• 제목/요약/키워드: Foam Volume

검색결과 150건 처리시간 0.026초

가교제의 종류가 천연고무 발포체의 팽윤거동에 미치는 효과 (Influence of the Type of Curing Agent on Swelling Behavior of Natural Rubber Foam)

  • 이환광;정태경;김성찬;김현기;최경만;김영민;한동훈
    • 한국산학기술학회논문지
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    • 제9권6호
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    • pp.1775-1781
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    • 2008
  • 가교제의 종류가 헬리콥터 연료탱크의 자기밀폐층 소재로 적용시키기 위한 천연고무 스폰지의 팽윤에 미치는 효과를 조사하였다. 과산화물과 황을 섞은 가교방식과 과산화물에 의한 가교방식을 채택하였다. 천연고무 콤파운드를 Kneader와 Roll-Mill을 활용하여 제조하고, 고압조건의 프레스에서 부분 가교시킨 후 대기압의 금형에서 발포와 완전가교를 실시하였다. 얻어진 스폰지의 겉보기밀도를 측정하고 스폰지의 셀구조를 주사전자현미경을 통하여 관찰하였다. 톨루엔, 이소옥탄과 항공유를 사용하여 실온에서 팽윤실험을 실시하였다. 용매에 2분 동안 침적 후 얻어지는 부피팽윤비 값은 과산화물 가교에 의한 천연고무 스폰지가 비슷한 양의 황과 과산화물의 혼합가교에 의한 경우보다 높았다. 스폰지의 겉보기밀도와 셀구조는 과산화물 함량에 매우 민감하였으며 이는 또한 천연고무 스폰지의 팽윤거동에 영향을 미쳤다. 천연고무 스폰지가 연료와 접촉하여 신속한 팽윤이 얻어지기 위하여 금형에서 동시에 발생하는 두 가지 반응인 발포제의 분해반응과 천연고무의 가교반응을 적절히 조절하는 것이 중요하다.

Dietary crude protein levels during growth phase affects reproductive characteristics but not reproductive efficiency of adult male Japanese quails

  • Retes, Pamela Lacombe;Neves, Danusa Gebin das;Bernardes, Laryssa Fernanda;Alves, Victoria Veiga;Goncalves, Natalia de Castro;Lima, Diego de Rezende;Alvarenga, Renata Ribeiro;Pereira, Barbara Azevedo;Seidavi, Alireza;Zangeronimo, Marcio Gilberto
    • Animal Bioscience
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    • 제35권3호
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    • pp.385-398
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    • 2022
  • Objective: The objective was to evaluate the influence of different dietary crude protein (CP) levels during the growth phase on reproductive characteristics and reproductive efficiency as well as the body development of adult male Japanese quail. Methods: Three hundred one-day-old male quails were distributed into five treatments with diets containing different CP levels (18%, 20%, 22%, 24%, and 26%) in a completely randomized design, with six replicates of ten birds each. The CP diets were applied only during the growth phase (1 to 35 days). At 36 days of age, the birds were transferred to 30 laying cages with three males and nine females each, and all birds received the same diet formulated to meet production-phase requirements until 96 days of age. Results: The growth rate of the birds increased linearly (p<0.01) with increasing dietary CP, but the age of maximum growth decreased (p<0.05). At growth maturity, all birds had the same body weight (p>0.05). At 35 days of age, higher weight gain was obtained (p<0.05) with diets containing 22% CP or higher. No effects on feed conversion were observed in this phase. The increase in dietary CP enhanced (p<0.01) nitrogen intake and nitrogen excretion but did not affect (p>0.05) nitrogen retention. Testis size, seminiferous tubular area, number of spermatogonia, and germinal epithelial height at 35 days of age increased linearly (p<0.05) with dietary CP, while the number of Leydig cells decreased (p<0.01). The Sertoli cell number at 60 days of age increased linearly (p<0.01) with dietary CP. Dietary CP levels did not affect cloacal gland size, foam weight, foam protein concentration, semen volume, or flock fertility at 90 days of age. Conclusion: Dietary CP concentration affected body and testicular development in male Japanese quails but did not affect reproductive efficiency.

가소성 경량기포콘크리트의 배합비 변화에 따른 공학적 특성 (Engineering Characteristics of Plasticizer Lightweight Foamed Concrete according to Changes of Mixing Ratio)

  • 서두원;김혜양;김경민;천병식
    • 한국지반환경공학회 논문집
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    • 제11권4호
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    • pp.33-42
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    • 2010
  • 구조물 뒤채움재로서 하중경감을 위해 사용되는 경량기포콘크리트는 기포의 소포작용에 의해 체적이 감소하여 재주입하는 문제점이 있다. 따라서 본 연구에서는 체적의 감소 문제를 보완하고자 가소제를 첨가한 가소성 경량기포콘크리트를 제작하였고, 공학적 특성을 실험적으로 규명하고자 하였다. 가소성 경량기포콘크리트의 공학적 특성을 파악하기 위해 배합요소들의 변화에 따른 일축압축강도, 단위중량, flow, pH, 투수시험에 대한 연구를 진행하였다. 실험결과로부터 가소제의 첨가에 따른 공학적 특성을 비교 분석하였고, 에트링자이트의 생성으로 인하여 flow값에 가장 큰 영향을 주는 것으로 나타났다. 가소제의 적정 첨가량은 2~2.4%정도가 적당할 것으로 판단되며, 구조물 배면의 충전재료로 사용하여 하중 경감측면과 재료의 과도한 유동성에 의한 안정성 증가에 큰 효과가 있을 것으로 판단된다.

탄소 전극 형상 변화에 따른 전기화학 커패시터 특성 향상 (Improvement of Electrochemical Characteristics by Changing Morphologies of Carbon Electrode)

  • 민형섭;김상식;정덕수;최원국;오영제;이전국
    • 한국재료학회지
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    • 제19권10호
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    • pp.544-549
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    • 2009
  • Activated carbon (AC) with very large surface area has high capacitance per weight. However, such activation methods tend to suffer from low yields, below 50%, and are low in electrode density and capacitance per volume. Carbon NanoFibers (CNFs) had high surface area polarizability, high electrical conductivity and chemical stability, as well as extremely high mechanical strength and modulus, which make them an important material for electrochemical capacitors. The electrochemical properties of immobilized CNF electrodes were studied for use as in electrical double layer capacitor (EDLC) applications. Immobilized CNFs on Ni foam grown by thermal chemical vapor deposition (CVD) were successfully fabricated. CNFs had a uniform diameter range from 50 to 60 nm. Surface area was 56 m$^2$/g. CNF electrodes were compared with AC and multi wall carbon nanotube (MWNT) electrodes. The electrochemical performance of the various electrodes was examined with aqueous electrolyte of 2M KOH. Equivalent series resistance (ESR) of the CNF electrodes was lower than that of AC and MWNT electrodes. The specific capacitance of 47.5 F/g of the CNF electrodes was achieved with discharge current density of 1 mA/cm$^2$.

Buckling and vibration analyses of MGSGT double-bonded micro composite sandwich SSDT plates reinforced by CNTs and BNNTs with isotropic foam & flexible transversely orthotropic cores

  • Mohammadimehr, M.;Nejad, E. Shabani;Mehrabi, M.
    • Structural Engineering and Mechanics
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    • 제65권4호
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    • pp.491-504
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    • 2018
  • Because of sandwich structures with low weight and high stiffness have much usage in various industries such as civil and aerospace engineering, in this article, buckling and free vibration analyses of coupled micro composite sandwich plates are investigated based on sinusoidal shear deformation (SSDT) and most general strain gradient theories (MGSGT). It is assumed that the sandwich structure rested on an orthotropic elastic foundation and make of four composite face sheets with temperature-dependent material properties that they reinforced by carbon and boron nitride nanotubes and two flexible transversely orthotropic cores. Mathematical formulation is presented using Hamilton's principle and governing equations of motions are derived based on energy approach and applying variation method for simply supported edges under electro-magneto-thermo-mechanical, axial buckling and pre-stresses loadings. In order to predict the effects of various parameters such as material length scale parameter, length to width ratio, length to thickness ratio, thickness of face sheets to core thickness ratio, nanotubes volume fraction, pre-stress load and orthotropic elastic medium on the natural frequencies and critical buckling load of double-bonded micro composite sandwich plates. It is found that orthotropic elastic medium has a special role on the system stability and increasing Winkler and Pasternak constants lead to enhance the natural frequency and critical buckling load of micro plates, while decrease natural frequency and critical buckling load with increasing temperature changes. Also, it is showed that pre-stresses due to help the axial buckling load causes that delay the buckling phenomenon. Moreover, it is concluded that the sandwich structures with orthotropic cores have high stiffness, but because they are not economical, thus it is necessary the sandwich plates reinforce by carbon or boron nitride nanotubes specially, because these nanotubes have important thermal and mechanical properties in comparison of the other reinforcement.

토코페롤에서 유도된 기능성 화장품용의 새로운 계면 활성제 (Polyoxyethylene Tocopheryl Ethers; A Series of Novel Surfactants from Tocopherol for Functional Cosmetics)

  • 김영대;김창규
    • 대한화장품학회지
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    • 제18권1호
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    • pp.1-41
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    • 1992
  • A new and unique class of nonionic surfactants was synthesized by reacting biological a-tocopherol with ethylene oxide for functional cosmetics. The structures were confirmed by Hl-UMR, FT-lR, TLC and elemental analysis. POV and conjugated diene value study for EPO showed POE(n)TE had antioxidative effect similar to tocopheryl acetate Protective effect on cell membrane in photohemolysis of POE(5)TE, POE(10)TE and POE(18)TE were slightly lower than tocopherol but higher than nonoxynol-12, and POE(10)TE had UV absorption power comparable with tocopherol and homosalate. Biological activity of the hydrophobic group of the new surfactants make them unique and different from those of conventional nonionic surfactants Systematic safety evaluations of POE(n)TEs on the skin and eye proved that they are as safe as tocopherol. The results of physicochemical study showed POE(10)TE had the lowest CMC value, POE(18)TE had the maximum surface tension reduction and the highest foam volume and POE(n)TEs had various HLB values by the degree of ethoxylation. The test resul Is of technological and practical applications of these surfactants for cosmetics showed some POE(n)TEs were superior to conventional surfactants. POE(5)TE in W/O emulsions, POE(10)TE and POE(12)TE in O/W emulsions, POE(12)TE in dispersions, POE(18)TE in solubilizations and POE(50)TE in gelations were shown to be excellent which was considered due to the structural characteristic and formation of liquid crystals of POE(n)TEs. By the development and applications of these excel lent multi-functional surfactants, innovative functional cosmetics were successfully formulated.

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건물용 고분자 전해질 연료전지 금속분리판 유동장 형상 변화에 따른 산소 확산 특성에 대한 연구 (A Study on Oxygen Diffusion Characteristics According to Changes in Flow Field Shape of Polymer Electrolyte Membrane Fuel Cell Metallic Bipolar Plate for Building)

  • 박동환;손영준;최윤영;김민진;홍종섭
    • 한국수소및신에너지학회논문집
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    • 제32권4호
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    • pp.245-255
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    • 2021
  • Various studies about metallic bipolar plates have been conducted to improve fuel cell performance through flow field design optimization. These research works have been mainly focused on fuel cells for vehicle, but not fuel cells for building. In order to reduce the price and volume of fuel cell stacks for building, it is necessary to apply a metallic flow field, In this study, for a metallic flow field applied to a fuel cell for building, the effect of a change in the flow field shape on the performance of a polymer electrolyte membrane fuel cell was confirmed using a model and experiments with a down-sizing single cell. As a result, the flow field using a metal foam outperforms the channel type flow field because it has higher internal differential pressure and higher reactants velocity in gas diffusion layer, resulting in higher water removal and higher oxygen concentration in the catalyst layer than the channel type flow field. This study is expected to contribute to providing basic data for selecting the optimal flow field for the full stack of polymer electrolyte membrane fuel cells for buildings.

람노리피드의 계면특성 및 액체세정제에서의 기능에 대한 연구 (Study on the Surface Activity of Rhamnolipid (RL) and Function of RL in Liquid Detergent)

  • 지경엽;임종주
    • 공업화학
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    • 제29권6호
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    • pp.753-758
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    • 2018
  • 미생물 발효 생계면활성제인 람노리피드의 계면활성(CMC, 표면장력, 기포력 등)을 측정하였다. 람노리피드는 우수한 표면활성을 나타내었다. 람노리피드가 처방된 세정제도 우수한 표면활성을 나타내었다. 액체세정제의 성능평가 결과 지방산 대비 람노리피드가 사용된 제품의 성능이 미세하게 우세하였다. 그렇지만 기포 프로화일에서는 람노리피드가 처방된 제품의 기포량이 아주 많았으며, 헹굼과정에서 지방산의 억포작용과 같은 헹굼성 보조 작용은 나타나지 않았다. 람노리피드는 생계면활성제로써 주계면활성제 또는 보조계면활성제로써 사용될 수 있을 것이다. 그러나 지방산과 같은 억포제 또는 헹굼 보조 기능은 가지지 않은 것으로 판단된다.

화장품 산업의 대중국 수출전략에 관한 연구: 관세 및 비관세조치 대응전략 수립을 중심으로 (A Study on the Export Strategy of China to the Cosmetic Industry: Focus on Countermeasures against Tariffs and Non-Tariff Measures)

  • 정우경;이서영;김태인
    • 아태비즈니스연구
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    • 제11권1호
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    • pp.145-165
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    • 2020
  • Purpose - The purpose of this study is to suggest strategies and solutions for entering China in the tariff and non-tariff sectors of the cosmetic industry. Design/methodology/approach - This study analyzed the import tariff rate of cosmetics in China, and analyzed the export cost by actually interviewing the exporting companies to derive the economic effect of non-tariff measures. Findings - First, We proposed the use of the FTA business model (basic cosmetics), the use of Korea-China FTA tariffs (foam cleansing, toothpaste), and the use of APTA tariffs (perfume). Second, We proposed cooperation between the governments to facilitate customs clearance procedures and improvement of FTA awareness among corporate practitioners. Third, We proposed the expansion and support of the AEO MRA system and the expansion of Korea-China MOU conclusions regarding the certification system, and the international standardization of domestic licensing system and technical conditions. Fourth, We proposed the use of government-supported projects related to obtaining overseas certifications and overseas expansion through collaboration with the same industry. Research implications or Originality - HS3304 products excluded from the Korea-China FTA should take full advantage of the FTA business model. In addition, the non-tariff measure costs are fixed costs per year, so the ratio decreases as the number of exports and export volume increases.

잠긴수제가 설치된 만곡수로에서의 이차류 거동 수치모의 (Numerical modeling of secondary flow behavior in a meandering channel with submerged vanes)

  • 이정섭;박상덕;최철희;백중철
    • 한국수자원학회논문집
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    • 제52권10호
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    • pp.743-752
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    • 2019
  • 만곡수로에서의 흐름은 나선형 운동 형태의 이차류가 지배적이며, 이로 인해 일반적으로 만곡 외측을 따라 침식 현상이 발생하게 된다. 이러한 이차류를 약화시키기 위해서 보통 만곡수로 외측을 따라서 수제와 같은 수공구조물을 설치한다. 이 연구에서는 OpenFOAM 오프소스 소프트웨어를 토대로 난류 해석을 위한 하이브리드 RANS/LES 기법과 자유수면 해석을 위한 VoF기법을 이용한 3차원 수치모의를 통해서 $90^{\circ}$ 만곡수로에 설치된 잠긴수제가 후루드수가 0.43인 조건에서 이차류의 발달에 미치는 영향을 분석하였다. 시간과 공간에 대해서 2차 정확도의 유한체적법을 이용하여 수치모의를 수행하였으며, 수치해석 결과는 실험결과와 비교하여 수치모의의 정확도를 평가하였다. 잠긴수제가 설치된 경우의 수치모의 결과를 흐름방향 유속 분포와 횡방향 순환 유속벡터장을 중심으로 수리실험 관측값들과 비교할 때 수치모의 결과는 수리실험에서 관측된 주요 이차류 흐름 거동과 현상들을 대부분 양호한 정확도로 잘 재현하는 것으로 나타났다. 수치모의 결과를 비교해보면, 잠긴수제 설치로 인해서 만곡이 끝나는 단면 외측 하상부근에서의 유속은 약 평균유속의 1/3 정도 감소하는 반면에 수제 상단부에서의 전단층 발달에 따른 흐름 가속으로 자유수면 부근까지 유속이 증가하고 만곡 수충부에서는 수면 부근 유속이 약 20% 증가하는 것으로 나타났다. 결과적으로 잠긴수제는 만곡부에서 발생하는 이차류의 강도를 약화시켜 만곡부 외측 하상의 안정에 도움이 될 것으로 판단된다. 한편, 각 잠긴수제 전면부에서 말발굽와가 그리고 후면부에서는 후류가 형성되면서 수제 구조물 주변에서 강한 국부세굴이 발생하는 것으로 나타남으로, 국부세굴을 최소화할 수 있는 수제의 형상 및 배열에 대한 추가 연구가 요구된다.