• Title/Summary/Keyword: Ferroelectric properties Dielectric properties

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Ferroelectric Characteristics of Pb-containing Perovskite-Pyrochlore Composites (Pb계 Perovskite-Pyrochlore 복합체의 강유전특성)

  • 조진우;손정호;조상희
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.500-504
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    • 1997
  • Perovskite Pb0.7Ba0.3Zn1/3Nb2/3O3 substituted with 0.3 mole fraction for Pb-site in PbZn1/3Nb2/3O3 relaxor and pyrochlore Pb1.83Ba0.29Zn1.71Nb2/3O6.39 were mixed and dielectric characteristics of this composites were investigated. Percolation limit of perovskite phase, which was determined by microstructural observation in the composite as an isolation of perovskite phase from pyrochlore matrix, was 28.9-47.5 vol%. Ferroelectric phase transition below percolation limit depends on a parameter which affects the propagation of lattice vibration between isolated perovskite phase and pyrochlore matrix. Therefore, it is believed that ferroelectric lattice vibration of isolated perovskite phase could be transfered to pyrochlore matrix when the oxygen octahedra are linked in 3-dimension and highly polarizable Pb2+ ions are contained in both phases.

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Piezoelectric and Dielectric Properties of PVC/PZT Composite (PVC/PZT 복합체의 압전 및 유전특성)

  • Kang, Dae-Ha;Lee, Jae-Hoon;Rho, Il-Soo;Park, Sang-Ho
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1392-1393
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    • 2006
  • In this paper dielectric and piezoelectric properties were measured for 2 phase - dispersed composite system consisting of ferroelectric ceramic PZT particles and polymer PVC. The results were analyzed and the validity of composite theories for experimental results were discussed. And also in high temperature where ionic conductivity is dominated, linear and nonlinear permittivites were measured and discussed.

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Dielectric Characteristics of PbSc1/2Nb1/2O3 Prepared by Using the One-step Solid State Reaction

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
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    • v.25 no.4
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    • pp.77-80
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    • 2016
  • The $PbSc_{1/2}Nb_{1/2}O_3$ ceramics at a relatively low temperature of $1300^{\circ}C$ was successful synthesized. Solid state reaction of two-step process is not necessary. The dielectric constant, dielectric loss and admittance of ceramic samples were determined. The pyroelectric characteristics are in good agreement with the dielectric properties. Ferroelectric properties of well-formed the $PbSc_{1/2}Nb_{1/2}O_3$ ceramics are in agreement with broad distribution of relaxation phenomenon. Relatively strong frequency dependent of dielectric constant is observed at about $110^{\circ}C$. The distinct thermal hysteresis was observed in the measurement of the dielectric constant and dielectric loss. The critical exponents of during cooling and heating measurements in the $PbSc_{1/2}Nb_{1/2}O_3$ ceramics were 1.14 and 1.59 at 1 kHz, respectively.

Structureal and dielectric properties of $(Pb_{x},Sr_{x-1})TiO_{3}$ thin film for tunable device application (Tunable 소자 응용을 위한 $(Pb_{x},Sr_{x-1})TiO_{3}$ 박막의 구조 및 유전특성)

  • Kim, Kyoung-Tae;Kim, Chang-Il;Lee, Sung-Gap
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.78-81
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    • 2002
  • Ferroelectric thin film is a very attractive material for the tunable microwave device applications such as electronically tunable mixers, delay lines, filters and phase shifters. Thin films of $Pb_{x}Sr_{1-x}TiO3(PST)$ were fabricated onto Pt/Ti/SiO2/Si substrate by the sol-gel method. We have investigated the structural and dielectric properties of PST(50/50) thin films for tunable microwave device applications. The PST thin films show typical polycrystalline structure with a dense microstructure without secondary phase formation. Dielectric properties of PST films are strongly dependent on annealing temperature. The dielectric constants, loss and tunability of the PST (50/50) thin films were 404, 0.023 and 51.73 %, respectively.

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Effect of Magnetic Field on the Dielectric Properties $BaTiO_3-MgFe_2O_4$ Composite

  • Tadi, Ravindar;Kim, Yong-Il;Kim, Cheol-Gi;Ryu, Kwon-Sang
    • Proceedings of the Korean Magnestics Society Conference
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    • 2011.06a
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    • pp.93-95
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    • 2011
  • In this study we tried to measure the effect of magnetic field on the dielectric properties of $BaTiO_3-MgFe_2O_4$ soft magnetic composite. Composites with different weight percents of ferroelectric and ferromagnetic phases were subjected to magnetic field in the order of 0 to 450 Oe and the variation of the dielectric properties was observed. The Variation of dielectric polarization was discussed in terms of Maxwell-Wagner type polarization in particulate composites.

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Fabrication of Thin Film Transistor Using Ferroelectrics

  • Hur, Chang-Wu;Kim, Jung-Tae
    • Journal of information and communication convergence engineering
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    • v.2 no.2
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    • pp.93-96
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    • 2004
  • The a-Si:H TFT using ferroelectric of $SrTiO_3$ as a gate insulator is fabricated on glass. Dielectric characteristics of ferroelectric are superior to $SiO_2$ and $Si_{3}N_{4}$. Ferroelectric increases on-current, decreases threshold voltage of TFT and also improves breakdown characteristics. The a-SiN:H has optical band gap of 2.61 eV, retractive index of 1.8∼2.0 and resistivity of $10^{13}$~$10^{15}$ $\Omega$cm, respectively. Insulating characteristics of ferroelectrics are excellent because dielectric constant of ferroelectric is about 60∼100 and breakdown strength is over 1MV/cm. TFT using ferroelectric has channel length of 8∼20 $\mu\textrm{m}$ and channel width of 80∼200 $\mu\textrm{m}$. And it shows that drain current is 3.4$\mu\textrm{A}$ at 20 gate voltage, $I_{on}$/$I_{off}$ is a ratio of $10^5$~$10^8$ and $V_{th}$ is 4∼5 volts, respectively. In the case of TFT without ferroelectric, it indicates that the drain current is 1.5 $\mu\textrm{A}$ at 20 gate voltage and $V_{th}$ is 5∼6 volts. With the improvement of the ferroelectric thin film properties, the performance of TFT using this ferroelectric has advanced as a gate insulator fabrication technology is realized.

The Electrical Properties of SBT Thin Film for Semiconductor Device (반도체 소자용 SBT 박막의 전기적특성)

  • Oh, Yong-Cheul;Cho, Choon-Nam;Kim, Jin-Sa;Shin, Chul-Ki;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.86-89
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    • 2003
  • SBT thin film for semiconductor device that is made by RF magnetron sputtering method studied electrical properties under various temperature condition. Dielectric constant who differ annealing condition appears highest in $750[^{\circ}C]$ and it is 213. Also, C-V properties by annealing temperature of SBT thin film for semiconductor device is no change almost to $600[^{\circ}C]$ and shows non-linear butterfly shape more than $650[^{\circ}C]$ Maximum capacitance and difference of smallest capacitance show the biggest difference in $750[^{\circ}C]$ as degree that domain wall motion contributes in ferrelectric polarization value in C-V characteristic curve of ferroelectric that this shows typical ferroelectric properties. Therefore, SBT thin film for semiconductor device that is annealing in $750[^{\circ}C]$ expressed the most superior electrical and ferroelectric properties.

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Densification and Electrical Properties of Screen-printed PZT Thick Films (스크린 프린팅법으로 제작한 PZT 후막의 치밀화와 전기적 특성)

  • Park, Sang-Man;Lee, Sung-Gap
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.7
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    • pp.667-672
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    • 2006
  • Ferroelectric $Pb(Zr_{0.52}Ti_{0.48})O_3$ (PZT(52/48)) thick films were fabricated by the screen-Printing method on the alumina substrates, and $PbTiO_3$ (PT) Precursor solution, which prepared by sol-gel method, was spin-coated on the PZT(52/48) thick films to obtain a densification. Its structural and electrical properties of the PZT(52/48) thick films with the treatment of PT precursor solution coating were investigated. The particle size of the thick films was increased with increasing the number of coatings and the thickness of the PZT-6 (6: number of coatings) films was about $60{\mu}m$. The relative dielectric constant increased and the dielectric loss decreased with increasing the number of PT sol coatings. The relative dielectric constant and dielectric loss of the PZT-6 thick film were 475 and 2 %, respectively. The remanent polarization, coercive field and breakdown strength of the PZT-6 film were $32.6{\mu}C/cm^2$, 15 kV/cm and 60 kV/cm, respectively.

Preparation and Dielectric Properties of the $PbTiO_3$ Thin Film by Sol-Gel Method (Sol-Gel법에 의한 $PbTiO_3$ 박막의 제조 및 유전 특성)

  • Chung, Jang-Ho;Park, In-Gil;Ryu, Ki-Won;Lee, Young-Hie
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1434-1436
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    • 1996
  • In this study, ferroelectric $PbTiO_3$ thin films were deposited on the Pt/$SiO_2$/Si substrate by Sol-Gel method. $PbTiO_3$ stock solution was made and spin-cooled at 4000[rpm] for 30[sec.]. Coated specimens were dried at $400[^{\circ}C]$ for 10[min.] and then annealed at $500{\sim}800[^{\circ}C]$ for 1 hour. Annealing temperature were examined to optimize micro structural and dielectric properties of the films. The ferroelectric perovskite phase was observed in the file annealed at $700[^{\circ}C]$ for 1 hour. In the case of $PbTiO_3$ thin films annealed at $700[^{\circ}C]$ for hour, dielectric constant and dielectric loss showed the good value of 324, 2.0[%], respectively.

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