• Title/Summary/Keyword: Fly slag

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Microstructural Characteristics of Alkali-Activated Cements Incorporating Fly Ash and Slag (플라이애시와 슬래그 혼합 알칼리 활성 시멘트의 미세구조 특성)

  • Jang, Jeong Gook
    • Journal of Urban Science
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    • v.7 no.1
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    • pp.39-43
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    • 2018
  • This study investigates microstructural characteristics of alkali-activated cements incorporating slag and fly ash. Samples were prepared with four fly ash:slag ratios, i.e., 100:0, 90:10, 70:30 and 50:50, and they were synthesized by using an alkali activator. Microstructural characteristics of the alkali-activated cements were determined by XRD, TGA, SEM, N2 gas adsorption/desorption methods, and compressive strength test. The results showed that properties of alkali-activated fly ash/slag were significantly affected by slag contents. Alkali-activated fly ash/slag with slag content of 30-50% showed higher compressive strength than ordinary Portland cement paste. An increase in slag content resulted in a denser microstructure, which composed of amorphous gel, therefore contributed to strength development of the material.

Properties of Self-Compacting Concrete Using Ground Granulated Blast Furnace Slag and Fly ash (고로슬래그미분말 및 플라이애쉬를 사용한 고유동콘크리트의 특성에 관한 연구)

  • 김은겸;박천세;최재진;전찬기;이호석
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.89-94
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    • 2003
  • In this research, the physical properties of self compacting concrete using ground granulated blast furnace slag and fly ash as a part of cement were investigated. Concrete using ground granulated blast furnace slag and fly ash was prepared with various ground granulated blast furnace slag(30-50 volume %) and fly ash(10-20 volume %) replacement for cement. The effect of each of the materals, which have effects on self compacting concrete made by the basic mix proportion used granulated blast furnace slag and fly ash after hardening, has been checked. The workability, flowing characteristics, resistance of segregation of materals, air content, and compressive strength of concrete using ground granulated blast furnace slag and fly ash were tested and the results were compared with those of ordinary portland cement concrete. In the experiment, we acquired satisfactory results at the point of flowing characteristics and strengths of concrete using ground granulated blast furnace and slag fly ash within the replacement ratio of 65%

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An Experimental Study on the Setting Time and Compressive strength of Mortar using Ferronickel Slag Powder (페로니켈슬래그 미분말을 사용한 모르타르의 응결시간 및 압축강도특성에 관한 실험적 연구)

  • Kim, Young-Uk;Kim, Do-Bin;Choi, Se-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.551-558
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    • 2018
  • This study evaluate the fluidity and hardening properties of mortar by replacement ratio of ferronickel slag powder to estimate the applicability of ferronickel slag powder for cement replacement materials. Ferronickel slag powder was replaced by 0, 5, 10, 15 and 20% of the cement weight. In addition, blast furnace slag powder and fly ash were also used for comparing with the mixtures using ferronickel slag powder. As the test results, the micro-hydration heat of the mixture containing the ferronickel slag powder was lower than that of the mixtures containing the same amount of blast furnace slag powder and fly ash. The flow of the sample with ferronickel slag powder was relatively higher than the other mixtures. In all ages, the compressive strength of the mixture with ferronickel slag powder and fly ash was similar to that of the mix containing only fly ash. In case of drying shrinkage, the mixture containing ferronickel slag powder exhibited lower drying shrinkage than the mixture using blast furnace slag powder, and similar to the mixture containing fly ash.

Effect on Ferronickel Slag Powder in ASR (페로니켈 슬래그 미분말이 ASR에 미치는 영향)

  • Kim, Min-Seok;Seo, Woo-Ram;Rhee, Suk-Keun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.1
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    • pp.9-14
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    • 2022
  • Most of the existing research on ferronickel slag has focused on its potential as aggregate and fine aggregate, this study was conducted focusing on the potential of ferronickel slag powder as a concrete admixture. For concrete, which fly ash, blast furnace slag, and FSP were mixed with each 10 % type the reactivity was evaluated by applying ASTM C 1260 of the United States. As a result, compared with the control group, the expansion rate of fly ash decreased by 8.43 % and that of fine blast furnace slag powder decreased by 14.46 %, while the expansion rate of ferronickel slag decreased by 49.40 %. it was confirmed that ferronickel slag can sufficiently be replaced existing supplementary cementitious admixtures such as fly ash and blast furnace slag in terms of suppressing the reactivity of aggregates. However as a result of SEM analysis, ettringites were generated, and additional research about how it affects concrete is needed.

Fly ash-Slag-Cement Composite

  • Bang, Wan-Keun;Lee, Seung-Kyou;Lee, Seung-Heun;Kim, Chang-Eun
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.286-290
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    • 2000
  • The hydration behavior of fly ash and slag on cement paste were investigated. Early stage of hydration reaction was delayed by mixing fly ash and/or slag with cement, but production of C-S-H hydrates by pozzolanic reaction densified the microstructure. The Ca/Si ratio of C-S-H hydrates in OPC and blended cement of fly ash 50%, slag 50%, fly ash+slag 50% were 2.24, 1.80, 1.82 and 1.97, respectively. The C-S-H gel with low Ca/Si ratio showed rather reticulate than needle-like structure.

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A Fundermental Study Color Removal of Dyeing Wastewater using Low Cost Adsorbents (저가흡착제를 이용한 염색폐수의 색도제거에 관한 기초 연구)

  • 김은호;장성호
    • Journal of environmental and Sanitary engineering
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    • v.14 no.2
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    • pp.40-45
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    • 1999
  • This study deals with an investigation on low cost adsorbents locally available n dyeing wastewater treatment of color removal. Peat, bentonite, slag and fly ash were utilized for this study. Considering that low cost adsorbents contained in $SiO_2$, $Fe_2O_3$ and $Al_2O_3$ compositions, and coagulants were mainly used aluminate and ferrate in color removal. Color of dyeing wastewater was high removed in peat, berntonite and slag except for fly ash with passed time. It could be known that color removal of peat and slag were increased to pH 4, but was hardly changed with advancing to alkaline. Color intended to be high removed with increasing of agitation speed but to be almost slow after 150rpm. As a result on the experiment of Freundlich adsorption isotherms, adsorption intensity(l/n) appeared to be peat>fly ash>slag>bentonite and adsorption capacity(k) came out peat>bentonite>slag>fly ash. Therefore, if low cost adsorbents substituted for existing adsorbents, peat, bentonite and slag could look forward to an expected economical effect.

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An Experimental Study on Ternary System Concrete Using Blast-furnace Slag and Fly-ash (고로(高爐)슬래그 미분말(微粉末)과 플라이애쉬를 이용(利用)한 3성분계(性分系) 콘크리트의 기초물성(基礎物性)에 관한 실험적(實驗的) 연구(硏究))

  • Lee, Hwa-Joong;Hong, Chang-Woo;Kim, Kyeong-Jin
    • Resources Recycling
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    • v.18 no.4
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    • pp.31-37
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    • 2009
  • The purpose of this study was to evaluate the effects of fly-ash and blast-furnace slag on strength development and durability of ternary blended concrete (TBC) and ordinary portland cement concrete as fly ash and slag contents. Main experimental variables were performed fly ash contents (0%, 10%) and slag contents (0%, 10%, 20%, 30%). The compressive and flexural strengths, chloride-ion rapid permeability and chemical attacks resistance were measured to analyze the characteristic of the developed TBC on hardened concrete. The test results showed that compressive and flexural strength of TBC increased as the slag contents increased from 0% to 30% at the long term of curing. It considers blast furnace slag used when fly ash content was up to 10%. The permeability resistance of TBC(fly ash 10%, blast 30%) was extremely good at the curing time 90 days. Also, the effects of added blast furnace slag on OPC and TBC were increased on the permeability and chemical attacks resistance.

Development of Fly Ash/slag Cement Using Alkali-activated Reaction(2) - Reaction products and microstructure - (알칼리 활성반응을 이용한 플라이 애쉬/슬래그 시멘트 개발(2) - 반응생성물과 미세구조 -)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Kwan-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.7
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    • pp.810-819
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    • 2007
  • Investigation of alkali activation of fly ash and blast furnace slag was carried out using waterglass and sodium hydroxide. XRD, FTIR, $^{29}Si$ and $^{27}Al$ NMR, TGA and SEM were used to observed the reaction products and microstructure of the fly ash/slag cement (FSC) pastes. The reaction products were amorphous or low-ordered calcium silicate hydrate and aluminosilicate gel produced from alkali activation of blast furnace slag and fly ash, respectively. On the basis of this investigation, waterglass solution with a modulus(Ms) of 1.0 and 1.2 is recommended for alkali activation of fly ash and blast furnace slag. Morphology of FSC pastes alkali-activated with Ms of 1.0 and 1.2 shows a more solid and continuous matrix due to restructuring of gel-like reaction products from alkali-activated fly ash and blast furnace slag together with another hydrolysis product(i.e., silica gel) from water glass.

Analytical Estimation of the Performance of Marine Concrete with Mineral Admixture (광물질 혼화재를 혼합한 해양 콘크리트의 해석적 성능 평가)

  • Lee, Bang-Yeon;Kwon, Seung-Jun;Kang, Su-Tae
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.3 no.4
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    • pp.301-306
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    • 2015
  • For the purpose of developing high performance marine concrete with improved crack resistance and durability, this analytical study aimed to estimate strength, hydration heat characteristics, and chloride attack resistance of concrete with mineral admixture. Ground granulated furnace slag and fly ash were considered for mineral admixture. The replacement of ground granulated furnace slag and fly ash considered in the analysis was in the range of 0~70% and 0~40 %, respectively. The analysis results indicated that both ground granulated furnace slag and fly ash decreased compressive strength, and the effect of adding ground granulated furnace slag on mitigation of hydration heat was limited whereas fly ash had an noticeable influence on it. It was also found that the replacement with ground granulated furnace slag enhanced the chloride attack resistance but fly ash deteriorated the resistance. From the analytical studies, It could be expected that a ternary blended cement composition with proper amount of ground granulated furnace slag and fly ash might be effective to control crack resistance as well as chloride attack resistance of marine concrete.

Fundamental Characteristics of Activated Fly Ash-Slag Cement Exposed to 5℃ Seawater (5℃ 해수에 노출된 알칼리 활성 플라이애시-슬래그 시멘트의 기초 특성)

  • Kim, Taewan;Jun, Yubin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.302-309
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    • 2019
  • This paper shows an experimental study for fundamental characteristics of alkali activated fly ash-slag cement paste exposed to seawater of 5℃. Fly ash and slag were blended in three different ratios; 6:4, 7:3, and 8:2. Activators (NaOH and Na2SiO3) used 5% of the binder weight. It was shown that as the fly ash substitution rate in creased, compressive strength and density decreased, and water absorption rate increased. The results of X-ray diffraction and thermogravimetry showed that hydration reactants formed in samples did not differ significantly, however, C-S-H gel increased as the slag substitution rate increased. It showed that mechanical properties of fly ash-slag cement pastes under 5℃ seawater condition were affected by the slag substitution rate rather than fly ash.