• Journal of Pharmaceutical Investigation
• /
• v.39 no.3
• /
• pp.185-199
• /
• 2009

Using a strain-controlled rheometer [Advanced Rheometric Expansion System (ARES)], the steady shear flow properties and the dynamic viscoelastic properties of $Antiphlamine-S^{(R)}$ lotion have been measured at $20^{\circ}C$ (storage temperature) and $37^{\circ}C$ (body temperature). In this article, the temperature dependence of the linear viscoelastic behavior was firstly reported from the experimental data obtained from a temperature-sweep test. The steady shear flow behavior was secondly reported and then the effect of shear rate on this behavior was discussed in detail. In addition, several inelastic-viscoplastic flow models including a yield stress parameter were employed to make a quantitative evaluation of the steady shear flow behavior, and then the applicability of these models was examined by calculating the various material parameters. The angular frequency dependence of the linear viscoelastic behavior was nextly explained and quantitatively predicted using a fractional derivative model. Finally, the strain amplitude dependence of the dynamic viscoelastic behavior was discussed in full to elucidate a nonlinear rheological behavior in large amplitude oscillatory shear flow fields. Main findings obtained from this study can be summarized as follows : (1) The linear viscoelastic behavior is almostly independent of temperature over a temperature range of $15{\sim}40^{circ}C$. (2) The steady shear viscosity is sharply decreased as an increase in shear rate, demonstrating a pronounced Non-Newtonian shear-thinning flow behavior. (3) The shear stress tends to approach a limiting constant value as a decrease in shear rate, exhibiting an existence of a yield stress. (4) The Herschel-Bulkley, Mizrahi-Berk and Heinz-Casson models are all applicable and have an equivalent validity to quantitatively describe the steady shear flow behavior of $Antiphlamine-S^{(R)}$ lotion whereas both the Bingham and Casson models do not give a good applicability. (5) In small amplitude oscillatory shear flow fields, the storage modulus is always greater than the loss modulus over an entire range of angular frequencies tested and both moduli show a slight dependence on angular frequency. This means that the linear viscoelastic behavior of $Antiphlamine-S^{(R)}$ lotion is dominated by an elastic nature rather than a viscous feature and that a gel-like structure is present in this system. (6) In large amplitude oscillatory shear flow fields, the storage modulus shows a nonlinear strain-thinning behavior at strain amplitude range larger than 10 % while the loss modulus exhibits a weak strain-overshoot behavior up to a strain amplitude of 50 % beyond which followed by a decrease in loss modulus with an increase in strain amplitude. (7) At sufficiently large strain amplitude range (${\gamma}_0$>100 %), the loss modulus is found to be greater than the storage modulus, indicating that a viscous property becomes superior to an elastic character in large shear deformations.

• Journal of Mechanical Science and Technology
• /
• v.20 no.1
• /
• pp.13-18
• /
• 2006

Ti-8Ta-3Nb, as a new biomaterial, was prepared by cast and swaging process. Their deformation behavior of Ti-8Ta-3Nb alloy has been characterized on the basis of its flow stress variation obtained from the true strain rate compression testing in the temperature of $700-900^{\circ}C$ and strain rate of $0.001-10\;s^{-1}$. At the strain rates lower than $0.1\;s^{-1}$ and the all temperature ranges which consist of two phase ${\alpha}+{\beta}$ as well as single ${\beta}$ phase fields, the flow curves show a small degree of flow softening behavior. In contrast, the shapes of the flow curves at other strain rates indicate unstable behavior. The shapes of the flow curves were similar in both as-cast and swaged specimen as well as in both ${\alpha}+{\beta}$ phase and ${\beta}$ phase. The flow stress data did not obey the kinetic rate equation over the entire regime of testing but a good fit has been obtained in the intermediate range of temperatures ($750-850^{\circ}C$). In this range, a stress exponent value of about 7.7 in as-cast specimens and about 6.2 in swaged specimens with an apparent activation energy of about 300 kJ/mol and about 206 kJ/mol respectively have been evaluated.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.26 no.7
• /
• pp.945-950
• /
• 2002

Shape optimization of a flow system is done to obtain the required effects, in the engineering fields. Most of these designs are accomplished by empirical or numerical analysis. In empirical analysis, it is difficult to obtain an optimal shape in the feasible design region. And, in numerical method, it usually needs much calculation expenses for shape optimization, because of design sensitivity analysis. In this study, we used the growth-strain method having only one distributed parameter such as a design variable. It optimizes a shape by making a distributed parameter such as dissipation energy uniform in a flow system, and then applied to two-flow systems. In order to overcome the stability occurred in numerical analysis performed by Azegami, the equation of volumic strain has been modified. Also, the shapes were compared with the known optimal shapes for the flow systems. Consequently, we confirm that the modified growth-strain method is very efficient and practical in shape optimization of the flow systems.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 1999.08a
• /
• pp.341-348
• /
• 1999

In the finite elemenet analysis of metal forming problems, the most critical input is the flow stress of workpiece. Conventionally, the flow stress of a metal at elevated temperatures is assumed to be a function of strain, strain rate and temperature, and obtained by experiment. However, if the workpiece is not continuously deformed as in mulit-pass rolling, the flow stress obtained by experiment is no longer valid because it does not consider the microstructure evolution occurring between deformations. In the present study, it was attemped that the flow stress of steel in the austenite region be obtained equations. It was applied to the prediction of flow stress variation at each stand during hot finishing rolling of steel.

• Korean Journal of Materials Research
• /
• v.26 no.5
• /
• pp.281-286
• /
• 2016

In the present study, the tensile properties and dynamic strain aging of an Fe-24.5Mn-4Cr-0.45C alloy were investigated in terms of strain rate. During tensile testing at room temperature, all the stress-strain curves exhibited serrated plastic flows related to dynamic strain aging, regardless of the strain rate. Serration appeared right after yield stress at lower strain rates, while it was hardly observed at high strain rates. On the other hand, strain-rate sensitivity, indicating a general relationship between flow stress and strain rate at constant strain and temperature, changed from positive to negative as the strain increased. The negative strain-rate sensitivity can be explained by the Portevin Le Chatelier effect, which is associated with dynamic strain aging and is dependent on the strain rate because it is very likely that the dynamic strain aging phenomenon in high-manganese steels is involved in the interaction between moving dislocations and point-defect complexes.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2008.10a
• /
• pp.292-296
• /
• 2008

A new method of evaluating critical damage values of commercial materials is presented in this paper. The method is based on the previous study of the methodology [1] of acquisition of true stress-strain curves or flow stress curves over large strain from the tensile test in which the flow stress is described by the Hollomon law-like form, that is, by the strain dependent strength coefficient and the strain hardening exponent. The strain hardening exponent is calculated from the true strain at the necking point to meet the Considere condition. The strength coefficient is assumed to be constant before necking and represented by a piecewise linear function of strain after necking. With the predicted flow stress, a tensile test is simulated by a rigid-plastic finite element method with higher accuracy of less than 0.5% error between experiments and predictions. The instant when the fracture begins and thus the critical damage is obtained is determined by observing the stress variation at the necked region. It is assumed that the fracture due to damage begins when the pattern of stress around the necked region changes radically. The method is applied to evaluate the critical damage of a low carbon steel.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2004.05a
• /
• pp.265-268
• /
• 2004

In this present study, mechanical properties of the Zr-Ti-Cu-Ni-Be bulk metallic glass are characterized by compression test over a wide range of temperatures and strain rates. Three different types of deformation behavior have been identified as a result, viz., Newtonian viscous flow, non-Newtonian flow and brittle fracture without plastic deformation. A transition state theory is applicable fur the flow stress - strain rate curve that contains the transition from Newtonian to non-Newtonian flow. Based on the relationship between viscosity and strain rate within undercooled liquid state, we can easily obtain the experimental deformation map and suggest the boundaries among different deformation behavior of this alloy.

• Macromolecular Research
• /
• v.14 no.3
• /
• pp.318-323
• /
• 2006

We investigated the rheological behaviors and orientation of three different types of layered silicate composite systems under external flow: microcomposite, intercalated and exfoliated nanocomposites. Rheological measurements under shear and uniaxial extensional flows, two-dimensional, small-angle X-ray scattering and transmission electron microscopy were conducted to investigate the properties, as well as nano- and micro-structural changes, of polymer/layered silicate nanocomposites. The preferred orientation of the silicate layers to the flow direction was observed under uniaxial extensional flow for both intercalated and exfoliated systems, while the strain hardening behavior was observed only in the exfoliated systems. The degree of compatibility between the polymer matrix and clay determined the microstructure of polymer/clay composites, strain hardening behavior and spatial orientation of the clays under extensional flow.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.27 no.7
• /
• pp.1152-1158
• /
• 2003

The mechanical behavior of a commercially pure titanium (CP-Ti) is investigated at high temperature Split Hopkinson Pressure Bar (SHPB) compression test with high strain-rate. Tests are performed over a temperature range from room temperature to 1000$^{\circ}C$ with interval of 200$^{\circ}C$ and a strain-rate range of 1900 ∼ 2000/sec. The true flow stress-true strain relations depending on temperature are achieved in these tests. For construction of constitutive equation from the true flow stress-true strain relation, parameters for the Johnson-Cook constitutive equation is determined. And the modified Johnson-Cook equation is used for investigation of behavior of flow stress in vicinity of recrystalization temperature. The Modified Johnson-Cook constitutive equation is more suitable in expressing the dynamic behavior of a CP-Ti at high temperature, i.e. about recrystalization temperature.

• Transactions of Materials Processing
• /
• v.7 no.2
• /
• pp.168-176
• /
• 1998

Hot workability of the AA5083 alloy ws investigated by torsion test at temperature ranges of $350{\sim}520^{\circ}C$ and strain rates of 0.5, 1.0, and 3.0/sec. The flow stress and hot ductility of the AA5083 alloy as a function of deformation variables such as temperature and train rate were studied. The microstructural evolution of the AA5083 alloy was studied in relation to Zener-Hollomon parameter (Z=exp( /RT) Also the hot restoration mechanism of the AA5083 alloy was small when Z val-ues were higher than $1.73{\times}1016/sec(370^{\circ}C,\;0.5/sec)$ In addition the difference microstructures during hot deformation. It was found that the increase of flow curves and deformed microstructures during hot deformation. It was found that the increase of flow stress of the AA5083 alloy was small when Z val-ues were higher than $1.73{\times}1016/sec(370^{\circ}C.\;0.5/sec)$. However under the low Z values less than $1.73{\times}1016/sec(370^{\circ}C,\;0.5/sec)$ the flow stress increase with increasing the Z values. The large dispersoid particles in the matrix grain decreased the flow strain of the AA5083 alloy because it caused the stress concentration during hot deformation.