• 제목/요약/키워드: Fractionation process

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평형 냉동에 의한 물동위원소의 레일리분별 (Rayleigh Fractionation of Stable Water Isotopes during Equilibrium Freezing)

  • 이정훈;정혜정;니암게렐 얄랄트
    • 자원환경지질
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    • 제54권1호
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    • pp.61-67
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    • 2021
  • 고체상의 눈 또는 얼음의 안정동위원소 값은 과거의 기후를 복원하고 동위원소 수문분리의 단성분으로 기여율을 계산하는 데에 사용되어 왔다. 융해와 냉동이 일어나면서 눈 또는 얼음과 액체상의 물 사이의 동위원소 분별작용이 일어나는데, 융해는 상대적으로 현장, 실험 및 모델연구를 통해 연구결과가 제시되어 있지만, 냉동에 대해서는 알려진 것이 많지 않다. 본 논평에서는 평형 냉동이 발생할 때 물의 두 안정동위원소인 산소, 수소의 선형관계 및 레일리분별과정을 통해 냉동에 의한 동위원소 분별과정을 고찰하였다. 해양에서 증발한 수증기에 의해 응축된 눈은 기울기 8을 가지는 지구천수선을 따라 움직이지만, 냉동 및 융해가 발생하게 되면 기울기 19.5/3.1~6.3을 가지는 선형관계를 나타내게 된다. 평형냉동 동안 레일리분별과정에 의해 액체상인 물은 열린 계와 닫힌계에서 같은 동위원소변동을 보여 주었다. 눈 또는 얼음이 제거되는 열린 계에서는 남아있는 물의 안정동위원소와 분별계수만큼의 차이를 가지면서 높은 값을 나타내었다. 닫힌 계에서는 초기 액체상의 물의 동위원소 값으로 눈 또는 얼음은 수렴하였다. 냉동에 의한 눈 또는 얼음의 동위원소변동과정은 고기후 연구 및 수문분리의 정확도를 증가시킬 것으로 기대된다.

Radical Scavenging Activity of Gallic Acid from Woodfordia Fruticosa Flowers

  • Bhatt, Lok Ranjan;Yook, Chan-Nam;Choi, Hwa-Jung;Baek, Seung-Hwa
    • 동의생리병리학회지
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    • 제22권4호
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    • pp.903-906
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    • 2008
  • Woodfordia fruticosa Kurz (Lythraceae) is used in the treatment of various ailments in traditional medicines. DPPH activity guided fractionation and purification process was used to identify the free radical-scavenging components from the flowers of this plant. The methanolic extract of the plant was first fractionated into four extracts; namely, n-hexane, chloroform, ethyl acetate and water fractions. Among them, the ethyl acetate fraction was found to be the most effective and was further subjected to activity guided-fractionation and isolation procedures. After successive column chromatography on silica gel and Sephadex LH-20, gallic acid, which is responsible for the radical scavenging activity, was isolated and its structure was elucidated by spectral methods ($^1H$ NMR, $^{13}C$ NMR) and by comparison with literature.

THE SCIENTIFIC BASIS OF THE PROCESS OF VEGETABLE JUICE SQUEEZINDG OUT OF LEAFSTALK BIOMASS

  • Proydak, N.I.
    • 한국농업기계학회:학술대회논문집
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    • 한국농업기계학회 1996년도 International Conference on Agricultural Machinery Engineering Proceedings
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    • pp.953-956
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    • 1996
  • The main regularities of the process of strain of the leafstalk boimass of the annual and parennial sown grasses (hard phase) with the simulataneous filtration of the vegetable juice (liquid phase) in the working members of the uninterrupted action(screw press) and the periodic action (Briqueting stamp press) were established . The engineering methods of calculation of the basic constructive -technological parameter of the pres equipment of the given types were worked out.

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경상분지 백악기 화산암류에 대한 암석화학적 고찰: 이원성 마그마의 가능성 (Petrochemical Study on the Cretaceous Volcanic Rocks in Kyeongsang Basin, Korea: Possibility of Magma Heterogeneity)

  • 성종규;김진섭;이준동
    • 자원환경지질
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    • 제31권3호
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    • pp.249-264
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    • 1998
  • The Creataceous volcanic rocks distributed in the southeastern part (Kyeongsang basin) of Korea peninsula are composed of basalt, basaltic andesite, andesite, dacite and rhyolite. The variation of major elements show that contents of MgO, CaO, $FeO^T$, $Al_2O_3$, $TiO_2$ and $P_2O_5$ decrease with increasing of $SiO_2$, but $K_2O$ contents are increased slightly, $Na_2O$ widely dispersed. We can show slightly inflection point and low frequency of dacites in range between 63-65 wt.% $SiO_2$, while continuous trend exit in variation diagram. Variation trends in Harker diagrams for the major, minor, trace and REEs suggest that the BAV (basaltic to andesitic volcanics) and DRV (dacitic to rhyolitic volcanics) are not related to a simple crystal fractionation process. In the regime of under 65 wt. % in silica content, fractionation of olivine and clinopyroxene is predominant, while that of plagioclase happens strongly higher than 65 wt.% (e.g., $SiO_2$, vs. Eu and Sr, MgO vs. $Al_2O_3$ and CaO). The latter means low-pressure fractional crystallization for DRV. On the discriminant diagram, DRV are located in more mature environment than BAV. The $(Ce/Sm)_N$ vs. CeN digram shows that these two classes cannot be related to crystal fractionation. If they had been produced by fractionation, although they plotted in a slightly elongate cluster along the same horizontal trend, DRV should lie to the right of these primitive compositions. These diagrams clearly rule out a simple fractionation throughout from BAV to DRV. BAV had been influenced greatly subductiong slab as shown by K/Yb vs. Ta/Yb. We suggest that BAV primitive magma generated higher degree of partial melting than DRV primitive magma. LILE (K, Ba, $Rb{\pm}Th$) enriched characteristics as shown in BAV are inherited from subducting slab fluids and/or higher degree of partial melting of mantle material. However, lower degree of partial melting of mantle relative to BA V and contamination at high-level magma reservoir caused LILE enrichment to DRV.

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다중모드 주성분분석에 기반한 천연가스 액화플랜트의 성분 분리공정 감시 시스템 개발 (Development of Monitoring System for the LNG plant fractionation process based on Multi-mode Principal Component Analysis)

  • 편하형;이철진;이원보
    • 한국가스학회지
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    • 제23권4호
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    • pp.19-27
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    • 2019
  • 세계 환경규제가 강화되면서 액화천연가스의 사용량이 지속해서 증가하고 있다. 안정적이고 효율적인 액화천연가스 생산을 위해서는 운전 조건을 세분화하여 감시하는 시스템 구축이 필수적이다. 본 연구에서는 천연가스 액화플랜트 성분 분리공정을 해석하여 구축한 동적 모델 데이터를 대상으로 다중 모드 감시시스템 개발 방법을 제안하였다. 먼저 전체 정상 데이터를 주성분분석과 k-평균 군집화 방법론을 사용하여 다중 정상 운전 모델로 구분하였다. 그 다음, 새로운 데이터 값을 k-최근접 알고리즘으로 구축된 다중 정상 모드와 매칭하였다. 마지막으로, 다중 모드 주성분분석 감시 기법을 통해 공정 데이터의 이상 여부를 판별하였다. 제시된 방법론은 45가지 이상경우에 적용하였고, 기본 주성분분석 방법론과 단변수 감시 방법론과의 비교를 통해 속도와 정확도 지표에서 평균 약 5~10%이상 우수함을 입증하였다.

파일럿 지료 조성설비를 이용한 폐 일회용 기저귀의 유용성분 회수에 관한 연구 (Studies on the Recovery of Useful Materials from Disposable Diaper Waste using Pilot Stock Preparation Units)

  • 이태주;남윤석;박정은;조준형;류정용;이호선
    • 펄프종이기술
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    • 제47권4호
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    • pp.66-75
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    • 2015
  • Disposable diaper waste is consisted of plastic, fiber, and SAP (Super Absorbent Polymer). They are valuable to be used as raw materials of other products including plastic blocks and pulp mold. Nevertheless, disposable diaper waste have been disposed by landfill and incineration without recycling. Due to strict environmental regulations it is necessary to develop fractionation technique to recycle the disposable diaper waste. In this study the fractionation technique using pilot-scale stock preparation units was investigated. Process for separation of plastic and fibers from disposable diaper waste was composed by the combination of pilot-scale pulper, drum screen, screen and cleaner. Recovery rate of plastics and fiber was checked according to the various operating conditions. In drum screen, recovery rate of plastic was high when the cut size of disposable diaper waste was $5cm{\times}5cm$. The highest recovery rate of fiber was achieved with 0.3 mm slot screen. It is important to control the neutral state of SAP for improvement of recovery rate of fiber since SAP can be swelled easily in water. Therefore SAP can be controlled efficiently by the addition of calcium chloride into the pulper. Consequently recovery rates of plastics and fibers were over 90 and 80% under the optimum pilot operating conditions.

[Retraction]Size measurement and characterization of ceria nanoparticles using asymmetrical flow field-flow fractionation (AsFlFFF)

  • Kim, Kihyun;Choi, Seong-Ho;Lee, Seungho;Kim, Woonjung
    • 분석과학
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    • 제32권5호
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    • pp.173-184
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    • 2019
  • As the size of semiconductors becomes smaller, it is necessary to perform high precision polishing of nanoscale. Ceria, which is generally used as an abrasive, is widely used because of its uniform quality, but its stability is not high because it has a high molecular weight and causes agglomeration and rapid precipitation. Such agglomeration and precipitation causes scratches in the polishing process. Therefore, it is important to accurately analyze the size distribution of ceria particles. In this study, a study was conducted to select dispersants useful for preventing coagulation and sedimentation of ceria. First, a dispersant was synthesized and a ceria slurry was prepared. The defoamer selection experiment was performed in order to remove the air bubbles which may occur in the production of ceria slurry. Dynamic light scattering (DLS) and asymmetrical flow field-flow fractionation (AsFlFFF) were used to determine the size distribution of ceria particles in the slurry. AsFlFFF is a technique for separating nanoparticles based on sequential elution of samples as in chromatography, and is a useful technique for determining the particle size distribution of nanoparticle samples. AsFlFFF was able to confirm the presence of a little quantities of large particles in the vicinity of 300 nm, which DLS can not detect, besides the main distribution in the range of 60-80 nm. AsFlFFF showed better accuracy and precision than DLS for particle size analysis of a little quantities of large particles such as ceria slurry treated in this study.

Performance of foam fractionator in seawater recirculating system

  • Lei Peng;Jo, Jae-yoon
    • 한국어업기술학회:학술대회논문집
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    • 한국어업기술학회 2003년도 춘계 수산관련학회 공동학술대회발표요지집
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    • pp.221-222
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    • 2003
  • Typically, closed production system units are subject to an accumulation of fine suspended solids and dissolved organics (Weeks et at., 1992). Foam fractionation process is believed to be most effective in marine application for solids removal. In present experiment, the performance of foam fractionator for removal of solids, protein, and other dissolved materials was evaluated at different foam overflow heights and air flow rates in a pilot-scale recirculating aquaculture system for culture of Korean rockfish. (omitted)

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두릅나무 근피의 혈당강하 성분에 관한 연구(I) -MeOH엑스 및 분획물의 혈당강하작용- (Antihyperglycemic Constituent of Aralia elata Root Bark(I) -Antihyperglycemic Action of ths Extract and Fractions-)

  • 이은방;김옥경
    • 생약학회지
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    • 제24권3호
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    • pp.213-218
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    • 1993
  • The methanol extract of Aralia elata root bark was found to decrease the blood glucose level in normal and alloxan-treated rats. The fractionation process confirmed positive activity in ethylacetate fraction. It is suggested that this fraction may show potent antihyperglyceimic activity through stimulation of insulin secretion.

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Bioactive Phenolic Constituents from the Culms of Phyllostachys bambusoides

  • Kim, Hyun-Jung;Kang, Min-Ah;Kim, So-Hyun;Yim, Soon-Ho;Lee, Ik-Soo
    • Natural Product Sciences
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    • 제17권4호
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    • pp.267-272
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    • 2011
  • In our search for bioactive phenolics from plants, the culms of Phyllostachys bambusoides has been selected for investigation of anti-cariogenic and 1,1-diphenylpicrylhydrazyl (DPPH) radical scavenging agents based on the initial screening results. Fractionation process of n-hexane and $CHCl_3$ extracts afforded four phenolic constituents, ferulic acid (1), vanillin (2), coniferaldehyde (3), and coniferyl alcohol (4) as guided by their DPPH free radical scavenging activities. Additionally, activity-guided fractionation of EtOAc extract with anti-cariogenic activity has resulted in the isolation of coniferaldehyde (3), 2,6-dimethoxy-p-benzoquinone (5), p-methoxycinnamic acid (6), (${\pm}$)-balanophonin (7), and 6-methoxychromanone (8). The structures of 1 - 8 were determined by spectroscopic data interpretation, and also by comparison of their data with the published values. Phenolic compounds 1 - 4 exhibited similar DPPH radical scavenging activities compared with the synthetic antioxidant, butylated hydroxytoluene (BHT), and compounds 3 and 5 - 8 showed significant antibacterial activity against cariogenic oral streptococci, Streptococcus mutans and S. sobrinus.