• 전자공학회논문지A
• /
• 제29A권7호
• /
• pp.73-81
• /
• 1992

We have investigated the thermal reaction property and the oxygen behavior of TiN/Ti/Si structure after different hear treatments using x-ray photoelectron spectroscopy and cross-sectional transmission electron microscopy measurements. During the heat treatment in N$_2$ amibient, the considerable amount of oxygen atoms incorporates into TiN/Ti/Si Structures. It is found that oxygen atoms pile up at the top surface of TiN and TiN/Ti interface, forming a compound of TiO$_2$ above $600^{\circ}C$. Inside the TiN film, the oxygen content increases as the annealing temperature increases, mostly TiO and Ti$_2$O$_3$ rather than thermodynamically stable TiO$_2$. Above the annealing temperature of 55$0^{\circ}C$, the TiSi$_2$ formation has initiated. One thing to note is that a severe blistering is observed in the sample annealed at $600^{\circ}C$, due to (1) the difference of thermal expansion coefficient between TiN and Si` (2) the compressive stress induced by the volume reduction caused by the Ti-Silicide grain while elevating temperatures.

• Journal of Information Display
• /
• 제4권2호
• /
• pp.29-34
• /
• 2003

We have studied liquid crystal (LC) molecular alignment on rubbed and photoaligned surfaces. Particular attention was paid to the intermolecular liquid crystalline interaction. We will first show that uniform molecular orientation on a rubbed surface does not mean spatially uniform interaction between the surface and LC molecules. Rather LCs tend to align themselves through LC interaction. The existence of nonuniformity of rubbing was successfully visualized by double surface treatment. The importance of intermolecular LC interaction was also found in the orientation formation process in 5CB evaporated on rubbed and photoaligned surfaces. By simultaneously analyzing polarized UVNIS absorption and second-harmonic generation (SHG) using the maximum entropy method, we succeeded in obtaining the temporal variation of the orientational distribution functions in the film forming process. The distribution anisotropy and pretilt are found to be generated under the influence of intermolecular LC interaction.

• International Journal of Ocean System Engineering
• /
• 제1권1호
• /
• pp.46-51
• /
• 2011

In a line heating process for hull forming, the phase of the steel transforms from austenite to martensite, bainite, ferrite, or pearlite depending on the actual speed of cooling following line heating. In order to simulate the water cooling process widely used in shipyards, a heat transfer analysis on the effects of impinging water jet, film boiling, and radiation was performed. From the above simulation it was possible to obtain the actual speed of cooling and volume percentage of each phase in the inherent strain region of a line heated steel plate. Based on the material properties calculated from the volume percentage of each phase, it should be possible to predict the plate deformations due to line heating with better precision. Compared to the line heating experimental results, the simulated water cooling process method was verified to improve the predictability of the plate deformation due to line heating.

• 한국세라믹학회지
• /
• 제37권7호
• /
• pp.665-672
• /
• 2000

The ferroelectric YMnO3 thin films were prepared by MOD(metal-organic decomposition) method with Y- and Mn-acetylacetonate as starting materials. Thin films were grown on various substrates by spin-coating technique. The crystalline phases of the thin films were identified by X-ray diffractometer as a function of heat-treatment temperature, pH of coating solution and substrate. In addition, the effect of Mn/Y molar ratio(0.8~1.2) on the formation of hexagonal-YMnO3 phase was investigated. In forming highly c-axisoriented hexagonal-YMnO3 single phase, the Pt coated Si substrate was more effective than the bare Si substrate, and the optimum heat-treatment condition was at 82$0^{\circ}C$ for 30 min. Higher Mn/Y molar ratio within 0.8~1.2 and pH of YMnO3 precursor solution within 0.5~2.5 favored formation of ferroelectric hexagonal phase rather than orthorhombic phase. Leakage current density of the hexagonal-YMnO3 thin film formed on Pt(111)/TiO2/SiO2/Si substrate was low enough as 0.4~4.0$\times$10-8(A/$\textrm{cm}^2$) at 5 V and its remanent polarization(Pr), calculated from the P-E hysteresis loop, was 3 nC/$\textrm{cm}^2$.

• 한국화재소방학회:학술대회논문집
• /
• 한국화재소방학회 1997년도 International Symposium on Fire Science and Technology
• /
• pp.598-605
• /
• 1997

In recent years, the number of vehicle fires, as well as the number of motor vehicles, has been increasing rapidly. Therefore, several types of automatic fire suppression systems for the engine compartment of automobiles have been developed to extinguish automobile fires, and most of these systems use halon 1301 as a fire extinguishing agent. Due to environmental concerns, the phase-out of halons has been announced, so now there is a need to replace halon 1301. For this, a 1,1,1,2,3,3,3-heptaflouropropane (HFC-227ea, FM-$200^{TM}$) gas-filled Aqueous Film- Forming foam (known as AFFF) extinguisher was devised even though air foam extinguishers could be used. This is because the air in the foam bubbles is a source of oxygen required for the combustion reaction. It can be surmised that it is possible to increase the fire extinguishing efficiency of AFFF by filling in foam bubbles with a gaseous extinguishing agent. The best choice is the FM-$200^{TM}$ gas-filled AFFF, Which has the maximum expansion ratio of 62:1. This makes it possible for the expanded foam to rapidly fill the engine compartment.

• 한국화재소방학회논문지
• /
• 제23권3호
• /
• pp.61-66
• /
• 2009

본 연구에서는 미분무수 노즐을 이용하여 설치높이 변화에 따른 3종의 포 소화 약제를 각각 혼합하여 소화성능 실험을 수행하였다. 소화성능 실험 결과 순수한 물과 기존의 3%형 수성막포를 사용한 경우보다는 2%형 미분무수 전용 수성막포와 1%형 합성계면활성제포가 더욱 빠른 소화시간을 나타내었다. 또한, 순수한 물만을 사용한 경우에는 3.5m, 포 소화 약제를 사용하였을 때에는 4m의 설치높이에서 가장 좋은 소화효과 나타내었다.

• 비교문화연구
• /
• 제19권
• /
• pp.101-126
• /
• 2010

Narcissism is a pathological phenomenon and narcissistic subject always needs to put itself on the top and has interest in nothing but its own determination. The protagonist of Adversary by ?mmanuel Carr?re does pay careful attention to what others are thinking of him while he does not distinguish difference between object of love and himself. So he can be allegedly narcissistic subject. And it can be said that the behaviors of Mary in the movie Under the sand by Ozon are included in narcissism in that narcissistic subject has the characteristics that idealizes the object of libido. However, in this study, the heroine is examined based on such a point that the object of love and extreme idealization incline toward others. We call this case reverse-narcissism. In Part 2, it is investigated what relation narcissism as an unconscious psychological tool has with Oedipus complex, which plays an important role in forming human psyche. For instance, disappointment caused by prohibition at the oedipal stage is too severe, which creates superego and its idealization to protect in such a way that narcissistic regression can not be done. Cases of extremely big gap between ego and ideal type are perversion, impostor, mania, paranoia, etc, where narcissistic and oedipal elements are combined to affect.

• 소성∙가공
• /
• 제28권3호
• /
• pp.115-122
• /
• 2019

In this paper, finite element analysis of an automatic five-stage precision cold forging process of a yoke, a steering part of a passenger's car, is conducted with emphasis on spring back analysis at the yoke-forming stage and its experimental verification is subsequently made. An elastoplastic finite element method with MINI-element technique employed for the analysis of the entire process is explained. There is emphasis that the thin film of material formed between the punch and die in the stage may result to some errors especially in elastoplastic finite element analysis of spring back due to frequent remeshing. The numerical robustness of the spring back analysis in regards to remeshing is hence shown first through investigation into its effect on the predicted spring back. Experimental measurement of displacement due to spring back is carried out for comparison with the predicted results, and they are in a qualitative agreement with each other.

• 한국표면공학회지
• /
• 제52권3호
• /
• pp.145-149
• /
• 2019

Transparent and conductive ZnO/Ag/SnO2 (ZAS) tri-layer films were deposited onto glass substrates at room temperature by using radio frequency (RF) and direct current (DC) magnetron sputtering. The thickness values of the ZnO and $SnO_2$ thin films were kept constant at 50 nm and the value for Ag interlayer was varied as 5, 10, 15, and 20 nm. In the XRD pattern the diffraction peaks were identified as the (002) and (103) planes of ZnO, while the (111), (200), (220), and (311) planes could be attributed to the Ag interlayer. The optical transmittance and electrical resistivity were dependent on the thickness of the Ag interlayer. The ZAS films with a 10 nm thick Ag interlayer exhibited a higher figure of merit than the other ZAS films prepared in this study. From the observed results, a ZAS film with a 10 nm thick Ag interlayer was believed to be an alternative transparent electrode candidate for various opto-electrical devices.

• Corrosion Science and Technology
• /
• 제21권3호
• /
• pp.200-208
• /
• 2022

Aluminum alloy is used by adding various elements according to the needs of the industry. Aluminum alloys such as 5052 and 6061 are known to possess excellent corrosion resistance by adding Mg. Despite their excellent physical properties, corrosion can occur. To solve this problem, an anodization technique generally can improve corrosion resistance by forming an oxide structure with maximized hydrophobic properties through coatings. In this study, the anodizing technique was used to improve the hydrophobicity of aluminum 5052 and 6061 by creating porous nanostructures on top of the surface. An oxide film was formed by applying anodizing voltages of 20, 40, 60, 80, and 100 V to aluminum alloys followed by immersion in 0.1 M phosphoric acid for 30 minutes to expand oxide pores. Contact angle and corrosion characteristics were different according to the structure after anodization. For the 5052 aluminum, the corrosion potential was improved from -363 mV to -154 mV as the contact angle increased from 116° to 136°. For the 6061 aluminum, the corrosion potential improved from -399 mV to -124 mV when the contact angle increased from 116° to 134°.