• 접착 및 계면
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• 제13권1호
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• pp.45-50
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• 2012

폴리케톤(polyketone, PK) 섬유는 고무의 강화재로 사용하기 위해서 최근 개발되고 있는 소재이다. 섬유의 고무와의 접착성을 향상시키기 위하여 플라즈마로 표면을 개질하였다. 산소 플라즈마 처리에 의한 섬유표면의 물리적 형태변화를 관찰하기 위하여 주사전자현미경과 원자현미경을 이용하여 관찰하였다. 섬유표면의 화학적 조성변화를 XPS (X-ray photoelectron spectroscopy)를 이용하여 알아보았다. 최종적으로 이러한 변화가 PK 섬유와 고무와의 계면접착력에 어떠한 영향을 미치는지를 microdroplet debonding 시험을 통해 분석하였다. 플라즈마 처리에 의하여 섬유표면에 산소함유기들이 증가하는 결과를 보였으며, 처리시간과 처리전력이 증가함에 따라 에칭에 의한 표면조도(RMS roughness)가 증가하였다. 그러나 장시간의 플라즈마 처리조건에서는 표면에 degradation이 발생하여 오히려 표면조도가 감소하는 결과를 보였다. PK 섬유와 고무와의 계면전단강도는 처리시간 60 s의 80 W, 처리전력 60 W의 180 s에서 처리한 경우에 최대 계면전단강도를 나타내었다. 그러나 그 이상으로 증가하면 degradation이 발생하면서 계면전단강도가 감소하였다.

• Fibers and Polymers
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• 제7권3호
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• pp.235-240
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• 2006

Polyacrylonitrile (PAN) fiber was grafted with casein after alkaline hydrolysis and chlorination reactions of the original fiber. The structures and morphologies of the casein grafted fiber were characterized by Fourier transform infrared spectroscopy (FTIR), X-Ray diffraction (XRD), and scanning electron microscope (SEM). Moisture absorption, specific electric resistance, water retention value, and mechanical properties were also investigated. The results showed that casein was grafted onto the surface of the PAN fiber and the grafted PAN fiber presented better hygroscopicity compared with the untreated fiber. With proper tensile strength, the modified fiber could still meet the requirement for wearing. A mechanism was proposed to explain the deposit of casein on the synthetic acrylic fiber.

• 대한금속재료학회지
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• 제49권7호
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• pp.522-529
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• 2011

Carbon fiber reinforced plastics (CFRP), which have been developed for their high mechanical properties, are insufficient to secure machinery. This paper investigates the use of magnetic abrasive finishing methods and the characteristics of surface roughness for mirror machining of CFRP. The cylindrical surface of CFRP was ground using a diamond paste with sizes of 0.1, 0.5, 1 and 6${\mu}m$. Consequently, an effective surface roughness of 0.03${\mu}m(R_a)$ could be obtained via a paste size of 0.5${\mu}m$. The surface roughness was not improved due to epoxy abrasion between the carbon fiber and the epoxy.

• Smart Structures and Systems
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• 제11권2호
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• pp.185-197
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• 2013

We developed a simultaneous strain measurement and damage detection technique using a pair of surface-mounted piezoelectric transducers and a fiber connecting them. This is a novel sensor configuration of the fiber acoustic wave (FAW) piezoelectric transducer. In this study, lead-zirconate-titanate (PZT) transducers are installed conventionally on a plate's surface, which is a technique used in many structural health monitoring studies. However, our PZTs are also connected with an optical fiber. A FAW and Lamb wave are simultaneously guided in the optical fiber and the structure, respectively. The dependency of the time-of-flight of the FAW on the applied strain is quantified for strain sensing. In our experimental results, the FAW exhibited excellent linear behavior and no hysteresis with respect to the change in strain. On the other hand, the well-known damage detection function of the surface-mounted PZT transducers was still available by monitoring the waveform change in the conventional Lamb wave ultrasonic path.

• 한국농공학회논문집
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• 제57권2호
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• pp.57-66
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• 2015

The purpose of this study was to improved the durability of a improved movable weir by replacing the improved movable weir's metal gate with a hybrid steel/glass fiber reinforced polymer composites panel gate. Because the metal gate of a improved movable weir is always in contact with water, its service life is shortened by corrosion. This study made four type of hybrid steel/glass fiber reinforced polymer composites panel gate with different steel gate surface deformation (control, sand blast, scratch and hole), flexural. Fracture properties tests were performed depending on the steel gate surface deformation. According to the test results, the flexural behavior, flexural strength and fracture properties of hybrid steel/glass fiber reinforced polymer composites panel gate was affected by the steel panel gate surface deformation. Also, the sand blast type hybrid steel/glass fiber reinforced polymer composites panel gate shows vastly superior flexural and fracture performance compared to other types.

• Advances in nano research
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• 제14권6호
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• pp.557-573
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• 2023

The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제48권2호
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• pp.86-91
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• 1999

In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. As irradiation energy are increased, the surface properties were steeply decreased in the range of 300[nm]. But the measured values within the scope of400[nm]∼440[nm] showed a increase as compared with the untreated ones. Also, fromthe result of ESCA spectrum, it was confirmed plenty of oxygen groups on the spot showing the maximum decrease of surface properties and the existence of ether groups on the surface of coloring phase. We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

• Korean Chemical Engineering Research
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• 제61권1호
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• pp.52-57
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• 2023

본 연구는 고성능 유연 전극 소재 개발을 위한 기초 연구로, 유연 전극 소재의 성능을 향상시키기 위해 금속 산화물 CuO nanoparticles (CuO NPs)를 도입하여 탄소나노튜브 섬유(carbon nanotube fiber; CNT fiber) 표면 위에 전기화학적 증착시켜 CNT fiber/CuO NPs 전극을 합성하고, 이를 전기화학적 비효소 글루코스 센서에 적용하였다. 이 전극의 표면 및 elemental composition 분석은 주사전자 현미경(SEM)과 에너지분산형 분광분석법(EDS)을 이용하였으며, 전극의 전기화학적 특성 및 글루코스에 대한 센싱 성능은 순환전압 전류법(CV)과 전기화학 임피던스법(EIS), 시간대전류법(CA)을 통해 조사되었다. CNT fiber/CuO NPs 전극은 CNT fiber의 우수한 특성과 함께 CuO NPs 도입에 따른 약 2.6배의 유효 전극면적(active surface area) 증가 효과와 11배 정도의 향상된 전자전달(electron transfer) 특성 및 우수한 전기적 촉매 활성(electrocatalytic activity) 덕분에 CNT fiber 유연 기반 전극의 글루코스 검출에 대한 성능이 개선되었다. 따라서, 본 연구를 기반으로 다양한 나노구조체를 활용한 고성능 유연 전극 소재 개발이 기대된다.

• 한국염색가공학회지
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• 제34권2호
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• pp.102-108
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• 2022

The physicochemical properties of stainless steel fibers which were modified by oxygen plasma treatment were analyzed through microscopy and XPS analysis. The wettability of the surface of the stainless steel fiber was observed by measuring water contact angle to find out the effect of the plasma treatment time on the surface characteristics of the stainless steel fiber. In addition, in order to understand the effect of oxygen plasma treatment on the deterioration of the stainless steel fiber properties, the physical properties due to plasma treatment was investigated by measuring the weight reduction, tensile strength, elongation, tensile modulus of the stainless steel fibers according to the treatment time. As a result, the stainless steel fiber surface was etched by the oxygen plasma and the surface became more wettable by the introduction of hydrophilic functional groups. However the physical properties of the stainless steel fiber were not significantly deteriorated even if the surface of the stainless steel fiber made hydrophilic.

• 한국염색가공학회지
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• 제18권4호
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• pp.37-42
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• 2006

Two kinds of sea-island type polyester ultramicro fibers (fiber fineness : 0.01 and 0.05 denier) were treated with NaOH varying time and concentration. Surface morphology of the treated fibers with alkaline weight loss was observed by SEM. The treated effects were investigated by measuring density, melting temperature, and X-ray diffraction patterns. The surface morphology of the polyester ultramicro fiber was changed by NaOH concentration. Weight loss of 0.01d fiber was much larger than that of 0.05d fiber. Density and crystallinity were increased with weight loss of fiber. After the weight loss had finished, the density and crystallinity were decreased because of attack of island partition of the fiber. A melting temperature$(T_m)$ is $250^{circ}$ at untreated fiber on the whole and in 0.05d fiber the $(T_m)$ is $252^{circ}$ at untreated. In 0.01d fiber the $(T_m)$ was increased with weight loss of fiber.