• Title/Summary/Keyword: Field Emission

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Electrical Conduction Characteristics of a Thick-film Form Multiwalled Carbon Nanotubes for Field Electron Emitter

  • Lee, Yun-Hi;Kim, Hoon;Ju, Byeong-Kwon;Yu, Jae-Eun;Oh, Myung-Hwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.53-54
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    • 2000
  • Measurements of the direct current resistivity, on multiwalled carbon nanotubes(MWNT) for field electron emitter source that had been screen printed in a thick film form were made as a function of temperature T in the range of 1.7K-390K. In this measuring temperature range, the electrical resistivity for the MWNT show that the main contribution to the conductivity comes form carries that hop directly between localized states executing variable range hopping processes. This thick-film form system for large area display showed a high bright light emission as well as very low turn-on field as like an individual MWNT system at room temperature. Furthermore, the electron emission characteristics followed well typical Fowler-Nordheim conduction under the vacuum.

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Field Emission Character and Low Temperature Synthesize of Carbon Nanofibers using Fe-phthalocyanine (Fe-Phthalocyanine을 이용한 Carbon Nanofiber의 저온합성과 전계전자방출 특성)

  • ;T. Ikuno;M. katayama;K. Oura
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.2
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    • pp.242-247
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    • 2004
  • Using Ar plasama and Fe-phthalocyanine, carbon nanofibers have been synthesized at a low temperature. Fe-phthalocyanine was used as a source material for this process. The carbon nanofibers were grown in random orientation with a diameter of about 100 nm and length up to 10${\mu}{\textrm}{m}$ on Si substrate. The synthesized carbon nanofibers exhibited excellent field emission characteristics. Protrusions with a nanometer size are observed at an angle of 60$^{\circ}$with respect to the nanofiber axis. Furthermore, we found the selective growth of nanofibers on a scratched substrates.

Modeling of transient temperature distribution in multilayer asphalt pavement

  • Teltayev, Bagdat B.;Aitbayev, Koblanbek
    • Geomechanics and Engineering
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    • v.8 no.2
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    • pp.133-152
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    • 2015
  • Mathematical model has been developed for determination of temperature field in multilayer pavement and subgrade, which considers transfer of heat by conduction and convection, receiving of heat from total solar radiation and atmosphere emission, output of heat due to the emission from the surface of pavement. The developed model has been realized by the finite element method for two dimensional problem using two dimensional second order finite element. Calculations for temperature field have been made with the programme realized on the standard mathematical package MATLAB. Accuracy of the developed model has been evaluated by comparison of temperatures, obtained theoretically and experimentally. The results of comparison showed high accuracy of the model. Long-term calculation (within three months) has been made in pavement points in accordance with the data of meteorological station for air temperature. Some regularities have been determined for variation of temperature field.

Enhanced characteristics of Molybdenum field emission arrays under laser irradiation

  • 송병권;서도석;남창우;홍진표;김채옥;차승남;이항우;박남신;이내성
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.154-154
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    • 2000
  • FED(Field emission display)의 FEAs(Field emitter arrays)에 형성되어 있는 micro-tip 은 tip 표면의 오염이나 진공내부의 잔류가스에 대단히 민감하다. 특히, emitter 물질의 일함수 및 겉모양 같은 기하학적 요소에 민감한 전계방출 소자의 특성상 tip 선단이 oxidation 될 경우 일함수가 증가하여 전자방출에 필요한 구동전압이 증가하고 전자 방출의 불균일성이 커지는 문제점이 발생한다. 이에 고진공의 동작 환경 및 FEAs 제작과정이나 공기의 노출에 발생하는 tip 표면의 오염물질 제거가 요구된다. 따라서 본 연구에서는 40$\times$40mm2 FEAs에 laser power, scan speed을 달리하며 laser(cw Nd-YAG, 1064nm)을 조사하였다. laser cleaning 효과를 보기 위해 laser irradiation 전, 후에 진공도 5$\times$10-7torr irradiation 후에 emitter tip의 뚜렷한 기하학적 모양의 변화를 볼 수는 없었지만, I-V 특성이 향상 되는 것을 볼 수 있었다.

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Electronic Spectroscopy and Ligand Field Analysis of mer-[Cr(progly)(2,2-tri)]$CIO_4$

  • Park, Jong-Ha
    • Journal of Photoscience
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    • v.9 no.3
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    • pp.51-55
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    • 2002
  • The 77 K emission and excitation spectra, and 298 K infrared and absorption spectra of [Cr(progly)(2,2-tri)]CIO$_4$[progly=prolylglycinate,2,2-tri=N-(2-aminoethyl)-1,2-ethanediamine] have been measured. The vibrational intervals of the electronic ground state are extracted from emission and infrared spectra. The twelve electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using the observed electronic transitions, a ligand field analysis was performed to determine the metaligand bonding properties for the coordinated atoms. It is found that the carboxylate oxygen of the progly is a strong $\sigma$-and $\pi$-donor while the peptide nitrogen has weak $\pi$-donor property toward chromium(III) ion.

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Spectroscopic Properties and Ligand Field Analysis of Pentaammine(imidazole)chromium(III) Perchlorate

  • 최종하
    • Bulletin of the Korean Chemical Society
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    • v.20 no.1
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    • pp.81-84
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    • 1999
  • The emission and excitation spectra of [Cr(NH3)5(imH)](ClO4)3·H2O (imH=imidazole) taken at 77 K are reported. The 298 K visible and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. Using the observed transitions, a ligand field analysis has been performed to determine the bonding properties of coordinated imidazole in the title chromium(Ⅲ) complex. It is confirmed that nitrogen atom of the imidazole ligand has a medium it-acceptor property toward chromium(Ⅲ) ion. The zero-phonon line in the excitation spectrum splits into two components by 181 cm-1, and the large 2Eg splitting can be reproduced by the ligand field theory.

A Revised Estimate of N2O Emission Factor for Spring Chinese cabbage fields in Korea (국내 봄배추 재배지의 아산화질소 배출계수 개발에 관한 연구)

  • Kim, Gun-Yeob;Park, Woo-Kyun;Jeong, Hyun-Cheol;Lee, Sun-il;Choi, Eun-Jung;Kim, Pil-Joo;Seo, Young-Ho;Na, Un-sung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.17 no.4
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    • pp.326-332
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    • 2015
  • Greenhouse-gas emission factors are widely used to estimate emissions arising from a defined unit of a specific activity. Such estimates are used both for international reporting to the United Nations Framework Convention on Climate Change (UNFCCC) and for a myriad of national and subnational reporting purposes. The Intergovernmental Panel on Climate Change (IPCC) provides a methodology for national and sub-national estimation of known greenhouse gas emissions including $N_2O$ for each sector from which the emissions arise. The objective of this study was to develop an emission factor to estimate the direct $N_2O$ emission from an agricultural field cultivated with Chinese cabbage during spring season in 2010-2012. An estimated emission factor of $N_2O$ calculated over three years from field experiment accounting for cumulative $N_2O$ emission, nitrogen fertilization rate, and background $N_2O$ emission was $0.0056{\pm}0.00254$ (95% CI) Kg $N_2O-N/kg$ N. More extensive studies are needed to develop $N_2O$ emission factors for other upland crops in various regions of Korea because $N_2O$ emission is influenced by many factors including climate characteristics, soil properties agricultural practices and crop species.

Measurement Uncertainty of Nitrous Oxide Concentrations from a Upland Soil Measured by an Automated Open Closed Chamber Method (밭토양에서 폐쇄형 자동 챔버법으로 측정한 아산화질소 농도에 대한 측정 불확도)

  • Ju, Ok Jung;Kang, Namgoo;Lim, Gap June
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.237-245
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    • 2020
  • BACKGROUND: The closed chamber method is the most commonly used for measuring greenhouse gas emissions from upland fields. This method has the advantages of being simple, easily available and economical. However, uncertainty estimation is essential for accurate assessment of greenhouse gas emissions and verification of emission reductions. The nitrous oxide emissions from upland field is very important for the nitrogen budget in the agriculture sectors. Although assessment of uncertainty components affecting nitrous oxide emission from upland field is necessary to take account of dispersion characteristics, research on these uncertainty components is very rare to date. This study aims at elucidation of influencing factors on measurement uncertainty of nitrous oxide concentrations measured by an automated open closed chamber method from upland field. METHODS AND RESULTS: The nitrous oxide sampling system is located in the upland field in Gyeonggi-do Agricultural Research and Extension Services (37°13'22"N, 127°02'22"E). The primary measurement uncertainty components influencing nitrous oxide concentrations (influencing factors) investigated in this research are repeatability, reproducibility and calibration in the aspects of nitrous oxide sampling and analytical instrumentation. The magnitudes of the relative standard uncertainty of each influencing factor are quantified and compared. CONCLUSION: Results of this study show what influencing factors are more important in determination of nitrous oxide concentrations measured using the automated open closed chambers located in the monitoring site. Quantifying the measurement uncertainty of the nitrous oxide concentrations in this study would contribute to improving measurement quality of nitrous oxide fluxes.

Research on the magnetic confinement of laser-induced plasma (레이저 유도 플라즈마에 대한 자기장 감금의 영향 연구)

  • Eunjoo Hyeon;Yong H. Ghym
    • Journal of IKEEE
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    • v.28 no.1
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    • pp.38-45
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    • 2024
  • Most previous works about magnetic effect on plasma emission were interested in emission enhancement which was useful to various fields of plasma application. On the contrary, the following work is interested in plasma dissipation rarely reported in prior researches and expected to help advance plasma-controlling technique. Nd:YAG laser (1064 nm, 6 ns) was focused on three kinds of metals (Al, Ti and STS) and air. The permanent magnetic field (0.4 T) of Nd2Fe14B magnet was provided passing throughout laser-induced plasma. The spectra of plasma in both the presence and absence of the magnetic field were observed with varying laser power and delay time of the spectrograph. In this work it was uniquely discovered that the plasma always dissipated easily in the presence of magnetic field irrespective of the laser power. With the O I(777.42 nm)-line shape function fitted to Lorentz profile, its half width at half maximum (HWHM) was evaluated to verify that the magnetic field increased the plasma density. It is concluded that magnetic field facilitates not only plasma emission enhancement but also plasma dissipation, increasing recombination rate which is proportional to plasma density.

Fabrication of Field Emitter Arrays by Transferring Filtered Carbon Nanotubes onto Conducting Substrates

  • Jang, Eun-Soo;Goak, Jung-Choon;Lee, Han-Sung;Lee, Seung-Ho;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.311-311
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    • 2009
  • Carbon nanotubes (CNTs) belong to an ideal material for field emitters because of their superior electrical, mechanical, and chemical properties together with unique geometric features. Several applications of CNTs to field emitters have been demonstrated in electron emission devices such as field emission display (FED), backlight unit (BLU), X-ray source, etc. In this study, we fabricated a CNT cathode by using filtration processes. First, an aqueous CNT solution was prepared by ultrasonically dispersing purified single-walled CNTs (SWCNTs) in deionized water with sodium dodecyl sulfate (SDS). The aqueous CNT solution in a milliliter or even several tens of micro-litters was filtered by an alumina membrane through the vacuum filtration, and an ultra-thin CNT film was formed onto the alumina membrane. Thereafter, the alumina membrane was solvated by acetone, and the floating CNT film was easily transferred to indium-tin-oxide (ITO) glass substrate in an area defined as 1 cm with a film mask. The CNT film was subjected to an activation process with an adhesive roller, erecting the CNTs up to serve as electron emitters. In order to measure their luminance characteristics, an ITO-coated glass substrate having phosphor was employed as an anode plate. Our field emitter array (FEA) was fairly transparent unlike conventional FEAs, which enabled light to emit not only through the anode frontside but also through the cathode backside, where luminace on the cathode backside was higher than that on the anode frontside. Futhermore, we added a reflecting metal layer to cathode or anode side to enhance the luminance of light passing through the other side. In one case, the metal layer was formed onto the bottom face of the cathode substrate and reflected the light back so that light passed only through the anode substrate. In the other case, the reflecting layer coated on the anode substrate made all light go only through the cathode substrate. Among the two cases, the latter showed higher luminance than the former. This study will discuss the morphologies and field emission characteristics of CNT emitters according to the experimental parameters in fabricating the lamps emitting light on the both sides or only on the either side.

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