• Journal of the Korean Society of Safety
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• v.20 no.4 s.72
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• pp.40-45
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• 2005

The principal actions of a flame retardant are to decrease or prevent the formation of volatile products and increase the formation of char layer. Use of flame retardant additives can decrease the overall fire hazard of the product containing them thus leading to an increase in overall fire safety. Although several flame retardants have been developed for use in polymers, many of these are known to increase the amount of smoke and toxic gases generated by them. This paper present a new flame retardant using metal addition flame retardant. For this study, the experiments of flame retardancy conducted are as follows : burning ratio, weight loss rate using TGA-DTA, the measurement of LOI and char yield. And smoke mass concentration and CO yield were measured. The metal addition flame retardant reduced burning ratio and weight loss rate, increased the LOI and yield of char formation with decreased smoke mass concentration and CO yield.

• Elastomers and Composites
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• v.55 no.1
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• pp.40-45
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• 2020

In this study, the mechanical and flame-retardant properties of ethylene-propylene-diene-termonomer (EPDM) based rubber compounds and various other environmentally friendly inorganic flame retardants were investigated. Alumina trihydrate (ATH) and magnesium hydroxide (MDH) were used as inorganic flame retardants. The mechanical properties after thermal oxidation aging and the flame-retardant properties of the EPDM compounds were measured using a moving die rheometer, a universal testing machine, a compression set, and a UL 94 V flammability test. We focused on how the properties were affected by the type and amount of flame retardants. The results demonstrated that the optimal mechanical and flame-retardant V-0 grade properties were obtained at an ATH content of 200 phr.

• Journal of the Korean Wood Science and Technology
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• v.48 no.5
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• pp.755-764
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• 2020

Due to pronounced mechanical performance and being environmental friendly, aqueous polymer isocyanate adhesive (API) has been widely applied in the production of formaldehyde-free wood products. In this study, flame retardant formaldehyde-free plywood was prepared by incorporation of flame retardants into the API adhesive. Partially phosphorylated poly (vinyl alcohol) (PPVA) which was prepared by reacting poly (vinyl alcohol) with phosphoric acid was used to replace PVA in API formula. In addition, Mg-Al layered double hydroxides (LDH) was chosen as additive flame retardant, replacing traditional filler CaCO₃ in API adhesive formula. And then, the flame retardant API adhesive with main agent (PPVA replacing PVA70wt.%, SBR emulsion 30wt.%), curing agent 10wt.% (accounts for of the main agent), and 20wt.% LDHs (accounts of the main agent) was used to prepare flame retardant plywood. The effect of application of PPVA and Mg-Al LDH on bonding strength of plywood was investigated. The flammability characteristics of the plywood were determined by cone calorimeter test (CCT). The results revealed that compared with the plywood prepared with API adhesive, the use of PPVA and LDH enhanced the flame retardancy of plywood without negatively affecting bonding strength. The CCT tests indicated that the heat release and smoke production flame retardant API plywood were lower than those of the ordinary API glued plywood. Promising developments for flame retardant API adhesive were expected in future applications of flame retardant formaldehyde-free plywood.

• Bulletin of the Korean Chemical Society
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• v.30 no.11
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• pp.2643-2646
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• 2009

In this study, a novel phosphorus-containing flame retardant copolymer of spirocyclic pentaerythritol di(phosphate monochloride) and bisphenol S (SPD-BS) was successfully synthesized and used as a flame retardant in diglycidyl ether of bisphenol A (DGEBA) epoxy resins. The chemical structure of the SPD-BS was characterized using FT-IR and $^1H$ NMR spectra. The thermal properties were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The effects of SPD-BS and nano-$CaCO_3$ on the flame-retardant properties of DGEBA/SPD-BS systems were evaluated by measurement of the burning rate. As a result, the thermal stabilities of the DGEBA/SPD-BS systems were decreased with increasing SPD-BS content. The flame-retardant properties and char yields of the systems were significantly increased when SPD-BS content increased. The synergism of nano-$CaCO_3$ incorporation on flame retardancy was found for the DGEBA/SPD-BS systems.

• Fire Science and Engineering
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• v.33 no.3
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• pp.29-36
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• 2019

The combustion properties required for fire simulations of multi-layer, multi-component flame retardant cables were measured using a cone calorimeter. The CO and soot yields combustion efficiencies of the flame retardant cables were investigated. TFR-8 (flame retardant PCV and XLPE added), TFR-CVV-SB (flame retardant PCV and general PVC), and VCTF, which are excellent in the flame retardancy of cables, were considered. As the main result, the CO yield (y_CO) of the TFR-8 and TFR-CVV-SB flame retardant cables increased by 23% and 16%, respectively, with increasing incident radiation heat flux from 25 kW/㎡ to 50 kW/㎡. On the other hand, the CO yield of VCTF was not influenced significantly by the changes in radiant heat flux. Finally, the soot yield and combustion efficiency increased as the sheath material (flame retardant performance) was strengthened. Therefore, in a fire environment where various heat fluxes coexist, attention should be paid to the top of the application of the combustion property of the flame retardant cable.

• Polymer(Korea)
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• v.27 no.6
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• pp.569-575
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• 2003

The flame retardancy was investigated when the halogenated flame retardant, decabromodiphenyl oxide (DBDPO) and chlorinated paraffin wax (CPW), was added to the polypropylene (PP) / montmorillonite (MMT) nanocomposites. The flame retardancy of polymer resin could be improved not only by addition of flame retardant but also with nanoparticles compositions. The effect of the contents of flame retardant and nanoparticles on the flame retardancy of polypropylene/ montmorillonite nanocomposite systems was thoroughly examined in terms of limited oxygen index (LOI) and cone calorimetry. As a results of cone calorimetry, the heat release rate (HRR) was reduced by the flame retardant DBDPO and CPW, and CPW was a little better than DBDPO. The LOI increased from flammable region (LOI<19) to nonflammable region (LOI>20) for all the flame retardants used in this study. Especially, the improvement in flame retardancy by compounding with PP and MMT was better than that by adding flame retardant to polypropylene. So, the addition of flame retardant after compounding with montmorillonite was more efficient than simple addition of flame retardant.

• Elastomers and Composites
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• v.37 no.4
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• pp.224-233
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• 2002

This study has investigated the flame retardant properties of EPDM rubber with the addition of various flame retardants. Carbon black, stearic acid, zinc oxide cross-linking agent were mixed with EPDM rubber to produce the base rubber E0 without the addition of flame retardants. Phosphorus flame retardant Tricrecyl phosphate(TCP) was added to E0 in 0.5, 1, 1.5, 2 phr to make E1~E4 samples and red phosphorus was added in 3, 6, 9, 12 phr to make E5~E8 samples. A flame retardant of the bromine family Decabromodiphenyloxide(DBDPO), and a chlorinated paraffin retardant of the chlorine family was added to E0 in 3, 6, 9, 12 phr to make E9~E12 and E13~E16 samples, repectively. Basic physical properties such as tensile strength, tear strength and hardness were measured for all the rubber samples with various flame retardant additions. There was no substantial differences. On the other hand, Oxygen index and UL94 were measured to study flame retardant properties. From oxygen index measurements E0 sample showed a value of 23.5%, indicating the improvement of flame retardant properties. Also from UL94 measurements, it was found that addition of red phosphorus resulted in maximum flame retardant effect. It was found that increasing the amount of addition resulted in decreasing combustion rate and improving flame retardant effect regardless of the kind of flame retardant.

• Korean Journal of Agricultural Science
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• v.43 no.3
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• pp.496-505
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• 2016

The purpose of this study was to investigate the economic effects of a flame retardant aluminum screen developed by a company Economic effects were analyzed in terms of micro and macro-economic aspects. In the macro-economic aspect, economic effects were analyzed under the assumptions that the total import volume of flame retardant aluminum screen was approximately $50m^2$ in 2015 and that possible import substitution rates were 100%, 80%, and 60%. Results showed economic values of 2.25 billion won (100% import substitution rates), 1.8 billion won (80% import substitution rates), and 1.35 billion won (60% import substitution rates). If existing farms which had been using imported flame retardant aluminum screen replaced it newly developed with the flame-retardant aluminum screen developed in this study at rates of 100%, 80%, and 60%, the farms could save 750 million won, 60 million won, and 45 million won, respectively. Furthermore, the social cost savings from fire prevention could be 1.184 billion won. In the micro-economic aspect, if a farm with a typical-size ($1,000m^2$) greenhouse growing red pepper wanted to install flame retardant aluminum screen instead of generic aluminum screen, the farm may only pay an additional cost of 720,000 won. In comparison, if the farm chose fire insurance instead of flame-retardant aluminum screen, then the farm would pay 21,000,000 won for fire insurance. The above results show that the economic effect of flame retardant aluminum screen developed by the company would be be very efficient compared to the imported one.

• Transactions on Electrical and Electronic Materials
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• v.7 no.6
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• pp.283-292
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• 2006

So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.238-249
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• 2021

In this study, the effect on flame retardancy and various physical properties when TiO₂ was added with a citric acid/phosphate complex acid catalyst together with Pyrovatex CP new (N-methylol dimethylphosphonopropionamide), a phosphorus-based flame retardant, was studied on cotton fibers. SEM-EDS analysis was performed to confirm the surface characteristics and surface element analysis of the flame-retardant treated cotton fibers, and a vertical carbonization test was performed to confirm the char formation capability and flame retardancy according to the phosphoric acid ratio. By comparing the LOI index before and after washing 10 times, the washing durability of the flame retardant solution containing the phosphoric acid catalyst and TiO₂ was tested by LOI index after ten washing cycles. In addition, the influence of the flame-retardant processing on the physical properties were compared including thermogravimetric analysis (TGA), tear strength and whiteness.