• 제목/요약/키워드: Flow deviation

검색결과 548건 처리시간 0.023초

GCOTC에 의한 알코올류 분리를 위한 시스템 적합성에 관한 연구 (Study on The System Suitability Test for Alcohols Separation by GCOTC)

  • 오도석;김성화;이슬;최재구
    • 한국산업보건학회지
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    • 제27권2호
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    • pp.123-129
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    • 2017
  • Objectives: The purpose of this study is to enhance the application of analytical method of polar solvents(alcohols) by GCOTC (gas chromatography open tubular column) through the system suitability test(SST) to estimate the whole chromatographic system performance(integral part). Methods: To perform the SST, carried out repeatability(n=6) as analytical method of polar solvents by GCOTC, got the retention time($t_R$), standard deviation(${\sigma}_{n-1}$) of $t_R$, baseline width($w_b=4{\sigma}_{n-1}$) and calculated dead time($t_m$) by $v_m=d^2{\pi}L(f/4)$ and $v_m=t_m$ x flow rate. Results: In this experiment, obtained the basic data, there were $t_m=2$ min, methanol($t_R=3.569$, ${\sigma}_{n-1}=0.01$, $w_b=0.04$), ethanol ($t_R=3.892$, ${\sigma}_{n-1}=0.004$, $w_b=0.016$), isopropanol($t_R=4.209$, ${\sigma}_{n-1}=0.004$, $w_b=0.016$). By using these data, calculated the corrected retention time($t_R{^{\prime}}$), capacity factor(k), separation factor(${\alpha}$), number of theoretical plate(n) and resolution($R_s$) for SST and got the good results. Conclusions: Through the SST, could reconfirm the whole chromatographic performance system(integral part) for analytical method of polar solvents by GCOTC. Therefore, this analytical method expect to be widely applied at the related areas.

충돌형 가스발생기 탈설계점 연소시험

  • 김승한;한영민;서성현;문일윤;이광진;김종규;설우석
    • 항공우주기술
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    • 제3권2호
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    • pp.81-90
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    • 2004
  • 액체로켓엔진에서 터보펌프의 160kW급 터빈 구동용의, 액체산소와 케로신을 추진제로 사용하는 가스발생기의 탈설계점 연소성능시험 결과에 대해 논의하였다. 가스발생기의 탈설계점 연소시험에서 연소압력은 O/F비와 추진제 공급유량의 함수로 나타나는데, 출구 온도편차는 turbulence ring이 있는 경우 ±7.5K 이내로 매우 균일한 공간적 온도분포임을 확인하였다. 각각의 탈설계점 연소시험에서 가스발생기 출구 온도는 가스발생기로 공급되는 추진제의 O/F 비의 함수로 나타낼 수 있었다. 본 가스발생기의 탈설계점 연소시험 결과, 특히 가스발생기의 혼합비와 가스온도와의 관계는 향후 개발되어질 가스발생기 설계나 저혼합비 연소해석 코드를 작성 시 매우 유용하게 사용되어질 것이다.

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충적하천의 유로이동에 관한 연구 (A Study of Channel Migration in Alluvial River)

  • 노섭;정용태;송재우
    • 대한토목학회논문집
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    • 제13권5호
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    • pp.173-181
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    • 1993
  • 자연하천에 대한 합리적인 하천개수계획수립 및 유로의 유지관리면에서 반드시 규명되어야 할 유로만곡부에서의 정량적인 해석은 여러가지 접근방법이 있으며, 사행하천의 유로이동에 대한 예측은 도로, 교량 등의 위치선정과 기존하천구조물의 방재에 필수적이다. 하상계수가 큰 우리나라의 하천에 유로이동 예측모형을 적용할 때 유량은 기간별-지배유량을 고려하는 것이 타당할 것으로 사료되며, 본 연구대상 유역에 대한 침식계수, 유로이동에 대한 평균오차량, 하상세굴계수 등을 비교검토한 결과 유로이동을 지배하는 유량이 존재함을 알 수 있으며, 연구대상유역에서 유로이동에 대한 지배유량은 재현기간 4년에 해당하는 6,000CMS 이상으로 사료된다. 유로이동모형을 실측값이 있는 남한강의 연구대상유로에 적용하여 침식계수를 구하였으며, 계산된 침식계수를 이용하여 그 유로에서의 2000년에 대한 유로이동을 예측하였다.

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Evaluation of the Immune-Stimulating Activity of Samul-tang, a Traditional Korean Herbal Medicine, Standardized by HPLC-PDA

  • Seo, Chang-Seob;Ha, Hye-Kyung;Jung, Da-Young;Lee, Ho-Young;Shin, Hyeun-Kyoo
    • 대한한의학회지
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    • 제32권3호
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    • pp.25-34
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    • 2011
  • Objectives: We performed simultaneous determination of five constituents by HPLC in Samul-tang (SMT). Additionally, we investigated the immune-stimulatory potential of SMT on specific cellular and humoral immune responses in ovalbumin (OVA)-immunized mice. Methods: Reverse-phase chromatography using a Gemini C18 column operating at $40^{\circ}C$, and photodiode array (PDA) detection at 190-400 nm, were used for quantification of the five components of SMT. Mobile phase using a gradient flow consisted of two solvent systems. Solvent A was 1.0% (v/v) aqueous acetic acid and solvent B was acetonitrile with 1.0% (v/v) acetic acid. C57BL/6 mice were immunized intraperitoneally with OVA/alum ($100{\mu}g/200{\mu}g$) on days 1, 8, and 15. The extract of SMT (1000 mg/kg) was given to mice orally for 21 days (from day 1 to day 21). At day 22, OVA-, lipopolysaccharide (LPS)- and concanavalin A (Con A)-stimulated splenocyte proliferation and OVA-specific and total antibodies were measured in plasma. Results: Calibration curves were acquired with $r^2$>0.9999, and the relative standard deviation (RSD, %) for intra- and inter-day precision were both less than 3.5%. The recovery was in the range of 95.69-115.12%, with an RSD less than 6.0%. The contents of five components in SMT were 1.08-15.30 mg/g. SMT significantly enhanced Con A-induced splenocyte proliferation in OVA-immunized mice (p<0.01). Also, SMT significantly enhanced OVAspecific IgG, IgG1 and total IgM levels in plasma compared with the OVA-immunized group. Conclusions: The established method will be applied for the quantification of major components and immunestimulating activity in OVA-immunized mouse model of SMT.

Computational optimisation of a concrete model to simulate membrane action in RC slabs

  • Hossain, Khandaker M.A.;Olufemi, Olubayo O.
    • Computers and Concrete
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    • 제1권3호
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    • pp.325-354
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    • 2004
  • Slabs in buildings and bridge decks, which are restrained against lateral displacements at the edges, have ultimate strengths far in excess of those predicted by analytical methods based on yield line theory. The increase in strength has been attributed to membrane action, which is due to the in-plane forces developed at the supports. The benefits of compressive membrane action are usually not taken into account in currently available design methods developed based on plastic flow theories assuming concrete to be a rigid-plastic material. By extending the existing knowledge of compressive membrane action, it is possible to design slabs in building and bridge structures economically with less than normal reinforcement. Recent research on building and bridge structures reflects the importance of membrane action in design. This paper describes the finite element modelling of membrane action in reinforced concrete slabs through optimisation of a simple concrete model. Through a series of parametric studies using the simple concrete model in the finite element simulation of eight fully clamped concrete slabs with significant membrane action, a set of fixed numerical model parameter values is identified and computational conditions established, which would guarantee reliable strength prediction of arbitrary slabs. The reliability of the identified values to simulate membrane action (for prediction purposes) is further verified by the direct simulation of 42 other slabs, which gave an average value of 0.9698 for the ratio of experimental to predicted strengths and a standard deviation of 0.117. A 'deflection factor' is also established for the slabs, relating the predicted peak deflection to experimental values, which, (for the same level of fixity at the supports), can be used for accurate displacement determination. The proposed optimised concrete model and finite element procedure can be used as a tool to simulate membrane action in slabs in building and bridge structures having variable support and loading conditions including fire. Other practical applications of the developed finite element procedure and design process are also discussed.

Novel Solid Phase Extraction Procedure for Some Trace Elements in Various Samples Prior to Their Determinations by FAAS

  • Sacmaci, Srife;Kartal, Senol;Sacmaci, Mustafa;Soykan, Cengiz
    • Bulletin of the Korean Chemical Society
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    • 제32권2호
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    • pp.444-450
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    • 2011
  • A novel method that utilizes poly(5-methyl-2-thiozyl methacrylamide-co-2-acrylamido-2-methyl-1-propanesulfonic acid-co-divinylbenzene) [MTMAAm/AMPS/DVB] as a solid-phase extractant was developed for simultaneous preconcentration of trace Cd(II), Co(II), Cr(III), Cu(II), Fe(III), Mn(II), Ni(II), Pb(II), and Zn(II) prior to the measurement by flame atomic absorpiton spectrometry (FAAS). Experimental conditions for effective adsorption of the metal ions were optimized using column procedures. The optimum pH value for the simultaneously separation of the metal ions on the new adsorbent was 2.5. Effects of concentration and volume of elution solution, sample flow rate, sample volume and interfering ions on the recovery of the analytes were investigated. A high preconcentration factor, 100, and low relative standard deviation values, $\leq$1.5% (n = 10), were obtained. The detection limits (${\mu}gL^{-1}$) based on the 3s criterion were 0.18 for Cd(II), 0.11 for Co(II), 0.07 for Cr(III), 0.12 for Cu(II), 0.18 for Fe(III), 0.67 for Mn(II), 0.13 for Ni(II), 0.06 for Pb(II), and 0.09 for Zn(II). The validation of the procedure was performed by the analysis of two certified reference materials. The presented method was applied to the determination of the analytes in various environmental samples with satisfactory results.

발전용 보일러의 최적연소조정기법에 대한 실험적 연구 (The Study of Optimized Combustion Tuning Method for Fossil Power Plant)

  • 정재진;송정일
    • 한국태양에너지학회 논문집
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    • 제29권5호
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    • pp.45-52
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    • 2009
  • Fossil power plants firing lower grade coals or equipped with modified system for $NO_x$ controls are challenged with maintaining good combustion conditions while maximizing generation and minimizing emissions. In many cases significant derate, availability losses and increase in unburned carbon levels can be attributed to poor combustion conditions as a result of poorly controlled local fuel and air distribution within the boiler furnace. In order to develop a on-line combustion tuning system, field test was conducted at operating power boiler. During the field test the exhaust gases' $O_2,\;NO_x$ and CO was monitored by using a spatially distributed monitoring grid located in the boiler's high temperature vestibule and upper convective rear pass region. At these locations, the flue gas flow is still significantly stratified, and air in-leakage is minimal which enables tracing of poor combustion zones to specific burners and over-fire air ports. using these monitored information we can improving combustion at every point within the furnace, therefore the boiler can operate at reduced excess $O_2$ and gas temperature deviation, reduced furnace exit gas temperature levels while also reducing localized hot spots, corrosive gas conditions, slag or clinker formation and UBC. Benefits include improving efficiency, reducing $NO_x$ emissions, increasing output and maximizing availability. Discussion concerning the reduction of greenhouse gases is prevalent in the world. When taking a practical approach to addressing this problem, the best way and short-term solution to reduce greenhouse gases on coal-fired power plants is to improve efficiency. From this point of view the real time optimized combustion tuning approach is the most effective and implemented with minimal cost.

지하철 차량운용 문제에 대한 수리적 해법에 관한 연구 (A Study on the Mathematical Programming Approach to the Subway Routing Problem)

  • 김경민;홍순흠
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2007년도 추계학술대회 논문집
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    • pp.1731-1737
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    • 2007
  • 차량운용문제 혹은 열차반복문제는 수송계획, 열차운행계획에서 작성된 열차운행시각에 기초하여 편성유형 또는 차종에 따라 주어진 제약조건(선회조건, 검수조건, 기지복귀조건 등)을 반영하여 최적의 차량운용 다이아, 운용순서를 구성하는 문제이다. 일반적으로 이 문제는 집합분할(Set Partition)문제로 모델링하여 열생성(Column Generation) 기법을 사용하여 제약조건에 맞는 운용을 생성하였다. 하지만, 본 연구에서는 지하철과 같이 열차운행의 빈도는 높고 물리적 네트웍은 간단하며 시종착역의 수가 적을 경우 많은 대안 경로(Alternative Routing)들이 생성되는 특징 및 일반 철도와는 다른 역에서의 공간적 제약에 따른 차량 선회 제약을 고려하여 차량운용수를 최소화할 수 있는 지하철 차량운용 문제에 대한 수학적인 모델을 제시하고자 한다. 먼저, 차량선회제약만을 고려하여 최소비용 흐름 모형으로 네트워크 모형을 구성하였다. 최소비용 흐름 모형을 결과로 생성된 운용을 바탕으로 각 운용의 운행거리를 정규화(Normalize)하는 휴리스틱 기법을 제안하였다. 또한, 이 방법론을 실제와 유사한 지하철 열차 스케줄에 적용하였고 약 14%의 차량소요 감소 및 최대 영업거리 약 11%, 표준영업거리편차 약 5% 감소를 통하여 본 연구결과의 유용성을 확인하였다.

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하천의 만곡류에 관한 이론적 고찰 (Fundamental Theory of flow of water in bends of open channel)

  • 선우중호;윤영남
    • 물과 미래
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    • 제10권1호
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    • pp.53-70
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    • 1977
  • The analysis performed here is aimed to increase the familiarity of hydrologic process especially for the small basins which are densely gaged. Kyung An and Mu Shim river basins are selected as a representative basin according to the criteria which UNESCO has established back in 1964 and being operated under the auspice of Ministry of Construction. The data exerted from these basins is utilized for the determination of characteristics of procipitation and runoff phenomena for the small basin, which is considered as a typical Korean samall watershed. The study found that the areal distribution of preciptation did not show any significant deviation from the point rainfall. Since the area studied is less than 20 km#, the pointrainfall may be safely utilized as a representative value for the area. Also the effect of elevation on the precipitation has a minor significance in the small area where the elevation difference is less than 200m. The methodology developed by Soil Conservation Service for determination of runoff value from precipitation is applied to find the suitability of the method to Korean river basin. The soil cover complex number or runoff curve number was determined by comsidering the type of soil, soil cover, land use and other factors such as antecedent moisture content. The average values of CN for Kyung An and Mushim river basins were found to be 63.9 and 63.1 respectively under AMC II, however, values obtained from soil cover complex were less than those from total precipitation and effective precipitation about 10-30%. It may be worth to note that an attention has to be paid in application of SCS method to Korean river basin by adjusting 10-30% increase to the value obtained from soil cover complex. Finally, the design flood hydrograph was consturcted by employing unit hydrograph technique to the dimensionless mass curve. Also a stepwise multiple regression was performed to find the relationship between runoff and API, evapotranspiration rate, 5 days antecedentprecipitation and daily temperature.

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Numerical Modeling of Regenerative Rotary Heat Exchanger: A Review

  • Baruah, Netramoni;Prasanna, Kumar G.V.
    • Journal of Biosystems Engineering
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    • 제42권1호
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    • pp.44-55
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    • 2017
  • Background: Heat recovery is one of the prominent ways to save a considerable amount of conventional fossil fuel and minimize its adverse effects on the environment. The rotary heat exchanger is one of the most effective and efficient devices for heat recovery or heat exchanging purposes. It is a regenerative type of heat exchanger, which has been studied and used for many heat recovery purposes. However, regenerative thermal wheels have been mostly used as heat recovery systems in buildings. For modeling a rotary regenerator, it is very important to numerically consider all the factors involved, such as effectiveness, rotational speed, geometrical size and shape, and pressure drop (${\Delta}p$). In recent times, several researchers have actively studied the rotary heat exchangers, both theoretically and experimentally. Reviews: In this paper different advances in the numerical modeling of regenerative rotary heat exchangers in relation to fluid flow and heat transfer have been discussed. Researchers have indicated that the effectiveness of the regenerative rotary heat exchanger depends on various factors including, among many others, rotational speed, rotational period and combustion power. It is reported that with the increase of periodic rotation the deviation of theoretical results from the experimental result increases. The available literature indicates that regenerative heat exchangers are having relatively more effectiveness (60-80%), compared to other heat exchangers. It is also observed that the finite difference method and finite volume methods are mostly used for discretizing the heat transfer governing equations, under some assumptions. Research also indicates that for the effectiveness calculation the ${\varepsilon}-NTU$ method is the most popular and convenient.