• Journal of the Korea Institute of Building Construction
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• v.16 no.4
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• pp.313-320
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• 2016

The aim of this study is to look into the metakaolin replacement ratio of blast furnace slag based alkali activated slag mortar and its mechanical characteristics according to changes in stimulant concentration. Metakaolin has high fineness, and therefore the fluidity becomes lower as the replacement ratio becomes higher. So in this study, a sufficient value of mixing water was provided to secure fluidity for the characteristic experiment, and a different W/B was derived for each specimen in order to make the fluidity identical. A characteristic experiment was conducted according to the mol concentration of NaOH, which was used as the mixing water that affects fluidity. Additionally, compressive strength measurement, observation of inner microstructure through SEM, acid resistance experiment, and neutralization resistance was conducted. The results of this study revealed that for a high concentration NaOH solution to have even fluidity, a high W/B is necessary, and the functions were enhanced, not degraded.

• Journal of the Korea Institute of Building Construction
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• v.10 no.3
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• pp.49-56
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• 2010

The purpose of this study is to examine the effect of variations in the mix rate of PVA fiber and the replacement ratio of non-sintering Hwangtoh on non-sintering Hwangtoh mortar and concrete mixed with PVA fiber. For water to binder ratio, mortar and concrete were both 50%, and PVA fiber mix rate was 0% and 0.3%. The replacement ratio of non-sintering Hwangtoh was 0, 25, 50 and 75(%) for mortar, and 0, 15, 30 and 50(%) for concrete. The properties of the mortar and concrete were compared and analyzed in 4 different levels, and the results can be summarized as follows. The replacement ratio of 30% of the non-sintering Hwangtoh, and the PVA fiber mix rate of 0.3% is determined to result in concrete of high quality, including strength and fluidity, and crack control by plastic shrinkage.

• Applied Chemistry for Engineering
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• v.16 no.6
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• pp.815-821
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• 2005

Three major commercially available organic chemical admixtures are modified lignosulfonates (LS), sulfonated naphthalene-formaldehyde resins (SNF) and sulfonated melamine-formaldehyde (SMF). In this study, various sulfonated melamine-formaldehyde (SMF) superplasticizers were synthesized via four synthetic steps including hydroxymethylation (Step 1), sulfonation (Step 2), polymerization (Step 3) and neutralization and stabilization (Step 4). In this synthesis, mole ratio of melamine to formaline and the amount of acid catalyst used were varied. The obtained SMF superplasticizers were applied to cement paste and mortar and their physical properties including workability, slump loss, compressive strength were investigated. Also their hydrate shapes were investigated by examining SEM images of the cured paste. It was found that the fluidity properties of cement were significantly influenced by the structure of SMF condensates.

• Proceedings of the KSR Conference
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• 2007.11a
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• pp.1273-1278
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• 2007

The cement-asphalt mortar is a mixture of cement and asphalt emulsion, and is utilized as a underpouring materials for the railway track which is used to fill under slab panel space so as to provide a stabilized track support and a tool for reduction of noise and vibration. To increase the workability of grouting, this study investigates the effect of temperature on cement-asphalt mortar by analyzing its physical and mechanical properties before/after hardening according to the temperature (10, 15, 20, 25, $30^{\circ}C$). According to the test results, it is found that as for the physical property of fresh cement-asphalt mortar the more mixture temperature become higher or lower, the more fluidity become worse. But by increasing reducing agent amount and its unit quantity, the required fluidity is met. The compressive strength as physical property of hardened cement-asphalt mortar become lower when temperature is lower but taking it by and large the physical properties of cement-asphalt mortar before/after hardening aren't so affected by temperature and well satisfy the requirement. And it has proved that rate of expansion and freezing and thawing resistance aren't affected by temperature.

• Journal of the Korean Ceramic Society
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• v.40 no.12
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• pp.1229-1234
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• 2003

The utilization of metakaoline as a mineral admixture for cement has received considerable attention in recent years. This paper investigates the rheological properties of cement pastes containing metakaoline in view of fluidity. The rheology of the paste is assessed by using a BROOKFIELD RVDV II + viscometer (SC4-21, 29) having cylindrical spindle. The results show the fluidity of cement pastes with metakaoline is increased by increasing W/S ratio and the dosage of superplastcizer. And also cement pastes with metakaoline as a partial replacement of cement show a dilatant behavior. Dilatancy is heavily influenced by W/S ratio and by the amount of metakaoline. However the thixotropy of the pastes is increased by silica fume.

• Journal of Korea Foundry Society
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• v.33 no.6
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• pp.242-247
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• 2013

The most widely utilized commercial, aluminum-casting alloys are based on an aluminum-silicon system due to its excellent casting, and good mechanical, properties. Unfortunately, these Al-Si based alloys are inherently poor energy conductors; compared to pure aluminum, because of their high silicon content. This means that they are not suitable for applications demanding high eletrical or thermal conductivity. Therefore, efforts are currently being made to develop new, highly-conductive aluminum-casting alloys containing no silicon. In this research, a number of properties; including potential for castability, were investigated for a number of Al-Fe-Zn-Cu alloys with varying Cu content. As the copper content was increased, the tensile strength of Al-Fe-Zn-Cu alloy tended to increase gradually, while the electrical conductivity was slightly reduced. Fluidity was found to be lower in high-Cu alloys, and susceptibility to hot-cracking was generally high in all the alloys investigated.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2005.11a
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• pp.57-61
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• 2005

Cement paste is originally the basic material and crucial factor consisting concrete. This study investigates the relationship between flow apparatuses, which are ring flow(R-F), flow cone(F-C) and mini slump(M-S), in order to estimate the fluidity of cement Paste. For quantitatively evaluating the measured data this study also investigated the calibration of the rheology consistent, such as yield value and plastic viscosity, of cement paste using viscometer For this purpose the present work discussed the influence of 3 type of ordinary portland cement with different companies, affecting the fluidity of cement paste. and it also demonstrated the influence of the various kinds of mineral admixtures, such as fly ash(FA), blast furnace slag(BS) and silica fume(SF) and that of incorporating ratio. The author concluded that using R-F apparatus is the most effective flow test method of cement paste and it is exactly proportional to other apparatus' rheological properties.

• Journal of the Korean Ceramic Society
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• v.45 no.6
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• pp.336-344
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• 2008

Rheological properties of cement pastes containing blast furnace slag (BFS: 3,900, $7,910\;cm^2/g$) or fly ash powder (FA: 4,120, $8,100\;cm^2/g$) according to the ratio of water/binder (W/B) and the dosage of polycarboxylate type superplasticizer (PC) were investigated by a mini slump and a coaxial cylinder viscometer. In this experiment, the ratio of replacing OPC with BFS or FA was 30 wt%, the W/B was from 30 to 70 wt%. As a result, the fluidity of cement paste containing BFS or FA was improved with increasing W/B and the dosage of PC. BFS or FA replaced cement paste with W/B 70% and PC 0.3% showed the highest fluidity. The segregation range of cement paste was occurred below $10\;d/cm^2$ of the yield stress and below 50 cPs of the plastic viscosity by the coaxial cylinder viscometer. And also it was formed that the plastic viscosity and the yield stress of FA replaced cement paste were higher than them of BFS replaced cement paste.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2014.11a
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• pp.178-179
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• 2014

The fine blast furnace slag is widely used as the admixture as it helps to increase the fluidity, long term strength of the concrete but decrease the heat of hydration. In case of the fine blast furnace slag, if the fineness of the slag is enhanced with the addition of gypsum to the concrete for the supplement of low strength in early stage and the facilitation of the initial hydration, the quality of the concrete is expected to change depending on the volume of the gypsum volume fraction. But, up to now the study on the fine blast furnace slag has only focused on the effect of fineness, replacement and admixture and there have been almost no studies on the effect of the gypsum volume fraction. Accordingly, this study focuses on what effect the gypsum volume fraction would make on the fluidity characteristics of the ultrafine furnace slag cement paste by using the rheology properties.

• YAKHAK HOEJI
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• v.38 no.2
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• pp.131-139
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• 1994

Calcein-encapsulated small unilamellar vesicles of various lipid composition were prepared using the sonication technique, and their stabilities at $20^{\circ}C$ were examined by measuring calcein leakage from the liposomes. The fluidity of these liposomal bilayers was also investigated by measuring the fluorescence polarization of DPH labelled into the liposomes. The results showed that liposomes made of PC mixtures with different acyl chain length were very stable, which may be due to the formation of interdigitated bilayer structure. The addition of cholesterol further stabilized these PC liposomes. However, addition of cholesterol reduced the encapsulation efficiences of liposomes. The fluidity of the liposomes was significantly decreased by cholesterol in the liquid crystalline state, but not changed in the gel state. These results suggest that the enhanced stability of PC mixture liposomes may be ascribed to the formation of stable interdigitated bilayer structure. In membrane-mimetic and drug-delivery studies, vesicles made of mixtures of various phospholipids are recommended instead of addition of cholesterol to the phospholipid.