• Title/Summary/Keyword: Framework structure

Search Result 1,652, Processing Time 0.026 seconds

Synthesis of Ti-SBA-15 Doped with Lanthanide Ions and Their Photocatalytic Activity (란탄족 이온이 도핑된 Ti-SBA-15의 합성 및 그들의 광촉매 활성)

  • Hong, Seong-Soo
    • Clean Technology
    • /
    • v.26 no.1
    • /
    • pp.7-12
    • /
    • 2020
  • Ti-SBA-15 catalysts doped with lanthanide ions (Ln/Ti-SBA-15) were successfully synthesized using conventional hydrothermal method. In addition, they were characterized by XRD, FT-IR, DRS, BET, and PL. The activity of these materials on the photocatalytic decomposition of methylene blue under ultraviolet light irradiation was also examined. Ti-SBA-15 catalysts doped with various lanthanide ions maintained their mesoporous structure. The pore size and pore volume of Ln/Ti-SBA-15 materials decreased but their surface area increased upon the doping of lanthanide ion. Ln/Ti-SBA-15 materials exhibited the type IV nitrogen isotherm with desorption hysteresis loop type H2, which was characteristic of mesoporous materials. The size of hysteresis increased in the doping of lanthanide ions on Ti-SBA-15 material. There was no absorption in the visible region (> 400 nm) regardless of the doping of lanthanide ions to TiO2 particles, while the broad bands at 220 nm appeared at the Ln/Ti-SBA-15 samples, indicating the framework incorporation of titanium into SBA-15. 1 mol% Pr/ Ti-SBA-15 catalysts showed the highest photocatalytic activity on the decomposition of methylene blue but the Ti-SBA-15 catalysts doped with Eu, Er, and Nd ions showed lower activity compared to pure Ti-SBA-15 catalyst. The PL peaks appeared at about 410 nm at all catalysts while the excitonic PL signal was proportional to the photocatalytic activity for the decomposition of methylene blue.

Descriptive Characteristics of the Label Texts Related to Earth Science: Toward Educationally Meaningful Communication (교육적으로 유의미한 의사소통을 위한 지구과학 관련 전시 라벨의 서술 특징)

  • Kim, Chan-Jong;Park, Eun-Ji;Yoon, Sae-Yeol;Lee, Sun-Kyung
    • Journal of the Korean earth science society
    • /
    • v.33 no.1
    • /
    • pp.94-109
    • /
    • 2012
  • The purpose of this study is to analyse the descriptive characteristics of the label texts related to Earth Science at a science museum and a natural history museum in Korea. The data were collected from Korean National Science Museum and Seodaemun Natural History Museum. The analysis framework was modified according to the Systemic Functional Linguistics. As a result, characteristics of the labels are 1) mostly declarative sentences, 2) appropriate amount of scientific information, and 3) mainly 'facts'. Moreover, all of the text genre are 4) 'logical expositions'. Particularly in Korean National Science Museum, the labels present 5) more scientific words among the entire terminologies and 6) more than half subjects omitted or long nominalized. Those results may imply that the labels can lead one-way communication regarding the culture of science rather than two-way. This study presents the descriptive characteristics of the label texts to make educationally meaningful communication possible by building an open structure between visitors' own culture in everyday life and the culture of science.

The Differences of Verbal Interactions according to Communication Structures and Communication Status in Small Group Activity of Earth Science Gifted Students (지구과학 영재들의 소집단 활동에서 의사소통 구조와 집단 내 지위에 따른 언어적 상호 작용의 차이)

  • Chung, Duk Ho;Lee, Chul Min;Park, Kyeong-Jin
    • Journal of the Korean earth science society
    • /
    • v.41 no.3
    • /
    • pp.307-319
    • /
    • 2020
  • The purpose of this study was to determine whether there are differences in the verbal interactions of earth science gifted depending on their communications structures and group status in small group activities. To this end, a small group activity was conducted to measure the density of the earth, and 8 small groups were selected, including 4 co-ownership type and 4 monopolistics type groups with different communication structures. And then, the framework was developed for analyzing verbal interactions to compare the differences in characteristics between small groups. The results are as follows. First, regardless of the communication structures, there were showing a simple pingpong-type communication structures for all small groups. Second, negative interactions such as 'restraint', 'command', 'complaint', and 'lack of confidence' predominantly appeared in all small groups. Third, the students in the status of out-lookers in small groups were mainly verbal interactions, such as instructing the other person, acting against the other person's actions, and expressing dissatisfaction with the attitudes and abilities of members. Therefore, teachers should guide students to use higher-level verbal interactions in their group activities in small group activities, and engage in students communication to prevent negative interactions from occurring. The teachers also need to check the level of achievement for students in the status of out-lookers in advance and guide them to participate more actively in small group activities. This study is meaningful in that it can be sued to design teaching and learning to improve students' problem solving and communication skills.

Semantic Network Analysis of Science Gifted Middle School Students' Understanding of Fact, Hypothesis, Theory, Law, and Scientificness (언어 네트워크 분석법을 통한 중학교 과학영재들의 사실, 가설, 이론, 법칙과 과학적인 것의 의미에 대한 인식 조사)

  • Lee, Jun-Ki;Ha, Minsu
    • Journal of The Korean Association For Science Education
    • /
    • v.32 no.5
    • /
    • pp.823-840
    • /
    • 2012
  • The importance of teaching the nature of science (NOS) has been emphasized in the science curriculum, especially in the science curriculum for science-gifted students. Nevertheless, few studies concerning the structure and formation of students' mental model on NOS have been carried out. This study aimed to explore science-gifted students' understanding of 'fact', 'hypothesis', 'theory', 'law', and 'scientificness' by utilizing semantic network analysis. One hundred ten science-gifted middle school students who were selected by a national university participated in this study. We collected students' written responses of five items and analyzed them by the semantic network analysis(SNA) method. As a result, the core ideas of students' understanding of 'fact' were proof and reality, of 'hypothesis' were tentativeness and uncertainty, of 'theory' was proven hypothesis by experimentation, of 'law' were absoluteness and authority, and of 'scientificness' were factual evidence, verifiability, accurate and logical theoretical framework. The result of integrated semantic network illustrated that the viewpoint of science-gifted students were similar to absolutism and logical positivism (empiricism). Methodologically, this study showed that the semantic network analysis method was an useful tool for visualization of students' mental model of scientific conceptions including NOS.

Electrochemical Study of Nanoparticle Li4Ti5O12 as Negative Electrode Material for Lithium Secondary Battery (리튬이차전지 음극재용 나노입자 Li4Ti5O12의 전기화학적 연구)

  • Oh Mi-Hyun;Kim Han-Joo;Kim Young-Jae;Son Won-Keun;Lim Kee-Joe;Park Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.9 no.1
    • /
    • pp.1-5
    • /
    • 2006
  • Lithium titanium oxide $(Li_4Ti_5O_{12})$ with spinel-framework structures as anode material for lithium-ion battery was prepared by sol-gel and high energy ball milling (HEBH) method. According to the X-ray diffraction (XRD), Particle Size Analyses(PSA) and scanning electron microscopy (SEM) analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100 nm were observed. Half cells, consisting of $Li_4Ti_5O_{12}$ as working electrode and lithium foil as both counter and reference electrodes showed the high performance of high rate discharge capacity and 173 mAh/g at 0.2C in the range of $1.0\sim2.5 V$. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transform during the lithium intercalation and deintercalation process.

Design and Implementation of an Ontology-based Access System of Nutrition and Food Guide Tower in Middle School Home Economics (온톨로지 기반 중학교 기술. 가정교과 영양소의 질의응답 시스템 설계 및 구현)

  • Cho, Young-Sun;Baek, Hyeon-Gi;Kim, Jeong-Kyoum;Yu, Jeong-Su
    • Journal of The Korean Association of Information Education
    • /
    • v.11 no.3
    • /
    • pp.317-327
    • /
    • 2007
  • The purpose of this study is to consider ontology theory and get to forge design and implementation of ontology-based access system which is support to the nutrition and food guide tower of Home Economics textbooks in middle school in order to offer the way of effective learning performance. It offers a model by establishing a nutrition and food guide tower access system based on Protege-2000 framework. This system is on the basis of XML, and it makes possible to work with semantic web, a next generation internet technology, and provides a meaning structure that can be shared in the field of nutrition in order to build up the fundament of knowledge an information system for the mutual operations. A learner can systemize the knowledge through a self-information access and an instructor can also check out the degree of learner's learning-accomplishment and interests, directly putting the access system into the teaching and learning process. In addition, it is supposed that the learner can maintain a balance and healthy life by internalizing his or her knowledge throughout ontology not only in a teaching and learning process but also in a daily life.

  • PDF

An Analysis of the Impact to Korea-China FTA Negotiation from China-Taiwan ECFA (중.대만 ECFA 체결이 한.중 FTA 협상에 미칠 영향에 관한 연구)

  • Kim, Sun-Kwang;Kim, Jong-Hun
    • International Commerce and Information Review
    • /
    • v.13 no.2
    • /
    • pp.179-203
    • /
    • 2011
  • Currently, the most common form of regional economic integration is FTA (Free Trade Area), which is formed by two countries or more as either a bilateral or multilateral agreement. A proposed FTA between Korea and China recently has been re-focused after China concluded its ECFA (Economic Cooperation Framework Agreement) with Taiwan in June 2010. By May 2010, China was the No.1 export partner to Korea (as a Chinese No.2 import partner). Also, Korea and Taiwan trade structure to China is similar and competitive at the same time. So, China-Taiwan ECFA has a significant effect on the trade between China and Korea. As a result, it will hurt Korean industrial production and trade with China. Therefore, the progress and expected issue of a FT A between Korea and China which is prompting will be analyzed. In this situation, the final purpose of this paper is to analyze the impact on a Korea-China FTA Negotiation from the China-Taiwan ECFA.

  • PDF

Analysis of Scientific Models in the Earth Domain of the 10th Grade Science Textbooks (10학년 과학 교과서 지구 분야에 등장하는 과학적 모델 분석)

  • Oh, Phil-Seok;Jon, Won-Son;Yoo, Jung-Moon
    • Journal of the Korean earth science society
    • /
    • v.28 no.4
    • /
    • pp.393-404
    • /
    • 2007
  • The purpose of this study was to identity scientific models included in the Earth domain of the $10^{th}$ grade science textbooks. Three earth science-related chapters in each of 11 trade books were analyzed. A framework was developed and used to classify a scientific model from three different perspectives: medium of representation, method of representation, and mobility of a model. Results showed that the science textbooks utilized domain-specific models in which the nature of sub-areas of earth science was embedded. That is, the unit of 'Change of the Earth' included many iconic models that represented the inaccessible inner structure of the earth and the movement of the tectonic plates. These were also two-dimensional pictorial and static models. In the chapter of 'Atmosphere and Oceans', symbolic and diagrammatic models were dominant in use, which included weather maps and contour line graphs of sea surface temperature and salinity. The unit of 'Solar System and Galaxies' showed the highly frequent use of iconic and analogical models for the large-scale celestial objects and their movements. Implications for earth science education and relevant research were discussed.

A Study on the Issues and Improvement of the Existing Environmental Impact Assessment System - Evaluation in an operator Viewpoint - (현행 환경영향평가 제도의 문제점과 개선방안 - 실무자적 관점에서 검토 -)

  • Lee, Seung-Won;Kim, Jung-gun;Seo, Jung-Kuk
    • Journal of Environmental Science International
    • /
    • v.27 no.5
    • /
    • pp.281-289
    • /
    • 2018
  • The Korean environmental impact assessment(EIA) system, and explored ways to improve it as a more efficient and viable institution relevant to the demand of our time and conditions in study. The first problem this study identified is found in the fact that the party to write up the assessment report is itself the business operator or the one who is planning to work out the business plan. This structure translates into placing an order with an agent for EIA report. The reporting job may br subcontracted to the agent at a cost far below the rate specified in the 'Standard for Estimate of Agency Fee for Environmental Impact Assessment.' This practice also causes the vicious circle of producing a report that is written to justify the project or business in question or it leads to rough-and ready and poor documentation to minimize the time required. Second, in order to achieve the goal of the plan or business, which is the target of EIA, the local residents tend to ve regarded as an obstacle. This means elimination of the local people from participating in the EIA or their opinion being frequently ignored. This is the seed of distrust and hostility that sometimes provoke disagreements or fierce conflicts. The first proposal to improve these problem is to improve the factors that cause poor documentation of the assessment report as well as improve the understanding of the EIA system. This study proposes the following measures for improvement. The agency cost for EIA should be paid by the business operator or a third party that can ensure faithful implementation of the payment. A system should be established to verify transparent estimation of the agency cost. In order to enhance the professional quality of EIA agents, there should be implementation of qualification test for industrial engineer of related engineers in addition to the current EIA Qualification Test. The second proposal for improvement is to improve the citizen participation process by instituting a legal framework to make clear the purpose of the briefing session for local residents, which is held as a procedure of EIA, and to ensure more positive publicity during the stage of listening to the opinion of the local community. For a smooth and rational communication process, a moderator and a communicator of opinion, as is the case in a public hearing, could be instituted to clearly get the purpose of the briefing session across to the residents and to help to carry out the explanation and Q & A sessions according to the categories of the opinion of the residents. At present, the notification of the public inspection of the draft of the assessment report and briefing session for the residents is made on the newspaper and internet network. But some people have difficulty with access to this method of announcement. A higher participation rate could be secured if a legal provision is added to specify putting up placards in specific places such as the entrance to the place for the briefing session for residents or the building of administrative agencies of the area concerned.

Exploratory Research on Automating the Analysis of Scientific Argumentation Using Machine Learning (머신 러닝을 활용한 과학 논변 구성 요소 코딩 자동화 가능성 탐색 연구)

  • Lee, Gyeong-Geon;Ha, Heesoo;Hong, Hun-Gi;Kim, Heui-Baik
    • Journal of The Korean Association For Science Education
    • /
    • v.38 no.2
    • /
    • pp.219-234
    • /
    • 2018
  • In this study, we explored the possibility of automating the process of analyzing elements of scientific argument in the context of a Korean classroom. To gather training data, we collected 990 sentences from science education journals that illustrate the results of coding elements of argumentation according to Toulmin's argumentation structure framework. We extracted 483 sentences as a test data set from the transcription of students' discourse in scientific argumentation activities. The words and morphemes of each argument were analyzed using the Python 'KoNLPy' package and the 'Kkma' module for Korean Natural Language Processing. After constructing the 'argument-morpheme:class' matrix for 1,473 sentences, five machine learning techniques were applied to generate predictive models relating each sentences to the element of argument with which it corresponded. The accuracy of the predictive models was investigated by comparing them with the results of pre-coding by researchers and confirming the degree of agreement. The predictive model generated by the k-nearest neighbor algorithm (KNN) demonstrated the highest degree of agreement [54.04% (${\kappa}=0.22$)] when machine learning was performed with the consideration of morpheme of each sentence. The predictive model generated by the KNN exhibited higher agreement [55.07% (${\kappa}=0.24$)] when the coding results of the previous sentence were added to the prediction process. In addition, the results indicated importance of considering context of discourse by reflecting the codes of previous sentences to the analysis. The results have significance in that, it showed the possibility of automating the analysis of students' argumentation activities in Korean language by applying machine learning.