• Macromolecular Research
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• 제8권6호
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• pp.285-291
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• 2000

Influence of silane coupling agent, bis-(3-(triethoxisilyl)-propyl)-tetrassulfide, on cure characteristics and bound rubber content of filled styrene-butadiene rubber (SBR) compounds and on physical properties of the vulcanizates was studied. Carbon black-filled and silica-filled compounds were compared. Content of the bound rubber increased with increased content of the silane coupling agent and this trend was shown more clearly in the silica-filled compounds. Optimum cure time of the carbon black-filled compound increased with increase of the silane content, while that of the silica-filled one decreased. Cure rate of the carbon black-filled compound became slower as the silane content increased while that of the silica-filled one became faster. By increasing the silane content, the minimum torque decreased and the delta torque increased. Physical properties of the silica-filled vulcanizate were found to be improved by adding the silane coupling agent. However, for the carbon black-filled vulcanizates, the tensile strength and tear resistance decreased with increase of the silane content. The differences between the carbon black-filled and silica-filled compounds were explained by difference in the reactivities of the fillers with the silane.

• 한국식품조리과학회지
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• 제33권2호
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• pp.181-189
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• 2017

Purpose: This study was conducted to examine the effects of the starch concentration of filled hydrogel and the addition of ${\alpha}-amylase$ and simulated mastication processing in an oral phase on lipid digestion and ${\beta}-carotene$ bioaccessibility of filled hydrogels. Methods: Lipid digestion and ${\beta}-carotene$ bioaccessibility of the filled hydrogels were measured after the samples were passed through an in vitro gastrointestinal tract model consisting of oral, gastric, and small intestinal phases. Results: The initial rate and final extent of lipid digestion were higher in the filled hydrogels than in the emulsion when the filled hydrogels were treated in an oral phase without simulated mastication processing and addition of ${\alpha}-amylase$, regardless of starch concentration. However, when the filled hydrogels were minced using mortar and pestle for 2 min and were exposed to ${\alpha}-amylase$, the filled hydrogel fabricated with 5% starch showed the lowest lipid digestion rate and extent compared to the emulsion and other filled hydrogels. Bioaccessibility of ${\beta}-carotene$ was higher in the filled hydrogels than in the emulsion, regardless of the digestion method performed in an oral phase and starch concentration. However, there were appreciable differences in bioaccessibility of the filled hydrogels depending on whether or not simulated mastication and addition of ${\alpha}-amylase$ were employed. Conclusion: These results suggested that the rheological properties of initial filled hydrogels and simulated mastication processing in an oral phase plays an important role in determining the lipid digestion and ${\beta}-carotene$ bioacccessibility entrapped within filled hydrogels.

• 폴리머
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• 제32권3호
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• pp.270-275
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• 2008

고무재료의 피로균열 성장특성은 고무제품의 강도와 내구성을 평가하는 매우 중요한 요소이다. 본 연구에서는 자체 제작한 피로균열 성장 측정기를 이용하여 충전제 종류에 따른 EPDM의 피로균열 성장특성을 고찰하였다. 피로균열성장은 진동수와 측정온도에 영향을 받았으며, 진동수가 증가함에 따라 균열성장속도는 감소하였고 온도가 증가함에 따라 균열성장속도는 증가하였다. 충전된 EPDM의 인열에너지와 균열성장속도의 상관관계는 지수법칙을 따랐으며, 충전제의 함량이 증가함에 따라 균열성장속도가 감소하였다. 또한, 실리카로 충전된 EPDM이 카본블랙으로 충전된 EPDM에 비해 더 우수한 피로저항 특성을 보였다. 실리카로 충전된 경우, 균열성장속도는 30 phr까지 감소하다가 그 이후 다시 증가하였다. 미충전 시편의 피로 파괴단면 SEM 사진에서 작고 유연한 파괴자국들이 관찰되었으며, 실리카가 충전된 시편의 단면에서는 보강효과로 인하여 인열 형태가 불규칙 적이고 비교적 거친 표면이 관찰되었다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2008년도 추계 학술논문 발표대회
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• pp.117-120
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• 2008

The Purpose of this is properties of CFT filled with expansion concrete. CFT(concrete filled steel tube) is the structure that circle shape steel column filled with concrete. 3 kinds of expansive additives and variation of replacement rate. we changed expansive additive from 0%, 10%, 20%, 30% of ratio of addition rate are selected for this experiment. Merits of CFT are concrete internal force rising influenced by steel shape restriction, reinforcing the local buckling, excellent resistance to transformation. Generally, High rise building using CFT utilize the high strength and fluidity concrete for packing the tube inside. As the result a steel tube charged expensive concrete has stiffness 1.5times more than a steel tube not charged concrete. Increase of resisting power about compressive stress by binding expansion of expansive concrete affects strength increase and softness.

• 한국가시화정보학회지
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• 제6권2호
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• pp.28-32
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• 2008

Contrary to the flow rate in fully filled pipe flows, the flow rate in partially filled pipe flows is significantly influenced by the variation of water level, channel slop, and so on. The major difference in these two flows results from the existence of a free surface. To make it clear, in the present study, a similarity of the velocity profile in a partially filled circular pipe has been investigated according to the water level. A particle image velocimetry (PIV) technique was applied to measure the three-dimensional velocity profiles. As a result, there is found a similarity of the velocity profile near the central region. However, near the side wall, the similarity is broken due to the interaction between the wall and the free surface.

• 폴리머
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• 제37권3호
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• pp.269-275
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• 2013

화학적 구조가 다른 thiuram계 TMTD(tetramethyl thiuram disulfide), DPTT(dipenta-methylene thiuram tetrasulfide), thiazole계 MBT(2-mercapto benzothiazole), MBTS(2,2-dithiobis(benzo-thiazole)), sulfenamide계 CBS(n-cyclohexyl benzothiazyl-2-sulfenamide), NOBS(n-oxydiethylene benzo-thiazyl-2-sulfenamide), 아연이 포함된 thiuram계 ZDBC(zinc di-n-butyl-dithiocarbamate)를 사용하여 각각의 촉진제가 실리카와 카본블랙으로 충전된 천연 고무 복합소재의 가황 속도 및 가황 지수에 미치는 영향을 비교 평가하였다. 양 시스템에서 가황 속도는 thiuram계, thiazole계, sulfenamide계의 순서로 동일한 경향을 보였다. 각 촉진제에 대하여 실리카 컴파운드는 카본블랙 컴파운드에 비해 $t_{s2}$, $t_{10}$, $t_{90}$에 도달하는 시간이 느리게 나타났으며 느린 가황 지수(CRI)를 나타내었다.

• Elastomers and Composites
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• 제33권4호
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• pp.274-280
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• 1998

가황반응에 대한 반응차수, 반응속도상수 및 활성화에너지, 가교결합에 의한 가교밀도 및 탄성상수를 동일한 가황시스템하에서 실리카와 카본블랙을 함유한 SBR/BR 블렌드에 대하여 조사하였다. 반응차수는 충전제 종류에 관계없이 1차 반응이었으며, 카본블랙이 첨가된 배합고무는 실리카가 첨가된 배합고무보다 반응속도가 빠르게 나타났다. 그러나 활성화에너지는 충전제 종류 및 고무 블렌드 조성에 관계없이 일정하게 나타났다. 가교밀도 및 탄성상수는 고무와 카본블랙간의 강한 상호작용으로 인해 카본블랙이 첨가된 조성물에서 높게 나타났다. 한편, 고무 블렌드중 부타디엔 고무 함량이 증가할수록 가교밀도 및 탄성상수는 감소하였다. 가황고무중 결합 황 함량 비교결과, 실리카가 첨가된 조성물중 일정한 결합 황 함량은 반응시작 후 20분 후에 나타났으나, 카본블랙이 첨가된 조성물은 10분 후에 나타났다. 또한 실리카가 첨가된 조성물은 카본블랙이 첨가된 조성물에 비해 반응 유도시간($t_2$) 및 최적 가황시간($t_{90}$)이 길게 나타났다.

• 대한설비공학회:학술대회논문집
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• 대한설비공학회 2006년도 하계학술발표대회 논문집
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• pp.773-778
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• 2006

Velocity profiles inside a partially filled pipline have been investigated experimentally. To measure the velocity fields, a particle image velocimetry (PIV), which is a recent quantitative visualization technique, is applied. The velocity profile inside a circular pipe is well known, but if the pipe is partially filled, the problem is entirely different in the sense that the velocity distribution is significantly affected by the slope of pipe and filled water level, and so on. In order to calculate exact flow rate in the open channel or partially filled pipeline, three-dimensional velocity distributions at a given cross-sectional area are measured and compared the flow rates with the previously known empirical formula of Manning equation. The results show that the velocity profiles at center plane is considerably different from each other when the slope and water level change. Thus, The three-dimensional velocity profile can be the most plausible estimate for the exact flow rate.

• Tribology and Lubricants
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• 제5권1호
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• pp.12-20
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• 1989

The friction and wear behavior of molybdenum disulfide filled polymer composites sliding against metal has been investigated using pin-on-disc machine and microscope. The observed wear rates were reduced by the addition of MoS$_2$ to nylon and this can be attributed to the homogenous transfer of MoS$_2$ to the counteddace thereby modifying sliding conditions. The friction of filled and unfilled nylon was increased with increasing sliding speed, and the catastropic wear rate was occurred at high normal load. This have been explained by thermal degradation. In the case of HDPE, however, the wear rate was not always reduced by the addition of MoS$_2$ and the influence of MoS$_2$ was mainly even the opposite. Filled and unfilled HDPE had lower values of friction and wear rate than those of nylon. Micrographs appeared that the delamination of the worn surface in nylon/MoS$_2$ composite occurred and revealed that the worn surface of HDPE presented a number of characteristic features as wear grooves, pulls, and smears and crescents.

• 한국가시화정보학회:학술대회논문집
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• 한국가시화정보학회 2006년도 추계학술대회 논문집
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• pp.73-77
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• 2006

Flow rate measurement is one of the difficult problems in the industrial applications. Especially, flow rate in a partially filled pipeline is affected by many parameters such as water level, channel slop, etc. In the present study, prior to the development of a flowmeter, the flow characteristics has been investigated by particle image velocimetry (PIV) measurements. Three-dimensional velocity distributions were obtained from sectional measurements of velocity profiles according to the water level. As a result, it is found that there is no similarity in the velocity profile when the lateral position is changed. In addition, the maximum velocity does not always occur on the free surface. It depends on the water level. In the aspect of flow rate measurement, the previous calculus based upon point measurement techniques is proved to be inaccurate because of the lack of whole flow information.