}$=.05). RESULTS. In the DEABP-containing resin, the DC values were significantly higher at all points in time (P<.001), and also the initial polymerization velocity was faster than in the DEABP-free resin. CONCLUSION. The addition of DEABP significantly enhanced the DC values and, thus, could potentially become an efficient photoinitiator when combined with a camphorquinone-amine system and may be utilized as a more advanced photopolymerization system for dental 3D printing.