• Title/Summary/Keyword: Fine-particle

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Study on Characteristics of PM2.5 and Its Ionic Constituents in Chuncheon, Korea (춘천시 PM2.5의 질량농도 및 이온성분 농도의 특성에 관한 연구)

  • Jung, Jin-Hee;Han, Young-Ji
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.6
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    • pp.682-692
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    • 2008
  • Fine particles ($PM_{2.5}$) were collected and analyzed from November 2005 through August 2007 in Chuncheon, Korea to investigate the characteristics of $PM_{2.5}$ and its ionic constituents. The average $PM_{2.5}$ concentration during the study period was $39{\mu}g/m^3$, which is almost two times higher than the annual US NAAQS $PM_{2.5}$ standard of $15{\mu}g/m^3$. $PM_{2.5}$ concentrations were higher in spring and winter than in summer and fall. During spring, Asian Dust events dramatically enhanced $PM_{2.5}$ concentrations, and long-range transport of $PM_{2.5}$ emitted in industrial area of China often occurred during winter based on trajectory analysis. Contribution of $PM_{2.5}$ to $PM_{10}$ concentrations ranged from $72{\mu}g/m^3$ during Asian Dust events to $457{\mu}g/m^3$, indicating that a large portion of $PM_{2.5{\sim}10}$ was transported from China during Asian Dust events. Among the major ionic constituents ${SO_4}^{2-}$ showed the highest concentration, followed by ${NH_4}^+$, ${NO_3}^-$ and ${NO_2}^-$. Chuncheon appeared to be ${NH_4}^+$ rich environment, indicating that $(NH_4)_{2}SO_4$ and ${NH_4}{NO_3}$ were the predominant forms of ${NO_3}^-$ and ${SO_4}^2$ in $PM_{2.5}$. Haze has frequently occurred in Chuncheon since So-Yang dam was constructed in 1973. Haze events were observed on 23 days during sampling period, and the average $PM_{2.5}$ concentration was approximately 1.6 times higher during haze events than during non-haze events. This result suggests that haze enhances the secondary aerosol formation because the aerosol spontaneously absorbs water to form a saturated salt solution, deriving a significant increase in the mass of the particle.

The Effect of Glue Solution on Manufacturing of White Clay Pigment (백토안료의 전통제법 중 아교수 영향에 관한 연구)

  • Kang, Yeong Seok;Jeong, Hye Young;Go, In Hee
    • Journal of Conservation Science
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    • v.32 no.3
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    • pp.417-423
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    • 2016
  • The effect of the glue solution were investigated in the grinding and elutriation process for manufacturing of White clay pigment. In grinding process, glue solution decreased the production of a too fine powder and enhanced the degree of sorting of ground pigments. The grinding performance and limit are generally influenced by the frictional force. Therefore, the friction force was measured in accordance with the grinding conditions. As a result of measuring a friction force, when using glue solution it showed the lowest friction. Finally, the application of glue solution in grinding process is believed to enhance the degree of sorting of ground pigments by reducing frictional force. In elutriation process, the application of glue solution enabled the screening of larger particles in the same conditions by reducing the sedimentation velocity. This result is due to increase in the viscosity of the glue solution according to glue concentration. As a result, the application of glue solution in elutriation process is though to enlarges the range of the selectable particle size and to enable the segmentation of the particles.

The Characteristics and Distribution of the Surface Sediment Grain Size of Nakdong River Deltaic Barrier Islands (낙동강 삼각주연안 사주섬 표층퇴적물의 입도특성과 공간적 분포)

  • Kim, Sung-Hwan;Rhew, Ho-Sahng;Shin, Young-Ho
    • Journal of the Korean association of regional geographers
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    • v.13 no.1
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    • pp.43-53
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    • 2007
  • Rapid geomorphic changes occur in Nakdong River deltaic coast which is composed of deltaic barrier islands and tidal flats. We investigate the pattern of these rapid geomorphic changes by analyzing the distributions of sediment grain size characteristics. The distributions of sediment grain size characteristics analysis is a very efficient method to explain geomorphic changes of deltaic barrier islands. In sediments from Jinwoo Island, Sinja Island, and Doyo Island which are composed of Nakdong River deltaic coast, mean particle size increases to onshore direction and become coarser in tidal inlets. All sediments are very well sorted. Though almost sediments show little negative skewness, several sediments from tidal inlets show negative skewness. These results provide that the stronger and more regular energies affect Nakdong River deltaic coast and make fine sediments selectively move toward tidal inlets. Because of this mechanism, the recurved spits of deltaic barrier islands enlarge.

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Release of Heavy Metals into Water from the Resuspension of Coastal Sediment (연안 오염퇴적물의 재부상에 의한 중금속의 수계용출특성)

  • Song, Young-Chae;Subha, Bakthavachallam;Woo, Jung-Hui
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.7
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    • pp.469-475
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    • 2014
  • The study investigated the physicochemical characteristics and the ecological risk of the Northport sediment in B city and the releasing properties of heavy metals into seawater during the resuspension also studied. The major components of the sediment are fine silt and clay which contains high organic matter and AVS (Acid volatile sulfide) and the ecological risk of the heavy metals in sediment also very high. The release rate of heavy metals into seawater was in order of Pb>>Cu>Cr>>Zn>Cd during the resuspension in a batch experiment, and the heavy metal release mainly attributed to the oxidation of metal sulfides. Heavy metals which came from easily oxidisable metal sulfides rapidly contaminated seawater within about 1.0 h of the sediment resuspension. The sulfide oxidation during the resuspension increased the residual fraction of heavy metals in the sediment, decreased the organic bound fraction, and changed the other fractions of heavy metals in the sediment. The release of heavy metals from the sediment during resuspension was affected by the resuspension time, the oxidation rate of metal sulfides and resuspended concentration of the sediment particle.

Comparative Study on Removal Characteristics of Disinfection By-products by Air Stripping and Flotation Processes (탈기와 부상 공정에 의한 소독부산물의 제거특성에 관한 비교 연구)

  • Cha, Hwa-Jeong;Won, Chan-Hee;Lee, Kang-Hag;Oh, Won-Kyu;Kwak, Dong-Heui
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.9
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    • pp.513-520
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    • 2016
  • It is well known that volatile compounds including disinfection by-products as well as emissive dissolved gas in water can be removed effectively by air stripping. The micro-bubbles of flotation unit are so tiny as microns while the diameter of fine bubbles applied to air stripping is ranged from hundreds to thousands of micrometer. Therefore, the micro-bubbles in flotation can supply very wide specific surface area to transfer volatile matters through gas-liquid boundary. In addition, long emission time also can be gained to emit the volatile compound owing to the slow rise velocity of micro-bubbles in the flotation tank. There was a significant difference of the THMs species removal efficiency between air stripping and flotation experiments in this study. Moreover, the results of comparative experiments on the removal characteristics of THMs between air stripping and flotation revealed that the mass transfer coefficient, $K_La$ showed obvious differences. To overcome the limit of low removal efficiency of dissolved volatile compounds such as THMs in flotation process, the operation range of bubble volume concentration is required to higher than the operation condition of conventional particle separation.

Comparison of Utrasonic and Vibration Diagnostic Techniques for the Inspection of Pipes in CVD System (화학증착 시스템에서의 파이프내 오염입자 관찰을 위한 초음파 및 진동 진단법의 비교연구)

  • Yun Ju-Young;Seong Dae-Jin;Shin Yong-Hyoen;Lee Ji-Hun;Moon Doo-Kyung;Kang Sang-Woo
    • Journal of the Korean Vacuum Society
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    • v.15 no.4
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    • pp.421-426
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    • 2006
  • In examining particulate deposits in the pipes of a chemical vapor deposition (CVD) system, vibration diagnostics is compared and studied against ultrasonic diagnostics, The latter method involves pulsing the outer wall of pipes with an ultrasonic sensor and analyzing the resulting echo to observe particulate deposits inside pipes. Vibration diagnostics examines the existence of particulate deposits by analyzing the difference in the frequencies generated when a vibrator is adhered to the outer wall of pipes. With ultrasonic diagnostics, good test results were obtained only when particulate deposits were attached to the inner wall of the pipes, After some time, however, particulate deposits were not detected properly, as the ultrasonic wave failed to cross the fine gaps created between the inner wall of the pipe and the deposits. The ultrasonic wave bounced back because of the dried particulate deposits on the wall. Thus, it has been proven that the ultrasonic diagnostics is not an appropriate means of examining the particulate deposits in a vacuum, On the other hand, vibration diagnostics succeeded in detecting the particulate deposits regardless of the lapsed time. In conclusion, the vibration diagnostics is being expected as the effective method in monitoring the particulate deposits inside pipes in the CVD system where the desired behavior is reduced frequency along with the particulate deposits in comparison to the case where the pipe is clean.

Comparison of Ambient Real-Time PM2.5 Concentrations at Major Roadside with on those at Adjacent Residential Sites in Seoul Metropolitan City (서울시 도로변지역과 인근 주거 밀집지역의 실시간 대기 중 PM2.5농도 비교)

  • Yun, Dongmin;Kim, Bokyeong;Lee, Dongjae;Lee, Seonyeob;Kim, Sungroul
    • Journal of Environmental Science International
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    • v.24 no.7
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    • pp.875-882
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    • 2015
  • In 2013, International Agency for Research on Cancer (IARC) concluded that outdoor air pollution is carcinogenic to humans, with the particulate matter component of air pollution most closely associated with sufficient evidence of increased cancer incidence by exposure to particulate matter component of air pollution. Motor vehicles are one of a major emission sources of fine particle ($PM_{2.5}$) in urban areas. A large number of epidemiological studies have reported a positive association of morbidity or mortality with distance from the roadside. We conducted this study to assess the association of $PM_{2.5}$ concentrations measured at roadside hotspots with those at adjacent residential sites using real-time $PM_{2.5}$ monitors. We conducted real-time $PM_{2.5}$ measurements for rush hour periods (08:00~10:00 and 18:00~20:00) at 9 roadside air monitoring Hotspot sites in metropolitan Seoul over 3 weeks from October 1 to 21, 2013. Simultaneous measurements were conducted in residential sites within a 100 m radius from each roadside air monitoring site. A SidePak AM510 was used for the real-time $PM_{2.5}$ measurements. Medians of roadside $PM_{2.5}$ concentrations ranged from $9.8{\mu}g/m^3$ to $38.3{\mu}g/m^3$, while corresponding median values at adjacent residential sites ranged from $4.4{\mu}g/m^3$ to $37.3{\mu}g/m^3$. $PM_{2.5}$ concentrations of residential sites were 0.97 times of hotspot roadside sites. Distributions of $PM_{2.5}$ concentrations in roadside and residential areas were also very similar. Real-time $PM_{2.5}$ concentrations at residential sites, (100 m adjacent), showed similar levels to those at roadside sites. Increasing the distance between roadside and residential sites, if needed, should be considered to protect urban resident populations from $PM_{2.5}$ emitted by traffic related sources.

Correlation Between Physical and Compaction Characteristics of Various Soils (다양한 지반의 물리적 특성과 다짐특성 상관성)

  • Park, Choonsik;Kim, Jonghwan
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.1
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    • pp.23-29
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    • 2017
  • This study, to provide quantitative data related to compaction characteristics, identifies the compaction characteristics of various types of soil samplers, in relation to their particle-size distribution and plasticity degree, and the compaction characteristics of artificially created granular materials, in relation to their A & D compaction. The results of the experiments show as follows. $r_{dmax}$ of clay is less than those of both sand and gravel approximately by 10%. O.M.C of clay has turned out to be greater than sand and gravel approximately by 20% and 30%, respectively. Changes in the compaction characteristics can be observed clearly around 30~60% of sand and 30~50% of passing No.200 sieve. It has also been shown that the compaction characteristics related to LL and PL are similar to each other in changes, and that the compaction characteristics become less clear with higher percent of fine grained soil. The compaction characteristics of the artificially created granular materials and field materials have appeared almost similar to each other. $r_{dmax}$ is less approximately by 30% and O.M.C greater approximately by 20% in A compaction than in D compaction. As $r_{dmax}$ and O.M.C become greater, its rate increases.

Plasma Etching Characteristics of Sapphire Substrate using $BCl_3$-based Inductively Coupled Plasma ($BCl_3$ 계열 유도결합 플라즈마를 이용한 사파이어 기판의 식각 특성)

  • Kim, Dong-Pyo;Woo, Jong-Chang;Um, Doo-Seng;Yang, Xue;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.363-363
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    • 2008
  • The development of dry etching process for sapphire wafer with plasma has been key issues for the opto-electric devices. The challenges are increasing control and obtaining low plasma induced-damage because an unwanted scattering of radiation is caused by the spatial disorder of pattern and variation of surface roughness. The plasma-induced damages during plasma etching process can be classified as impurity contamination of residual etch products or bonding disruption in lattice due to charged particle bombardment. Therefor, fine pattern technology with low damaged etching process and high etch rate are urgently needed. Until now, there are a lot of reports on the etching of sapphire wafer with using $Cl_2$/Ar, $BCl_3$/Ar, HBr/Ar and so on [1]. However, the etch behavior of sapphire wafer have investigated with variation of only one parameter while other parameters are fixed. In this study, we investigated the effect of pressure and other parameters on the etch rate and the selectivity. We selected $BCl_3$ as an etch ant because $BCl_3$ plasmas are widely used in etching process of oxide materials. In plasma, the $BCl_3$ molecule can be dissociated into B radical, $B^+$ ion, Cl radical and $Cl^+$ ion. However, the $BCl_3$ molecule can be dissociated into B radical or $B^+$ ion easier than Cl radical or $Cl^+$ ion. First, we evaluated the etch behaviors of sapphire wafer in $BCl_3$/additive gases (Ar, $N_2,Cl_2$) gases. The behavior of etch rate of sapphire substrate was monitored as a function of additive gas ratio to $BCl_3$ based plasma, total flow rate, r.f. power, d.c. bias under different pressures of 5 mTorr, 10 mTorr, 20 mTorr and 30 mTorr. The etch rates of sapphire wafer, $SiO_2$ and PR were measured with using alpha step surface profiler. In order to understand the changes of radicals, volume density of Cl, B radical and BCl molecule were investigated with optical emission spectroscopy (OES). The chemical states of $Al_2O_3$ thin films were studied with energy dispersive X-ray (EDX) and depth profile anlysis of auger electron spectroscopy (AES). The enhancement of sapphire substrate can be explained by the reactive ion etching mechanism with the competition of the formation of volatile $AlCl_3$, $Al_2Cl_6$ or $BOCl_3$ and the sputter effect by energetic ions.

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A Study on the Removal Efficiency of Harmful Pollutants in the Cooking Chamber (조리실내의 유해오염물질 제거율에 관한 연구)

  • Kwon, Woo-Taeg;Lee, Woo-Sik
    • Culinary science and hospitality research
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    • v.22 no.8
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    • pp.149-156
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    • 2016
  • The purpose of this study is to reduce the contaminants (total volatile organic compounds (TVOCs), fine particle, odor and total airborne bacteria) during cooking process in cooking chamber, and to decrease the health damage in indoor space that has bad work environment. In order to solve the shortcomings of existing air purifiers and remove all kinds of pollutants effectively, this study focused on the development of indoor air purifiers which are made of bar type. Bio-ceramics filter which combines activated carbon and loess. The air cleaners developed with 4 measuring items including TVOCs, particulate matter, complex odor and total airborne bacteria were measured comparing their pre-service test to their post-service test after a period of time. The measured results showed higher removal efficiency of 91.02% as the concentration of TVOCs was reduced from $2,500{\mu}g/m^3$ to $223{\mu}g/m^3$. Second, the particulate matter removal ratio was 97.51% efficient with average concentration of $26.68{\mu}g/m^3$. Third, the odor showed 95.20% reduction as air dilution ratio averaged out at 144. Last, total airborne bacteria was eliminated by over 94% showing the changeable concentration from $787{\sim}814CFU/m^3$ to $47{\sim}40CFU/m^3$. In addition, the removal rate of harmful pollutants is excellent, and it is expected that the environment of the existing poor cooking room will be greatly improved by using the developed air purifier in combination with the ventilation device and the stove hood.