• Title/Summary/Keyword: Fouling mechanism

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Fouling characteristics of humic substances on tight polysulfone-based ultrafiltration membrane

  • Ariono, Danu;Aryanti, Putu T.P.;Wardani, Anita K.;Wenten, I.G.
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.353-361
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    • 2018
  • Fouling characteristics of humic substances on tight ultrafiltration (UF) membrane have been investigated. The tight UF membrane was prepared by blending polysulfone (PSf) in N.N-dimethylacetamide (DMAc) with 25%wt of Polyethylene glycol (PEG400) and 4%wt of acetone. Fouling characteristic of the modified PSf membrane was observed during peat water filtration in different trans-membrane pressure (TMP). It was found that the acetone modified membrane provided 13% increase in TMP during five hours of peat water filtration, where a stable flux was reached within 150 minutes. Meanwhile, the increase of TMP from 10 psig to 30 psig resulted in a fouling resistance enhancement of 60%. Furthermore, based on the fouling analysis, fouling mechanism at the first phase of filtration was attributed to intermediate blocking while the second phase was cake formation.

Fouling mechanism and screening of backwash parameters: Seawater ultrafiltration case

  • Slimane, Fatma Zohra;Ellouze, Fatma;Amar, Nihel Ben
    • Environmental Engineering Research
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    • v.24 no.2
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    • pp.298-308
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    • 2019
  • This work deals with the membrane fouling mode and the unclogging in seawater ultrafiltration process. The identification of the fouling mechanism by modeling the experimental flux decline was performed using both the classical models of Hermia and the combined models of Bolton. The results show that Bolton models did not bring more precise information than the Hermia's and the flux decline can be described by one of the four Hermia's models since the backwash interval is ${\leq}60$ min. An experimental screening study has been then conducted to choose among 5 parameters (backwash interval, duration, pulses and the flow-rate or injected hypochlorite concentration) those that are the most influential on the fouling and the net water production. It has emerged that fouling is mainly affected by the backwash interval; its prolongation from 30 to 60 min engenders an increase in the reversible fouling and a decrease in the irreversible fouling. This later is also significantly reduced when the hypochlorite concentration increases from 4.5 to 10 ppm. Moreover, the net water production significantly increases with increasing the filtration duration up to 60 min and decreases with decreasing the backwash duration and backwash flow-rate from 10 to 40 s and from 15 to ${\geq}20L.min^{-1}$, respectively.

Fouling evaluation on nanofiltration for concentrating phenolic and flavonoid compounds in propolis extract

  • Leo, C.P.;Yeo, K.L.;Lease, Y.;Derek, C.J.C.
    • Membrane and Water Treatment
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    • v.7 no.4
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    • pp.327-339
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    • 2016
  • Nanofiltration is useful to concentrate propolis extract. During the selection of membrane, both compound rejection and permeate flux are important indicators of process economy. Brazilian green propolis extract was studied to evaluate the separation performance of Startmen 122 and NF270 membranes. Compared to Starmen 122, NF270 membrane showed better rejection of bioactive compounds. The flux decline patterns were further studied using Hermia's model. Cake formation is the major fouling mechanism on the hydrophobic surface of Starmen 122. While the fouling mechanism for NF270 is pore blocking. The fouled membranes were further characterized using SEM and FT-IR to confirm on the predicted fouling mechanisms.

Hydraulic Cleaning Effect on Fouling Mechanisms in Pressurized Membrane Water Treatment (가압식 멤브레인 수처리에서 수리학적 세정이 파울링 기작에 미치는 영향)

  • Charfi, Amine;Jang, Hoseok;Kim, Jeonghwan
    • Membrane Journal
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    • v.27 no.6
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    • pp.519-527
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    • 2017
  • Membrane fouling is the main issue hindering the expansion of low pressure membrane processes for surface water treatment. Therefore, applying periodic hydraulic cleaning for fouling control should be well optimized. Better understanding of membrane fouling associated with periodic hydraulic cleaning would be useful to optimize membrane cleaning strategies. By comparing experimental permeability data with the classical Hermia blocking laws, this study aims at analyzing membrane fouling and understanding dominant fouling mechanisms occurring when filtering a synthetic surface water solution with a pressurized membrane process during six filtration cycles of 30 min each, separated with cyclic cleaning of 1 min by backwashing and forward flushing separately and combined. When applying single cleaning technique, membrane fouling during the first cycles was controlled by complete blocking mechanism while the last cycles were dominated by cake formation. Nevertheless, when combining cleaning technique better membrane regeneration was obtained and fouling was mainly due to cake formation.

Investigation of Al-hydroxide Precipitate Fouling on the Nanofiltration Membrane System with Coagulation Pretreatment: Effect of Inorganic Compound, Organic Compound, and Their Combination

  • Choi, Yang-Hun;Kweon, Ji-Hyang
    • Environmental Engineering Research
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    • v.16 no.3
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    • pp.149-157
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    • 2011
  • Nanofiltration (NF) experiments were conducted to investigate fouling of Al-hydroxide precipitate and the influence of organic compound, inorganic compound, and their combination, i.e., multiple foulants. $CaCl_2$ and $MgSO_4$ were employed as surrogates of inorganic compounds while humic acid was used as surrogate of organic compound. The flux attained from NF experiments was fitted with the mathematical fouling model to evaluate the potential fouling mechanisms. Al-hydroxide fouling with a cake formation mechanism had little effect on the NF membrane fouling regardless of the Al concentration. The NF fouling by Al-hydroxide precipitate was deteriorated in presence of inorganic matter. The effect of Mg was more critical in increasing the fouling than Ca. This is because the Mg ions enhanced the resistances of the cake layer accumulated by the Al-hydroxide precipitate on the membrane surfaces. However, the fouling with Mg was dramatically mitigated by adding humic acid. It is interesting to observe that the removal of the conductivity was enhanced to 61.2% in presence of Mg and humic acid from 30.9% with Al-hydroxide alone. The influence of dissolved matter (i.e., colloids) was more negative than particulate matter on the NF fouling for Al-hydroxide precipitate in presence of inorganic and organic matter.

Analyses of Fouling Mechanism using Visualization Techniques in a Lab-scale Plate-Type Heat Exchanging System (실험실용 판형 열교환 시스템에서 가시화를 이용한 파울링 기구 해석)

  • 성순경;서상호;노형운
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.4
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    • pp.349-354
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    • 2004
  • Scale is formed when hard water is heated or cooled in heat transfer equipments such as heat exchangers, condensers, evaporators, cooling towers, boilers, and pipe walls. When the scale deposits in a heat exchanger surface, it is conventionally called fouling. The objective of the present study is to analyze the process of the fouling formation in a heat exchanger according to different types of water using visualization techniques. In order to experimentally investigate the formation of the fouling, this study built a lab-scaled heat exchanging system. Using the visualization techniques of Scanning Electron Microscopy (SEM) and X-Ray diffraction method, the three dimensional configurations of the fouling formation could be successfully obtained. Based on the experimental results, it was found that the configurations of the fouling formation were different when using tap water compared to river water.

Prediction of Compressor Fouling Using an Analytic Method (해석적 방법을 통한 압축기의 파울링 해석)

  • Song, Tae Won;Kim, Tong Seop;Kim, Jae Hwan;Ro, Sung Tack
    • 유체기계공업학회:학술대회논문집
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    • 2000.12a
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    • pp.176-183
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    • 2000
  • The performance of gas turbines decreases as their operating hours increase. Compressor fouling is the main reason for this time-dependent performance degradation. Airborne particles adhere to the blade surface and results in the change in the blade shape. It is difficult to exactly analyze the mechanism of the compressor fouling because the growing process of the fouling is very slow and the dimension of the fouled depth is very small compared with blade dimensions. In this study, an analytic method to predict the motion of particles and their deposition inside axial flow compressors is proposed. The analytic model takes into account the blade shape and the flow within the blade passage. Comparison of simulation result with field data shows the feasibility of the model. Influence of the particle distribution on the compressor fouling is also examined.

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Fouling Mechanism of Microfiltration/Ultrafiltration by Macromolecules and a Suppression Strategy from the Viewpoint of the Hydration Structure at the Membrane Surface

  • Akamatsu, Kazuki;Nagumo, Ryo;Nakao, Shin-ichi
    • Membrane Journal
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    • v.30 no.4
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    • pp.205-212
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    • 2020
  • This short review focuses on fouling by proteins and macromolecules in microfiltration/ultrafiltration. First, an experimental system that enables investigation of how the extent of the adsorption of proteins and macromolecules on membrane surfaces contributes to a decrease in filtrate flux in microfiltration/ultrafiltration is described. Using this system, a causal relationship - not a correlation - indicating that adsorption results in a decrease in filtrate flux could be clearly demonstrated in some cases. Second, a hydration structure at the membrane surface that can suppress adsorption is discussed, inspired by biomaterial research. In their hydrated states, polymers with low-fouling properties have water molecules with a particular structure. Finally, some successful examples of the development of low-fouling membranes via surface modification using low-fouling polymers are discussed.