• Journal of the Korean Institute of Gas
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• v.16 no.6
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• pp.87-101
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• 2012

In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

• Fire Science and Engineering
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• v.34 no.2
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• pp.14-21
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• 2020

This paper presents the study of a fire risk to the backside of two miniatures of ISO 9705 2/5 using a lightweight partition for indoor space division and reproduction of the ISO 9705 test. An SGP partition, stud partition, glass wool panel, urethane foam panel, sandwich panel, and glass partition were selected as the test specimens, which are frequently used in construction. According to the ISO 9705 test standard, stabilization was achieved using a measuring device that recorded data before the ignition of a burner and continued recording for 120 s thereafter. After ignition was achieved, the power was increased to 300 kW for 600 s and then reduced to 100 kW for 600 s. The specimens were subsequently observed for 180 s, and the fire risk to the backside and the fire pattern of the wall unit were analyzed. Owing to the amount of heat generated by the ignition source, the maximum temperature of the backside was observed to be 67.7 ℃ for the SGP partition, 55.1 ℃ for the stud partition, 52.4 ℃ for the glass wool panel, 727.4 ℃ for the sandwich panel, 561 ℃ for the urethane foam panel, and 630.5 ℃ for the glass partition. In the cases of the sandwich and urethane foam panels, the explosion of flammable gas occurred by virtue of fusion of the interior materials. The reinforced glass was fractured owing to the temperature difference between the heat- and nonheat-responsive parts. Ultimately, the fire risk to the nearby section room was deemed to be high.

• Fire Science and Engineering
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• v.34 no.2
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• pp.94-96
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• 2020

In November 2013, a case of sustained combustion of a female body was encountered in a Korean farming village. The body was almost completely incinerated from the neck to the knees, and other parts of the body, such as the head, arms, lower legs, and feet, were slightly damaged. The most likely external ignition source was the flame from a matchstick. The elderly woman was found incinerated on the floor of the living room, while other objects in the house were largely undamaged except for having a brown oily or greasy coating. Flammable substances were not detected from the woman's intact pieces of clothing and socks, and her muscular tissues did not contain toxic chemicals. The concentration of carboxyhemoglobin in her peripheral blood was 11% and that of ethyl alcohol in her aqueous humor was below 0.010%. An autopsy failed to determine the exact cause of death because of excessive charring.

• Journal of the Society of Disaster Information
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• v.14 no.1
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• pp.89-100
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• 2018

when the explosive wastes to be treated as designated wastes are brought into the wastes treatment plant by mistake and lead to an explosion in the wastes disposal process, many people and property damage are involved. Waste should be treated properly. As mentioned in this paper, ignition reac- tion tests of ignitable re-burning of explosives packing material waste (solid butadiene) confirmed that ignition was easily occurred, and that even small ignition sources were easily ignited and burned quickly and explosively. In particular, when explosives are loaded into incineration wastes in large quantities and mixed with organic compound wastes, such as fire and explosion accidents caused by explosives packing materials at waste disposal sites, flammable and oxidative gases are generated due to mutual oxidation and pyrolysis It is confirmed that there is a possibility that ignition sources such as spark ignite and instantaneously lead to explosion. It is hoped that this study will be a small reference for on - site detection in the field of fire, and it is expected that the fire - fighting agency will be recognized as a fire investigation agency and will contribute to the improvement of the credibility.

• Fire Science and Engineering
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• v.31 no.3
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• pp.97-105
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• 2017

Because asphalt is a solid at normal temperature and is not a hazardous material as stipulated in the Safety Management Act on Hazardous Materials, it is often recognized as having no risk of fire or explosion. On the other hand, it is as dangerous as flammable liquid because it is heated to $170-180^{\circ}C$ and stored in a storage tank. This study analyzed the risk of fire and explosion during the storage and handling of asphalt and the actual conditions of asphalt regulations by fire service organizations. Moreover, this study analyzed the domestic case of explosions in the production process of asphalt concrete (ASCON) and domestic and foreign cases of asphalt storage tank explosions. The analysis suggested that unlike Japan, Korea has no asphalt regulations in fire service organizations. Explosions can occur when ignition is delayed after fuel is sprayed on the dryer drum burner of the aggregates during the production of ASCON. A physical explosion can occur in the storage tank when environmental purification facilities suddenly work strongly to remove air pollutants or bad smells during the heating of asphalt in an asphalt storage tank. In addition, explosions can occur when fires such as welding is performed in the asphalt storage tank.

• Fire Science and Engineering
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• v.31 no.3
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• pp.25-30
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• 2017

Because of the vertical combustion characteristics of combustible substances, accurate substance safety information for their safe use, handling and transportation is essential. The flash point, fire point, explosion limits and autoignition temperature (AIT) are important safety parameters which need special attention in chemical plants and laboratories that handle dangerous materials. In this study, tert-butylbenzene which is widely used as an intermediate material in the chemical industry was selected. For the reliability of the flammable properties of tert-butylbenzene, this study was investigated the explosion limits of tert-butylbenzene in the reference data. The flash points, fire points and AITs by the ignition delay time for tert-butylbenzene were experimented. The lower flash points of tert-butylbenzene by using the Setaflash and Pensky-Martens closed-cup testers measured $39^{\circ}C$ and $44^{\circ}C$, respectively. The flash points of tert-butylbenzene by using the Tag and Cleveland open cup testers are measured $51^{\circ}C$ and $54^{\circ}C$. And the fire points of tert-butylbenzene by the Tag and Cleveland open cup testers were $54^{\circ}C$ and $58^{\circ}C$ respectively. The AIT of tert-butylbenzene measured by the ASTM 659E tester was measured as $450^{\circ}C$. The lower explosion limit of $39^{\circ}C$ which measured by the Setaflash flash point tester was calculated to be 0.68 vol%.

• Fire Science and Engineering
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• v.28 no.4
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• pp.1-7
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• 2014

Several complex devices and equipments are installed in the car's engine room, including various kind of oils or other flammable materials. So re-ignition is very likely to take place in it. In addition, it is restrictive for the driver or the occupant to open the bonnet and to spray the fire extinguisher in the engine room due to the high possibility of explosion. Therefore, a fire extinguishing system, which can detect a fire and inject the fire extinguishing agent to extinguish it, and fire extinguishing agents including HFC-227ea, which can stand the high temperature within the engine room and hold the viscosity sufficient to keep it in the kind of foam, were developed and tested. And the suffocation effect and the cooling effect come from the fire extinguishing principle of the foam fire extinguishing agent and the inhibiter catalyst effect come from the one of HFC-227ea was led simultaneously, and fire extinguishing agents without the secondary damage caused by residuals after the fire extinguishment like a case of the powder fire extinguishing agent, were developed. And experiments using a vehicle collision after the discharge is complete, foreign material can be removed without extinguishing the advantage that experimental results obtained.

• Journal of Energy Engineering
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• v.14 no.2 s.42
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• pp.159-166
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• 2005

In Korea, although the generation of waste plastic has been increasing, the rate of recycling is considerably low and moreover, there is no suitable method for the treatment of waste plastics. However, pyrolysis, which is appropriate for the treatment of highly polymerized compounds, such as plastics, has recently gained much interest. In this study, a property of the products from the pyrolysis of mixed waste plastics, with a possible practical use for the recycling oil produced, were assessed. First of all, in order to investigate the pyrolysis characteristic of waste plastics, TGA (Thermogravimetric analysis) and DCS (Differential Scanning Calorimetry) were performed on a number of different plastics, including PP, LDPE, HDPE, PET and PS, as well as others. According to the result, it appeared that PP was the most efficiently pyrolyzed by changing the temperature, followed by LDPE, HDPE, PET, PS and the other plastics, in that order. From the results, the optimum conditions f3r pyrolysis were set up, and the different waste plastics pyrolyzed. The recycling oil produced from the flammable gases generated during the pyrolysis was com-pared with fuel oil by an analysis using the petroleum quality inspection method on KS(Korea industrial Standard). The results of the analysis showed the recycling oil was of a similar standard to fuel oil, with the exception of the ignition point, with a quality somewhere between that of paraffin oil and diesel fuel. With respect to these results, the quality of the recycling oil produced by the pyrolysis of waste plastics was suf-ficient for use as fuel oil.

• Journal of the Korean Institute of Gas
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• v.5 no.2 s.14
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• pp.36-42
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• 2001

A leak of fuel gas in partially confined area creates a flammable atmosphere and give rise to an explosion, which is one of the most common accident in domestic. Observations from accident in domestic suggest that some explosions are caused by a quantify of fuel significantly less than lower explosion limit(LEL) amount required to fill the room, which is attributed to inhomogeneous mixing of leaked gas. The minimum amount of leaked gas for explosion is highly dependent on the mixing degree in the area. For lighter gas, such as methane, a high concentration tends to build up in the space from ceiling of room. But heavy gas, such as propane, a high concentration tends to build up in the space from bottom of room. This paper presents a method for analysing the explosion hazard in a room with very small amount of leaked gas. Based on explosion limit concentration, the gaussian distribution model is used to estimate the minimum amount of leak which yields a specified explosion pressure. The results demonstrate that catastrophic structural damage can be achieved with a volume of fuel gas which is less than 0.5 percent of the total enclosed volume in domestic. The method will help analyzing hazard to develop new safe device as well as investigating accident.

• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.106-112
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• 1997

This study measured the ignition limits of methane-air, propane-air, ethylene-air, and hydrogen-air mixture gases by discharge spark of D.C. power resistive circuit. The used experimental device is the IEC type spark ignition test apparatus, it consists of explosion chamber and supply -exhaust system of mixture gas. Mixture gases (methane-air, propane-air, ethylene-air, and hydrogen-air) were put into explosion chamber of IEC type spark ignition test apparatus, then it was confirmed whether ignition was made by 3,200 times of discharge spark between tungsten electrode and cadmium electrode. The ignition limits were found by increasing or decreasing the value of current. For the exact experiment, the ignition sensitivity was calibrated before and after the experiment in each condition. The ignition limits were found by changing the value of concentration of each gas-air mixture in D.C. 24 [V] resistive circuit. As the result of experiment, it was found that the minimum ignition limit currents exist at the value of methane-air 8.3 [$Vol\%$], propane-air 5.25[$Vol\%$], ethylene-air 7.8 [$Vol\%$], and hydrogen-air 21[$Vol\%$] mixture gases. For each the minimum ignition concentration of gases, the relationships between voltage and minimum ignition current were found. The results are as follows. - The minimum ignition limits are decreasing in the order of methane, propane, ethylene, and hydrogen. - The value of ignition current is inversely proportional to the value of source voltage. - The minimum ignition limit currents increase sharply at more than 2 [A]. The reason is caused by overheating the electrode.