• Polymer(Korea)
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• v.24 no.1
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• pp.113-123
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• 2000

Poly(p-hydroxybenzoate) (PHB)/poly(ethylene terephthalate) (PET) 8/2 thermotropic liquid crystalline copolyester, poly(ethylene 2,6-naphthalate) (PEN) and PET were mechanically blended to obtain the pseudo liquid crystalline (LC) phase of ternary blends. The torque values of blends with increasing PHB content were abruptly decreased above 40 wt% of PHB content, because the melt viscosity of ternary blends decreased. Tensile strength and initial modulus of blends containing above 30 wt% PHB were improved with increasing PHB content. Tensile strength and modulus of fiber were increased with PHB contents and take-up speed. Degree of transesterification and randomness of blends were increased with blending time. The blend of 40 wt% PHB was shown pseudo LC phase in the polarized optical photographs. Crystallinity of PHB/PEN/PET ternary blend were increased with PHB content.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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• 2003.05a
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• pp.294-299
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• 2003

The efficiency of complex slurry preparation route for the development of high performance RS-SiCf/SiC composites has been investigated. The green bodies for RS-SiC and RS-SiCf/SiC composite materials prior to the infiltration of molten silicon were prepared with various C/SiC complex matrix slurries, which associated with both different sizes of starting SiC particles and blending ratios of starting SiC and carbon particles. The reinforcing materials in the composite system were uncoated and C coated Tyranno SA SiC fiber. The characterization of RS-SiC and RS-SiCf/SiC composite materials was examined by means of SEM, EDS and three point bending test. Based on the mechanical property-microstructure correlation, process optimization methodology is discussed.

• Journal of the Korea Concrete Institute
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• v.24 no.2
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• pp.111-120
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• 2012

This paper is a report about lap splice performance of rebar embedded in the strain-hardening cement-based composites (SHCCs) under monotonic and repeated tension loading. Ten mix proportions of cement-based composites such as SHCCs and normal concrete were investigated. The study parameters are comprised of (1) types of reinforcing fibers (polyethylene and steel fiber), (2) replacement levels of expansive admixture (EXA, 0% and 10%), and (3) compressive strength (30 and 100 MPa) of cement-based composites. Lap splice lengths (ld) of rebars in SHCC materials and normal concrete were 60% and 100% of splice length calculated by code requirements for structural concrete, respectively. Test results indicated that SHCCs materials can lead to enhancements in the lap splice performance of embedded rebar. All of the fiber reinforcement conditions (PE-SHCC and PESF-SHCC) considered in this study produced considerable improvements in the tensile strength, cracking behavior, and bond strength of lap-spliced rebar. Furthermore, adding EXA to SHCC matrix improved the tensile lap splice performance of rebar in SHCC materials. However, for controlling crack behavior, the performance of PE-SHCC was better than that of PESF-SHCC due to its mechanical properties. This study demonstrated an effective approach for reducing required development length of lap spliced rebar by using SHCC materials.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.5
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• pp.95-102
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• 2020

For the purpose of developing a PE fiber-reinforced highly ductile cementitious composite having high tensile strain capacity more than 2% under the condition of containing aggregates with large particle size, this study investigated the tensile behavior of composites according to the particle size and distribution of aggregates in the composite. Compared with the mixture containing silica sand of which particle size is less than 0.6 mm, mixtures containing river sand and/or gravel with the maximum particle size of 2.36 mm, 4.75 mm, 5.6 mm, 6.7 mm were considered in the experimental design. The particle size distributions of aggregates were adjusted for the optimized distribution curves obtained from modified A&A model by blending different sizes of aggregates. All the mixtures presented clear strain-hardening behavior in the direct tensile tests. The mixtures with the blended aggregates to meet the optimum curves of aggregate size distributions showed higher tensile strain capacity than the mixture with silica sand. It was also found that the tensile strain capacity was improved as the maximum size of aggregate increased which resulted in wider particle size distribution. The mixtures with the maximum size of 5.6 mm and 6.7 mm presented very high tensile strain capacities of 4.83% and 5.89%, respectively. This study demonstrated that it was possible to use coarse aggregates in manufacturing highly ductile fiber-reinforced cementitous composite by adjusting the particle size distribution.

• Journal of Korean Ophthalmic Optics Society
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• v.18 no.4
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• pp.365-371
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• 2013

Purpose: In this study, we evaluated the physical and thermal properties of the compositions made by blending glass fiber (GF) of different contents into glass fiber polyamide-66, and investigated if the compositions applying to the glasses frame to replace the TR-90, which is polyamide-12 resin used as an injection-type spectacle frame material. Methods: To investigate the characteristics change of polyamide-66 (PA-66) compositions with the change of the content of glass fibers, we produced a composition of the content by using a twin-screw extruder. The mechanical strength of the composition production was measured and coating properties as well as cutting processability were evaluated. We evaluated the applicability of the glasses frame by comparison the results of new compositions with characterizations of traditional TR. Results: For the results of the characterization of Polyamide-66/GF composition, we found that the higher increase of content of the glass fiber, the less mold shrinkage rate, and the mechanical strength was increased. Tensile strength increased from $498kg/cm^2$ for 0 wt% of the content of the glass fibers to $849kg/cm^2$ for 30 wt% of the content of the glass fibers. As a result of a coating evaluation, the strength of coating was 4B in the GF 5wt% and 5B, which was extremely good coating characteristics, in the over than GF 5 wt%. Conclusions: In case that 30 wt% of the glass fiber was blended, the mechanical strength was greatly improved, the hardness was increased, injection temperature increased due to increase of the viscosity, and the flow mark of the product may occur. The paint coating of PA-66 blended with glass fiber was all excellent. With general evaluating physical properties and workability properties it was determined that around 10 wt% of the content of the glass fibers was possible to apply a spectacle frame.

• Membrane Journal
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• v.22 no.6
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• pp.404-414
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• 2012

In order to investigate $SO_2$ removal, PEI hollow fiber membranes were produced by a dry-wet phase inversion method. The membrane support layer on surface was coated with PEBAX1657$^{(R)}$ and PEG blending materials. Modules were prepared for the single gas permeation characteristics of composite membrane according to temperature and pressure. As a result, $SO_2$ permeance and $SO_2/N_2$ selectivity were 220~1220 GPU and 100~506 through operating condition, respectively. Moreover, $SO_2/CO_2/N_2$ mixture gas was used to compare the performance of separation properties according to temperature, pressure and retentate flow rate difference. $SO_2$ removal efficiency was increased with pressure and temperature.

• Textile Coloration and Finishing
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• v.20 no.2
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• pp.1-8
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• 2008

Regenerated composite fibers are prepared from solution(styela clava tunics /poly vinyl alchol) using N-methylmorpholine-N-oxide(NMMO)/water(87/13)(wt/wt) as a solvent by dry-wet spinning. The chemical cellulose (94%, ${\alpha}$-cellulose content) used for this study is extracted from styela clava tunics (SCT, Midduck), which are treated in chemical process and mechanical grinding. The structure and physical properties of regenerated composite fibers were investigated through IR-spetra, DSC, TGA and SEM. The optimal blend ratio of SCT/PVA for spinning solution was 70/30 and the total weight was 4% concentrations in NMMO/water solvent system. The fiber density, moisture contents and the degree of swelling were $1.5(g/cm^3)$ 10.2(%) and 365(%), respectively. The crystallinity index of composite fibers are decreased as the PVA contents increased. Thermal decomposition of composite fibers took place in two stages at around $250^{\circ}C$ and $550^{\circ}C$. The best thermal stability was obtained with 30% PVA contents.

• Textile Coloration and Finishing
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• v.20 no.3
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• pp.31-38
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• 2008

Regenerated composite fibers were prepared from solution of styela clava tunics(SC) and poly vinyl alchol(PVA) using N-methylmorpholine-N-oxide(NMMO)/water(87/13)(wt%/wt%) as a solvent by dry jet-wet spinning. Structure and physical properties of regenerated composite fibers were investigated through birefrngence, x-ray diffratograms, tenacity, fibrillation and SEM. Optimal blend ratio of SC/PVA for mechanical properties of composite fibers was 70/30 and total weight was 4wt% concentrations in NMMO/$H_2O$ solvent system. Crystallinity index of composite fibers were decreased as the PVA contents increased. Fibrillation of $10{\sim}20wt%$ PVA blended fibers were occurred less than pure SC fiber. Shape of composite fibers were a circle cross section within 10wt% PVA content. But the cross section of fibers were changed as crushed flat with the PVA contents increased.

• Journal of the Korean Society of Clothing and Textiles
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• v.25 no.2
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• pp.237-248
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• 2001

The purpose of this study was to compare the comfort sensation depending on four different kinds of denim blue jeans: cotton, cotton/tencel, tencel, cotton/pp. The objective and subjective experiments were conducted to measure the comfort of blue jeans. To investigate the objective comfort, physical properties related to thermal insulation, moisture properties and hand were measured. For subjective comfort measurement, 5 healthy female college students were taken as subjects. The outcomes of the experiments are as follows: The higher the air permeability and bulk density of the denim, the lower the thermal insulation, the thicker the denim, the higher the thermal insulation. Tencel blending denim showed the higher bulk density, the lower air contents, and consequently the lower thermal insulation than the other denims. Tencel showed the highest moisture regain, and cotton/tencel blend showed the highest water vapor permeability. Tencel denim had relatively better flexibility, shape stability and elastic recovery than the other denims. The total hand values of the denims by KES-FB system were not significantly different. Cotton and cotton/pp denims raised the subjects body temperature after excercise more than tencel or cotton/tencel denims. Average skin temperature was found to have a correlation with micro climate temperature and micro climate humidity. The correlation coefficients were 0.749 and 0.767, respectively. However, average skin temperatures were not significantly different among the materials. Pulse rate was found to be the highest when wearing cotton/pp and the lowest in case of cotton/tencel denim. The energy was consumed in order of cotton>cotton/pp>tencel>cotton/tencel. There was no significant difference in preference before excercise, but, after the excercise, the order of preference changed as the following; cotton/tencel>tencel>cotton/pp>cotton.

• Applied Chemistry for Engineering
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• v.4 no.1
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• pp.54-63
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• 1993

Some emulsified 1, 2-disubstituted imidazolinium salts were synthesized by quaternization of 1, 2-disubstituted imidazoline which had been prepared by the reaction of dodecanoic acid with tetraethylenepentamine. 2-Docosamido-2'-docosanoyloxydiethylamine was prepared by the reaction of docosanoic acid with hydroxylethylethylenediamine. Then, some emulsified fatty carbamide salts were also synthesized by quaternization of fatty carbamide which had been prepared by the reaction of urea with the 2-docosamido-2'-docosanoyloxydiethylamine. Some softners were prepared by blending of these salts mentioned above. These softners were treated on acrylic fiber, then several properties were measured. As the results, softening and lubricating properties are good and a little antistatic property was observed. The synthesized softners were also proved as a durable softner by means of the several experiments : bending resistance test and measurements of feeling change with washing according to the pH changes. The surface structure of acrylic fibers treated with the softner were characterized by SEM.