• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.6
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• pp.1652-1660
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• 1990

Combined radiative-convective heat transfer in a hot gas tube flow has been investigated numerically and experimentally. In the numerical analysis, a standard k-.epsilon. model is used for the evaluation of turbulent shear stresses and spherical harmonics method with the Weighted Sum of Gray Gases Model for the solution of radiative transfer equation. In the experimental study measured are the velocity and temperature of the hot gas flow generated by the propane gas combustion, and tude wall heat flux distribution. Numerical results are compared with experimental ones and it is confirmed that P-3 provides quite reliable results in the analysis of the combined radiation-convection system.

• Bulletin of the Korean Chemical Society
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• v.35 no.7
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• pp.2057-2064
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• 2014

Thermochemical sulfate reduction (TSR) was conducted in autoclave on the system of crude oil and $MgSO_4$ at different temperatures. Gas chromatography pulsed flame photometric detector (GC-PFPD) was used to detected the composition of organic sulfur compounds in oil phase products. The results of the analysis indicate that with increased temperature, the contents of organic sulfur compounds with high molecular weight and thermal stability, such as benzothiophenes and dibenzothiophenes, gradually became dominated. In order to gain greater insight into the formation and distribution of organic sulphur compounds from TSR, positive ion electrospray Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used in detecting the detailed elemental composition and distribution of them. The mass spectra showed that the mass range of sulfur compounds was 200-550 Da. Four sulfur class species, $S_1$, $N_1S_1$, $O_1S_1$ and $O_2S_1$, were assigned in the positive-ion spectrum. Among the identified sulfur compounds, the $S_1$ class species was dominant. The most abundant $S_1$ class species increase associated with the DBE value and carbon number increasing which also indicates the evolution of organic sulfur compounds in TSR is from the labile series to the stable one. In pure blank pyrolysis experiments with crude oil cracking without TSR, different composition and distribution of organic sulfur compounds in oil phase products were seen from mass spectra in order to evaluate their pyrolysis behaviors without $MgSO_4$. FT-IR and XRD were used in analyzing the products of solid phases. Two distinct crystallographic phases MgO and $MgSO_4$ are found to coexist in the products which demonstrated the transformation of inorganic sulfur compounds into organosulfur compounds exist in TSR.

• The Journal of the Petrological Society of Korea
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• v.10 no.3
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• pp.172-178
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• 2001

K-Ar dating system of Korea Basic Science Institute (KBSI) was installed in 1997 and has been used since then. The system consists of high temperature graphite furnace, gas purification system, and mass spectrometer with data acquisition system. K-Ar age is determined by the measurement of the concentrations of Ar and K through isotope dilution method using $^{38}Ar$ as spike and flame spectroscopy, respectively. The accuracy and reliability for the K-Ar age are checked using the several K-Ar standard materials. Although the exact age determination for young samples of less than 1 Ma is hampered by small fluctuations of sensitivity and mass discrimination, the present system yields the reliable K-Ar age compared to the standard materials of Tertiary and Mesozoic age. The measurements for the SORI93 biotite with the recommended K-Ar age of $92.6\pm$0.6 Ma and Bern4M muscovite of $18.5\pm$0.6 Ma yield the reliable age of $92.1\pm$1.1 Ma and $17.8\pm$0.2 Ma, respectively.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.10
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• pp.652-658
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• 2016

Thermal batteries use inorganic salt as electrolyte, which is inactive at room temperature. As soon as heat pellets are fired by an igniter, all the solid electrolytes are instantly melted into excellent ionic conductors. However, the abnormal heat generation by the igniter flame or heat pellets causes the thermal decomposition of the electrode and the melting of the anode, eventually leading to a thermal runaway, which results in overheating or explosion. The thermal runaway can be significantly reduced by the adoption of $Zr/BaCrO_4$ heat papers. In this study, the heat papers with various ratios of fuel (Zr) and oxidizer ($BaCrO_4$) were prepared by the paper-making process. We have investigated the calorimetric value, burning rate, and ignition sensitivity. The ignition test of heat pellets and the discharge test of thermal batteries were also carried out. At the composition of 40 wt.% of Zr, the heat papers showed the highest specific calorimetric value and burning rate. As a result, $Zr/BaCrO_4$ heat paper made by the paper-making process has shown the applicability for thermal batteries.

• Journal of the Korea Institute of Building Construction
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• v.16 no.5
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• pp.397-403
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• 2016

As a building energy saving standard strengthened, The number of building installed external thermal insulation composite system(ETICS) using EPS insulation increased. But frequent fire accident in the buildings installed EIFS using EPS led to strengthening of building fire safety regulation. This study is for fire property of EPS ETICS reinforced with noncombustible calcium silicate-based mineral insulation as a fire spread prevention structure(FSPS). Fire test for large scale wall by ISO 13785-2 was applied and results showed EPS EIFS with FSPS got 3~8 times superior fire safety than normal EIFS by visual investigation. Temperature and heat flux measurement results, which data of upside of specimen were lower than downside, also supported fire safety of EIFS with FSPS.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.5 no.3
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• pp.218-222
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• 2004

We developed the stamper structured mold with moving core type with nano pattern. Among the factors affecting the quality of injection molding plastic parts, We studied the effects of moving core surface heating method on the transcription of injection molding plastic parts with nano structures. Moving core surface heating has been tested by three different methods. The first was conventional injection molding process without heating moving core surface, the second was halogen lamp radiation heating process and the last was MmSH process using gas flame. As a result of making injection molded parts by using thermoplastic amorphous resins such as COC, PMMA, MmSH method which is the most high temperature of moving core surface showed the best nano pattern transcription of the three methods, but the outcome of conventional injection molding process was not better than others.

• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.559-568
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• 2006

The purpose of this study is to evaluate the mechanical performance and fire resistance of wet-mixed high strength sprayed polymer-modified mortar in order to protect tunnel lining system which are in the event of fire disaster. Since the current commercial fire-resistant materials reproduce the low strength issue of mortar, this study aims to provide an enhanced fire-resistant mortar with a proper strength. Normally, a large temperature gradient phenomenon arise in the vicinity of free surfaces which are fully exposed in the event of persistent flame. Thereby, the determination of optimal cover depth of wet-mixed high strength sprayed polymer-mortar(WHSPM) is important for fire-resistance of tunnel lining system. With comparison of current commercial fire-resistance materials and WHSPM, the experimental result of WHSPM shows the better fire-resistant performance than the others. In addition, the cover limitation should be controlled by minimum 4cm depth in order to avoid fire-induced damage.

• Journal of Energy Engineering
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• v.16 no.3
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• pp.113-119
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• 2007

The auto-ignition characteristics and combustion behaviors of one-dimensional array of water-in-fuel droplets suspended in a high temperature chamber have been investigated experimentally with various droplet spacing and number of droplets. The fuels used were pure n-decane and emulsified n-decane with water contents varied from 10% to 30%. All experiments have been performed at 920 K under the atmospheric pressure. The number of droplets in an array were fixed as 3 or 5 and its spacing was varied from 3 mm to 7 mm by 1mm interval. The imaging technique with a high-speed camera has been adopted to measure the ignition delay and flame life time. The micro-explosion behaviors were also observed. As the droplet array sparing increased, the ignition delay also increased regardless of water contents. However, the life time of droplet array decreased as the droplet spacing increased. The full combustion time in array of 3 droplets was found to be longer than that for 5 droplets case due to the longer ignition delay.

• Fire Science and Engineering
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• v.30 no.4
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• pp.88-93
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• 2016

A fire detector installed in wood cultural properties has not have selected the detector type appropriate for the features of cultural properties and the structure of wood fire after the fire in Sungnyemun-Gate since 2008. Applying wooden cultural properties different from the general architecture of the structure and fire characteristics is difficult. Therefore, buildings were classified into four shape types and field survey and wooden architecture structure characteristics to identify the problems of the detectors installed on wooden cultural property buildings. The problems appeared to lack the adaptability to external fire detection sensor selection and missing fire detectors installed in accordance with the place. To solve the problem, the closed and open space of the rooms used a smoke detector, outdoor select flame or fixed temperature linear detector to solve the problem.

• Fire Science and Engineering
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• v.30 no.3
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• pp.16-22
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• 2016

Fire fighters rely on fire fighter protective clothing (FFPC) to provide adequate protection in the various hazardous environments. To enhance its protection performance, the FFPC material must be thick and thus it is difficult to achieve weight reduction. One of the methods of overcoming this problem, the addition of phase change material (PCM) to FFPC, is a new technology. In previous studies, the researches was mostly related to the temperature characteristics of the fibers incorporating PCM, but little information is available about its effect on burn injuries. Thus, in this study, the inhibitory effects of adding PCM to FFPC on second degree burns were investigated through numerical calculations. Thermal analyses of biological tissues and FFPC with embedded PCM exposed to several fire conditions causing severe tissue damage were studied by using a finite difference method based on the Pennes bio-heat equation. FFPC with embedded PCM was found to provide significantly greater protection than conventional fire fighting clothing, because the heat of absorption due to the phase change within the material is used to limit the heat conduction of the material.