A Study on the Surface Degradation Properties of Epoxy / Glass fiber Treated with Ultraviolet Rays

자외선 처리된 Epoxy/Glass Fiber의 표면 열화 특성에 관한 연구

  • 이백수 (인하대 공대 전기공학과) ;
  • 이덕출 (인하대 공대 전기공학과)
  • Published : 1999.02.01

Abstract

In order to analyse the degradation process of epoxy/glass fiber for outdoor condition, FRP laminate was exposed to the wavelength of ultraviolet rays and evaluated by comparing contact angle, surface resistivity, surface potential decay, and ESCA spectrum respectively. As irradiation energy are increased, the surface properties were steeply decreased in the range of 300[nm]. But the measured values within the scope of400[nm]∼440[nm] showed a increase as compared with the untreated ones. Also, fromthe result of ESCA spectrum, it was confirmed plenty of oxygen groups on the spot showing the maximum decrease of surface properties and the existence of ether groups on the surface of coloring phase. We can conclude that the degradation phenomena on the surface of epoxy composites are dominated by the induction of ester and carboxyl groups.

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References

  1. 日本電氣學會論文A v.111 no.2 室外用高分子材料表面の評價法의 の檢討 小松原實;石井勝
  2. 11th FRP Sympo. Status of FRP in Electric Industry M. Morita(et al.)
  3. Reinforced Plastics v.32 Approach of FRP to Electric and Electronic Devices M. Morita(et al.)
  4. 전기전자재료학회논문지 v.10 no.1 FRP 복합절연재료의 유전특성에 미치는 염수처리의 영향 박강식(외 5인)
  5. Infra-red spectra of Conplex Molecules L.J. Bellamy
  6. 전기전자재료 학회논문지 v.11 no.3 열처리된 유리섬유 강화 복합재료의 전기적 및 기계적 성질에 미치는 영향 이백수;이덕출
  7. 熱力學的 · 電氣的ぉょひ光學的性質 高分子學會高分子實驗學編集委員會(編)
  8. POLYMER SURFACES from Physics to Technology Fabio Garbassi;Marco Morra;Ernesto Occhiello
  9. Polymer Interface and Adhesion Souheng Wu
  10. Aging and Stabilization of Polymers M.B. NEIMAN
  11. Polymer Surface Modification and Characterization Chi-Ming Chan