• Title/Summary/Keyword: Formamide

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Study on Bond Used in Shoes Manufacturing Industry (신발제조업체에서 사용되는 접착제에 관한 연구)

  • Park, D.H.;Moon, D.H.;Lee, C.U.
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.1 no.2
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    • pp.200-213
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    • 1991
  • ln order to acquire the fundamental data for the organic solvents in bond and to contribute the health improvement of workers in deprtment of organic solvents in shoes manufacturing industries. The authors surveyed the contents of organic solvent in adhesive and determined the amount of volatilization of organic solvent by time and temperature with gaschromatography from March to September 1990. The results were as follows; 1) The kinds for organic solvents in bond were 9 that was Toluene, C-Hexane, N-Hexane, C-Hexanon, Aceton, Methyl Ethyl Keton, Dimethyl Formamide, Etyly Acetate. 2) Toluene and Methyl Ethyl Keton among the organic solvents in adhesive were over 80.18%. 3) The amount of volatilization of Methyl Cyclohexanone and Aceton by time and temperature were the most level than other compounds.

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Microwave Heat Dyeing of Polyester Fabric

  • Kim, Sam-Soo;Lee, Su-Gyung m;Ghim, Han-Do;Kim, Joon-Ho;Lyoo, Won-Seok
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.204-209
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    • 2003
  • The effect of padding solution on the microwave heat dyeing of polyester fabric was studied extensively. Polyester fabrics were impregnated in aqueous urea solution and aqueous sodium chloride solution for 10 min and then dyed for 7 min by microwave apparatus (2450 MHz, 700 W) under optimum conditions which provide good exhaustion. Aqueous solutions of urea and sodium chloride showed more effective than water as a padding solution for microwave heat dyeing. The type of solvent added in padding media and its concentration significantly affects the K/S values of dyed polyester fabric. Added solvents such as n-hexane, acetone, and dimethyl formamide were also more effective than 100 % water as padding media for the microwave heat dyeing. It is supposed that the effect of used solvents on dyeing property of polyester fabrics depends on the solubility parameter difference between solvent and polyester fabric.

Solution behavior of PS-PEG-PS triblock copolymer in DMF and Benzene (DMF와 Benzene에서 PS-PEG-PS의 solution거동)

  • Kim, Eun-Sub;Kim, Byoung-Chul;Ahn, Sung-Kook;Cho, Chang-Gi
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.179-180
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    • 2003
  • ABA triblock copolymer made up of long middle block(B) and sho.1 terminal blocks(A) is being widely used as thermoplastic elastomers. Block copolymers with non-polar hydrophobic polystyrene and polar hydrophilic poly(ethylene glycol) blocks has been prepared and the physical properties of the solutions of PS-PEG-PS in polar (dimethyl formamide, DMF) and non-polar solvent (benzene) were investigateded[-3]. (omitted)

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Preparation of Poly(imide)-based Carbon Fiber web from PMDA-ODA Poly(amic acid) solution (PMDA-ODA poly(amic acid) 용액의 전기방사에 의한 폴리이미드계 탄소섬유 웹의 제조)

  • 최영옥;임대영;변성원;양갑승
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.130-133
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    • 2003
  • 폴리이미드(poly(imide), PI)는 반복 단위 내에 이미드 그룹을 함유하고 있는 고분자로 매우 강한 물리적인 특성을 지니며 열적 및 화학적 안정성이 매우 큰 고분자이다[1-4]. 그러나 이는 대부분이 불용ㆍ불융하기 때문에 프리커서인 poly(amic acid) (PAA) 용액 상태에서 어느 특정한 형태로 가공한 후 열적 혹은 화학적 방법에 의해 이미드 구조로 전환시켜준다. PAA 용액에 사용되는 용매로는 N,N-dimethylacetamide (DMAc), N-methyl-2-pyrrolidone (NMP), N,N-dimethyl-formamide(DMF) 등과 같이 비등점이 높은 극성 용매들이 사용되어진다. (중략)

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Temperature, Medium and Structural Effects on the Acid Dissociation Constants of Certain Schiff Bases Derived from Isatin with Some Amino Acids and Aroylhydrazines

  • Hassaan, Aly M.A.;Quenawy, M.T.A.
    • Archives of Pharmacal Research
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    • v.16 no.3
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    • pp.180-185
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    • 1993
  • The acid dissociation constants of certain Schiff bases derived from isatin with p-substituted benzoyl hydrazines and somee amino acids of glycine, $\beta$-and $\alpha$-alanine, valine, $\beta$-phenyl-$\alpha$-alanine and anthranilic acid have been detemined potentiometrically at different temperatures in different aquo-organic solvent mixtures (ethnol, dioxane, dimethyl formamide, methanol, acetone and tetrahydrofurance). The pKa values were demonstrated on the light of the different electornic and steric effects of the substituents and the sovlent characteristics. In all the mixed media used, ionization of the compounds decreased by increasing the mole fraction of the organic cosolvent. Theemodynamic parameters $(\Delta{H}^\circ,\;\Delta{G}^\circ,\;\Delta{S}^\circ)$ were evaluated. The structural effects of the investigated compounds on these parameters were reported and discussed.

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Synthesis of Some New Condensed Pyrimidine Derivatives

  • Mohamed, Enaiat K.;Shehab, Wesam S.
    • Journal of the Korean Chemical Society
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    • v.55 no.6
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    • pp.988-993
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    • 2011
  • Cyclodehydration of 6-amino-5-cyano pyrimidine derivative (2) afforded pyrimidoisoindole derivatives (3). Compound (3) reacted with carbethoxymethylene derivative to give pyridopyrimidine derivatives (5a,b). Compound (3) was also reacted with formamide to give the corresponding pyrimidopyrimdine derivatives (6) that condensed with benzaldehyde to give Schiff's base (7). Refluxing of compound (3) with triethyl orthoformate afforded compound (8) that cyclized with ammonium hydroxide giving the same compound (6). Compound (8) cyclized with hydrazine hydrate giving compound (9) which also cyclized with triethyl orthoformate affording compound (10). Diazotization of compound (3) led to the formation of triazinopyrimidine derivative (11). Cyclization of compound (11) upon treatment with hydrazine hydrate afforded compound (12). Compound (15) was prepared from reaction of compound (3) and ethylenediamine in presence of carbon disulfide. The behaviour of compound (15) toward benzoyl chloride, triethyl orthoformate, nitrous acid and/or carbon disulfide was also described. All proposed structures were supported by elemental analyses, spectroscopic data and some of the new products showed antimicrobial activity.

NMR Studies on the Isomerization of Vanadium(V)-Propylenediaminetetraacetate Complex in Solution

  • Han, Sang-Gyu;Park, Sam-Soo;Lee, Man-Ho;Park, Heai-Ku
    • Bulletin of the Korean Chemical Society
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    • v.25 no.1
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    • pp.106-108
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    • 2004
  • In this paper we have determined the thermodynamic parameters for the isomerization between the ${\alpha}$-cis and the ${\beta}$-cis isomers in vanadium(V)-propylenediaminetetraacetate complex in water by $^{51}V$ NMR spectroscopy. In addition, the effects of organic solvents (methanol, formamide and dimethylsulfoxide) and inorganic salts (NaCl, $NaClO_4\;and\;NH_4Cl$) on the isomerization in solution have been investigated.

The study on Cr-C alloy electroplating and its characteristics (Cr-C합금 도금층 제조 및 특성 연구)

  • 김동수;김만;박상언;남기석;장도연;권식철;신동수
    • Journal of the Korean institute of surface engineering
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    • v.34 no.1
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    • pp.49-55
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    • 2001
  • The addition of organic compound containing -COOH, X$800_2$, -CHO group such as formic acid, formamide, formaldehyde or diethyleneamine to a chromium electroplating bath results in a chromium deposit in which carbon is incorporated. Such deposits have fewer defects than chromium layers produced by a conventional method. It was found that the as-deposited layers were amorphous and auger electron spectroscopy (AES) showed that carbon is distributed uniformly in the deposit. During heat treatment, Cr-C deposits began to crystallize at $400^{\circ}C$, and at $800^{\circ}C$ they were crystallized into chromium carbides and oxides. The effects of current density, amount of additives, applied current waveform on Cr-C alloy electroplating were examined.

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Enhanced Dispersion of Multi-Walled Carbon Nanotubes by Polydimethylsiloxane Coating and Its Application

  • Yoon, Hye Soo;Jeong, Myung-Geun;Kim, Kwang-Dae;Kim, Dae Han;Park, Eun Ji;Kim, Young Dok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.279-279
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    • 2013
  • We report on the preparation of polydimethylsiloxane (PDMS) coated multi-walled carbon nanotubes (MWNTs) followed by their dispersion in various solvents. To disperse MWNTs without acids of surfactants, which are the commonly used methods, hydrophobic PDMS coating was selected. It was determined that the PDMS coated MWNTs are more dispersed in diverse solvents such as dimethyl formamide (DMF) and acetone than bare MWNTs. In case of DMF solvent, dispersion of MWNT was improved by 40 % upon PDMS-coating of MWNT, which was confirmed by UV/Vis absorption spectroscopy. In this work, the PDMS coated MWNTs dispersed solution was also used for the fabrication of film, which is conductive, transparent and superhydrophobic because of the reduced aggregation and increased water repellency of MWNTs.

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Enhencement of Specificity of PCR Amplification of GC-rich Mycobacterium paratuberculosis DNA by Denaturants (Denaturant에 의한 Mycobacterium paratuberculosis DNA의 PCR 증폭의 특이성 증진)

  • Kim Doo;Chang Yung-fu
    • Journal of Veterinary Clinics
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    • v.12 no.1
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    • pp.905-910
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    • 1995
  • GC 함유량(72%)이 높은 Mycobacterium paratuberculosis의 DNA의 PCR 증폭시 특이성과 생산성을 높이기 위하여 PCR 반응액에 denaturant인 DMSO, glycerol, formamide, Tween 20과 NP 40를 첨가하였다. Denaturant를 첨가하지 않은 상태의 PCR에서는 다수의 비특이적인 DNA가 관찰되었으며 표적 DNA 생산량이 낮았다. 모든 denaturant는 PCR의 특이성과 생산물의 생산량을 증가시했으며, 이들 중 DMSO, glycerol, farmamide와 NP 40는 높은 농도에서 생산량을 증가시켰다. Tween 20은 낮은 농도에서 생산량을 증가시켰다. Denaturant를 첨가하였음에도 불구하고 대부분의 반응에서 1 또는 2개의 비특이적인 DNA가 관찰되었다.

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