• 한국가스학회지
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• 제16권2호
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• pp.45-51
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• 2012

최소자연발화온도는 가연성혼합물이 화염이나 스파크 없이 주위로부터 충분한 열에너지를 받아서 스스로 발화하는 최저온도를 말한다. 본 연구에서는 ASTM E659 장치를 이용하여 가연성 혼합물인 n-Pentanol+Ethylbenzene계를 구성하는 순수물질과 혼합물의 최소자연발화온도를 측정하였다. Pentanol과 Ethylbenzene의 측정된 최소자연발화온도는 각 각 $285^{\circ}C$, $475^{\circ}C$ 였다. 그리고 n-Pentanol+Ethylbenzene 계의 예측된 최소자연발화온도는 실험값과 적은 평균절대오차에서 일치하였다.

• Coupled systems mechanics
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• 제1권3호
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• pp.285-295
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• 2012

In this paper, two types of porous burners with radial and axial flow have been modeled numerically and compared. For this purpose, governing equations were solved one-dimensionally for methane-air premix gas. The mechanism used in simulating combustion phenomenon was 15 stage reduced mechanism based on GRI3.0. In order to compare the two burners, the inlet flow rate and fuel-air ratio have been assumed equal for the two burners. The results of the study indicated that reduction in speed and increase in cross-section area in the direction of flow have a considerable influence on the behavior of radial burner in comparison to axial burner. Regarding temperature distribution inside the burner, it was observed that the two above mentioned factors can be influential in temperature of flame propagation region. Also, regarding distribution of CO and NO emission, the results indicate that the porous radial burner has lower emissions in comparison to the axial once. The output radiative heat transfer efficiency of the two burners was also compared and in this case also even the radial porous burner was found to be preferable.

• Journal of Mechanical Science and Technology
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• 제19권6호
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• pp.1358-1365
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• 2005

Flue gas recirculation (FGR) is widely adopted to control NO emission in combustion systems. Recirculated flue gas decreases flame temperature and reaction rate, resulting in the decrease in thermal NO production. Recently, it has been demonstrated that the recirculated flue gas in fuel stream, that is, the fuel induced recirculation (FIR), could enhance much improved reduction in NO per unit mass of recirculated gas, as compared to conventional FGR in air. In the present study, the effect of dilution methods in air and fuel sides on NO reduction has been investigated numerically by using $N_2$ and $CO_2$ as diluent gases to simulate flue gases. Counterflow diffusion flames were studied in conjunction with the laminar flamelet model of turbulent flames. Results showed that $CO_2$ dilution was more effective in NO reduction because of large temperature drop due to the larger specific heat of $CO_2$ compared to $N_2$. Fuel dilution was more effective in reducing NO emission than air dilution when the same recirculation ratio of dilution gas was used by the increase in the nozzle exit velocity, thereby the stretch rate, with dilution gas added to fuel side.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
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• pp.518-525
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• 1997

A series of measurements and visualization to investigate the interaction of water sprays with pool fires is presented. Fire source is a small-scale pool burner with methanol, ethanol and gasoline. Measurements of temperatures, $O_2$, $CO_2$, and CO concentrations along the plume centerline are carried out to observe pool fire structures without water sprays. Visualization by the Ar-ion laser sheet shows flow pattern of droplets of the sprays above the pool fires. It is observed that in the case of methanol and ethanol, water sprays continuously penetrate into the center of fuel surfaces. The gasoline pool fire allows intermittent penetration of water sprays because of pulsating characteristics of the gasoline flame. To evaluate the cooling effect of the fuel surface by the sprays, the temperature was measured at the fuel surface. As soon as the mists reach the fuel surface of methanol and ethanol, the temperatures of the fuel surface decrease rapidly below the boiling point, and then the fires are extinguished. Due to the application of mist upon the gasoline fire, though the fuel temperature decrease abruptly at the time of the injection, such a rapid decrease do not continue till the extinction point.

• 대한건축학회논문집:구조계
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• 제34권4호
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• pp.35-42
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• 2018

This study evaluated the fire resisting capacity and post-fire serviceability of the concrete beams retrofitted by near surface mounted method(NSM) using GFRP plates. Main parameters in the test are grout materials and fire exposure. For the test, two types of grout materials between concrete substrate and GFRP plate were used; flame resisting epoxy and filling mortar. Four RC beam specimens were made and two of them were exposed to fire according to real scale fire curve proposed KS F 2257. After the fire exposure test, flexural test were performed to investigate the flexural performance of concrete beams including strength and deformation. From the test results, it was found that the beam retrofitted by NSM-GFRP presented higher flexural strength than that of the beam without retrofit, which indicates NSM-GFRP retrofit technologies is effective to maintain flexural strength even after fire exposure. In addition, the specimens grouted by epoxy showed good performance in strength but bad performance in ductility.

• 공업화학
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• 제21권6호
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• pp.627-631
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• 2010

본 연구에서는 암모늄염 처리에 의하여 리기다 소나무를 바탕으로한 재료의 난연성을 시험하였다. 실온에서 3종류의 암모늄염 즉, ammonium sulfate, monoammonium phosphate, 그리고 diammonium phosphate의 20 wt% 수용액에 각각 리기다 소나무를 함침시켜 건조시킨 후 콘칼로리미터(ISO 5660-1)를 이용하여 그들의 연소성을 조사하였다. 암모늄염으로 처리한 시험편들은 미처리된 시험편에 비하여 연소억제성을 향상시켰다. 그러나 CO의 발생량은 증가하여 정도에 따라 독성 영향을 미치는 것으로 보여졌다. 또한 미처리된 순수 시험편에 비해 총연기방출율과 총연기량이 모두 낮은 값을 나타내었다. 처리된 시험편 중 diammonium phosphate로 처리된 것이 가장 연소억제 효과가 강한 것으로 판단되었다.

• 한국수소및신에너지학회논문집
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• 제31권1호
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• pp.82-88
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• 2020

Recently, a fuel reforming plant for supplying high purity hydrogen has been studied to increase the operation time of underwater weapon systems. Since steam reforming is an endothermic reaction, it is necessary to continuously supply heat to the reactor. A fuel reforming plant needs a methanol-O₂ catalytic burner to obtain heat and supply heat to the reformer. In this study, two types of designs of a catalytic burner are presented and the results are analyzed through the experiments. The design of the catalytic burner is divided into that the O₂ supply direction is perpendicular to the methanol flow direction (Design 1) and the same as the methanol flow direction (Design 2). In case of Design 1, backfire and flame combustion occurred in the mixing space in front of the catalyst, and in the absence of the mixing space, combustion reaction occurred only in a part of the catalyst. For above reasons, Design 1 could not increase the exhaust gas temperature to 750℃. In Design 2, no flashback and flame combustion were observed, the exhaust gas could be maintained up to 750℃. However, the O₂ distributor was exposed to high temperatures, resulting in thermal damage.

• 에너지공학
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• 제19권3호
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• pp.163-170
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• 2010

소결버너를 이용한 표면점화는 제철공정에서 철광석의 소결을 위한 중요한 공정 중 하나이다. 본 연구에서는 듀얼 타입 소결 버너의 연소 특성을 분석하기 위하여 실험실적 규모의 실험과 전산 해석을 수행하였다. 라디칼 측정을 통해 연소특성을 파악하였으며, 열전대를 이용한 실험과 전산 해석 결과를 검증하였다. 검증된 전산 해석 모델을 바탕으로 싱글타입 소결 버너와 듀얼 타입 소결버너의 연소를 비교하였으며, 노즐 간격과 각도가 연소에 미치는 영향을 분석하기 위하여 3가지 노즐 간격 및 4개의 노즐 각도에 대한 전산해석을 수행하였다. 듀얼 타입이 싱글 타입 소결 버너보다 넓고 균일한 화염 폭을 형성함을 확인하였으며, 45도 비대칭 노즐 간격이 소결 베드 표면 점화를 위한 최적의 화염 폭을 형성함을 확인할 수 있었다.

• 한국추진공학회지
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• 제3권1호
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• pp.78-85
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• 1999

복기 추진제인 N-5 추진제에 4종의 금속선(Ag, Cu, Al, Ni-Cr선)을 삽입하여 연소 특성을 고찰하여 보았다. 금속선이 삽입된 복기 추진제의 연소속도 증가비($r_w$/$r_sb$)는 Ag선 > Cu선 > Al선 > Ni-Cr선의 순으로서 금속선의 열확산 계수의 크기 순과 일치하였다. 금속선을 삽입한 N-5추진제의 $r_w$/$r_sb$는 단열 불꽃 온도와 구조의 차이에 의하여 혼합형 추진제보다 작게 나타났다. 복기 추진제에 열확산 계수가 비교적 큰 Ag, Cu, Al선을 삽입한 경우, 금속선이 삽입되지 않은 추진제에서 나타난 plateau와 mesa 연소 특성이 사라진 반면 열확산 계수가 작은 Ni-Cr선을 삽입한 경우에서는 plateau와 mesa 연소 특성이 그대로 존재했다.

• 연구논문집
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• 통권27호
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• pp.101-108
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• 1997

The characteristics of combustion and emissions in multi-staged oil burner have been experimentally studied for the various range of equivalence ratios, drop sizes and fuel formulations. Malvern system was used to measure droplet size of fuel. Light fuel oil and light fuel oil doped with pyridine($C_5H _5N$) were used to investigate the effects on fuel NOx emission. The emissions of NO and CO in exhaust gas and the flame temperatures were measured by the gas analyzer and thennocouples. NOx emissions were increased by increasing the excess air ratio (range:$lambda=1.1-1.4$) or decreasing the SMD of droplet in single-staged burner. In comparison with the single-staged burner, the emission of NOx in multi-staged burner was reduced by 50% but CO emission was slightly increased. It is found that multi-staged burner has a good capability in reducing thermal NOx resulting from the distributed heat release rate and lower flame temperature in fuel-rich and fuel-lean combustion zone. Moreover, the fuel NOx emission of the multi-staged burner is lower than that of single-staged burner, because multi-staged burner has fuel rich zone where fuel N is converted to $N_2$ more than NO. In 3-staged burner, the percentage of each stage combustion air have strong influence on emission characteristics. It is also found that NOx emission can be reduced by decreasing inner and outer air percentage or increasing middle air flow rate and CO emission is vice versa.