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Preparation of Silicon Tetrachloride by Chlorination of Silicon (실리콘의 염소화반응에 의한 사염화규소 제조)

  • Park, Kyun Young;Lee, Mi Sun;Kim, Min Cheol;Lee, Chan Hee;Park, Hoey Kyung;Kang, Tae Won;Jeong, Hae Seong;Han, Kyoung Ah;Huh, Weon Hoe;You, Ji Cheol
    • Korean Chemical Engineering Research
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    • v.51 no.3
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    • pp.407-410
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    • 2013
  • The chlorination of a metallurgical-grade silicon was carried out in a fluidized bed reactor, 25 mm in diameter. The flow rate of the chlorine admitted into the reactor was 0.2 L/min and that of the carrier nitrogen was 0.8~1.0 L/min. The reactor temperature was maintained at $450^{\circ}C$ and the temperature of the coolant at the $SiCl_4$ condenser was at $-5^{\circ}C$. The $SiCl_4$ yield increased with increasing the mole fraction of chlorine in the feed gas, exhibiting 28% at the mole fraction of 0.2. Further increase of the chlorine mole fraction was not attempted in a worry that the reactor might be failed due to the high exothermicity of the reaction. The production of $SiCl_4$ from silicon by fluidized bed chlorination was demonstrated on a laboratory scale, which is a stepping stone for future studies under more severe conditions toward industrial application.

Improvement of Endoscopic Image using De-Interlacing Technique (De-Interlace 기법을 이용한 내시경 영상의 화질 개선)

  • 신동익;조민수;허수진
    • Journal of Biomedical Engineering Research
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    • v.19 no.5
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    • pp.469-476
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    • 1998
  • In the case of acquisition and displaying medical Images such as ultrasonography and endoscopy on VGA monitor of PC system, image degradation of tear-drop appears through scan conversion. In this study, we compare several methods which can solve this degradation and implement the hardware system that resolves this problem in real-time with PC. It is possible to represent high quality image display and real-time processing and acquisition with specific de-interlacing device and PCI bridge on our hardware system. Image quality is improved remarkably on our hardware system. It is implemented as PC-based system, so acquiring, saving images and describing text comment on those images and PACS networking can be easily implemented.metabolism. All images were spatially normalized to MNI standard PET template and smoothed with 16mm FWHM Gaussian kernel using SPM96. Mean count in cerebral region was normalized. The VOls for 34 cerebral regions were previously defined on the standard template and 17 different counts of mirrored regions to hemispheric midline were extracted from spatially normalized images. A three-layer feed-forward error back-propagation neural network classifier with 7 input nodes and 3 output nodes was used. The network was trained to interpret metabolic patterns and produce identical diagnoses with those of expert viewers. The performance of the neural network was optimized by testing with 5~40 nodes in hidden layer. Randomly selected 40 images from each group were used to train the network and the remainders were used to test the learned network. The optimized neural network gave a maximum agreement rate of 80.3% with expert viewers. It used 20 hidden nodes and was trained for 1508 epochs. Also, neural network gave agreement rates of 75~80% with 10 or 30 nodes in hidden layer. We conclude that artificial neural network performed as well as human experts and could be potentially useful as clinical decision support tool for the localization of epileptogenic zones.

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Breakage and Liberation Characteristics of Iron Ore from Shinyemi Mine by Ball Mill (신예미 광산 철광석의 볼밀 분쇄 및 단체분리 특성 연구)

  • Lee, Donwoo;Kwon, Jihoe;Kim, Kwanho;Cho, Heechan
    • Resources Recycling
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    • v.29 no.3
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    • pp.11-23
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    • 2020
  • This study aims to investigate breakage and liberation characteristics of iron ore from Shinyemi mine, Jeongseon by ball mill. Parameters of breakage functions for three grade samples of iron ore were obtained using single-sized-feed breakage test and back-calculation based on nonlinear programming. The results showed that with the increase in the grade of iron ore, the breakage rate factor decrease whereas the particle size sensitivity decreases. This results from retardation of microcrack-propagation by magnetite grain in the ore. Breakage distribution analysis showed that the breakage mechanism appear to be impact fracture dominant with the increase of grade owing to the stress distribution effect by magnetite grain. Degree of liberation (DOL) increased with the increase in grade and decrease in particle size, respectively. Using the breakage function and size-DOL relationship, a model that can predict time-dependent-DOL is established. When scale-up factors from operating condition are available, the model is expected to be capable of predicting size and DOL with time in actual mining process.

A Simulation Study on the Cascade Refrigeration Cycle for the Liquefaction of the Natural Gas [2]: An Application to the Multistage Cascade Refrigeration Cycle (천연가스 액화를 위한 캐스케이드 냉동사이클의 전산모사에 대한 연구 [2]: 다단 캐스케이드 냉동 사이클에 적용)

  • Cho, Jung-Ho;Kim, Yu-Mi
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.2
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    • pp.1013-1019
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    • 2011
  • In this paper, simulation works for a multi-stage cascade refrigeration cycle using propane, ethylene and methane as refrigerants have been performed for the liquefaction of natural gas using Peng-Robinson equation of state built-in PRO/II with PROVISION release 8.3. The natural gas feed compositions were supplied from Korea Gas Corporation and the flow rate was assumed to be 5.0 million tons per annual. Supply temperature for propane refrigerant was fixed as $-40^{\circ}C$, that for ethylene refrigerant as $-95^{\circ}C$, and that for methane refrigerant as $-155^{\circ}C$. For the multi-stage refrigeration cycle, three-stage refrigeration was assumed for propane refrigeration cycle, two-stage refrigeration for ethylene refrigeration cycle and three-stage refrigeration for methane refrigeration cycle. Natural gas was finally cooled and liquefied to $-162^{\circ}C$ by Joule-Thomson expansion. Conclusively, 91.71% by mole of the natural gas liquefaction ratio was obtained through a cascade refrigeration cycle and Joule-Thomson expansion and 0.433 kW of compression power was consumed for the liquefaction of 1.0 kg/hr of natural gas.

Influence of pH and Ionic Strength on Treatment of Radioactive Boric Acid Wastes by Forward Osmosis Membrane (정삼투막에 의한 붕산함유 방사성 폐액 처리를 위한 pH 및 이온강도 영향)

  • Choi, Hye-Min;Hwang, Doo-Seong;Lee, Kune-Woo;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.3
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    • pp.193-198
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    • 2013
  • In general, boron recovery of 40-90% could be achieved by Reverse Osmosis (RO) membranes in neutral pH condition. As an emerging technology, Forward Osmosis (FO) membrane has attracted growing interest in wastewater treatment and desalination. The objective of this study is to evaluate the possibility of the boron removal in radioactive liquid waste by FO. In this study, the performance of FO was investigated to remove boron in the simulated liquid waste as the factors such as pH, osmotic pressure, ionic strength of solution, etc. The pH of feed solution is a major operating parameter which strongly influences to the permeation of boron and more than 80% of boron content can be separated when conducted at pH values less than 7. The water flux is not influenced but the boron flux and permeation rate tends to decrease in the low salt concentration of 1,000 mg/L. The boron flux increases linearly, but the permeation ratio of reducing boron is nearly constant even with changes in the draw solution concentration.

Profitability Analysis Based on Cropping System of the Land Use Changes in Paddy Field (논 타작물 재배 작부체계별 수익성 분석)

  • Yu, Chan-Ju;Um, Ji-Bum;Ko, Hyeon-Seok;Park, Sang-Youn
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.1
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    • pp.216-222
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    • 2020
  • A comparative analysis of farm incomes was performed from the new composition system of crops, such as feed crops, including soybeans, Italian ryegrass, soybean-potatoes, and soybean-barley planted in rice fields. Through this analysis, the suggested implications were derived, and the technological solutions were determined. The profitability of the composition of soybean-Italian ryegrass showed that the soybeans yield was 325kg/10a, and the sale price was ₩3,962/kg, leading to a gross revenue of ₩1,288,000/10a. The yield of Italian ryegrass was 1,584kg/10a with a sale price of ₩125/kg, showing a gross revenue of ₩198,000/10a. The net income of soybeans was ₩284,000/10a, which means a net income rate of 22.1%, whereas the net income of Italian ryegrass was -₩30,000/10a. The composition of soybeans-potatoes and soybeans-barley showed a gross revenue of ₩930,000/10a and ₩375,000/10a, respectively. The crop composition types have been developed for the Income Type, Production Type of Forage, Improvement Type of Food Self-Sufficiency, and Corresponding Type to Climate Change. On the other hand, regional types have not been developed sufficiently. In addition, various selections of alternative crops and the establishment of crop composition congruent to the specific regions should be developed systematically in terms of the production technology. Therefore, it is necessary to develop the technological establishment of the crop composition through continuous related studies with the mid-to-long term objectives of land utilization and grain self-sufficiency rates.

HVOF Thermal Spray Coating of WC-Co for Durability Improvement of High Speed Spindle (초고속 스핀들의 내구성 향상을 위한 WC-Co 분말의 HVOF 용사 코팅)

  • Kim, K.S.;Baek, N.K.;Yoon, J.H.;Cho, T.Y.;Youn, S.J.;Oh, S.K.;Hwang, S.Y.;Chun, H.G.
    • Journal of Surface Science and Engineering
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    • v.39 no.4
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    • pp.179-189
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    • 2006
  • High velocity oxygen fuel(HVOF) thermal spray coating of WC-Co powder is one of the most promising candidate for the replacement of the traditional hard chrome plating and ceramics coating because of the environmental problem of the very toxic $Cr^{6+}$ known as carcinogen and the brittleness of ceramics coating. WC-Co micron and nano powder were coated by HVOF thermal spraying method for the study of durability improvement of the high speed spindle. Coatings were planned by Taguchi program for the four spray parameters of spray distance, flow rates of hydrogen, oxygen and powder feed rate. Optimal coating process was obtained by the studies of coating properties such as porosity, surface roughness, micro hardness, and micro structure. WC-Co micron and nano powder were coated on the Inconel 718 substrate by the optimal coating process obtained in this study. The wear behaviors were studied by the sliding wear tester at room temperature and at an elevated temperature of $500^{\circ}C$ for the application to high speed spindle. Sliding wear test was carried out for four most promising hard coatings of chrome coating, ceramics coatings such as $A1_2O_3,\;Cr_2O_3$ and HVOF Co-alloy T800 for the comparison of their wear behaviors. HVOF WC-Co coating was better than other coatings showing highest micro hardness of 1400 Hv and comparable friction coefficients with others. HVOF WC-Co coating is a strong candidate for the replacement of the traditional hard chrome plating for the high speed spindle.

A Study on GHS Classification of 3-Methylpentane by Subacute Inhalation Toxicity (아급성흡입독성시험을 이용한 3-Methylpentane의 GHS 분류·표시)

  • Chung, Yong Hyun;Han, Jeong Hee;Shin, Seo Ho
    • Journal of the Korean Institute of Gas
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    • v.21 no.1
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    • pp.6-17
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    • 2017
  • Objectives : The purpose of this study was to obtain information regarding Globally Harmonized System(GHS) classification and health hazards that may result from a 4 weeks inhalation exposure of 3-Methylpentane in Sprague-Dawley rats. Methods : The testing method was conducted in accordance with OECD guidelines for the testing of chemicals No. 412(Subacute Inhalation Toxicity). The Rats were divided into 4 groups(5 male and 5 female rats in each group) and exposed to 0 ppm, 284 ppm, 1,135 ppm, 4,540 ppm 3-Methylpentane in each exposure chamber for 6 h/day, 5 days/week, for 4 weeks. After two weeks, the test animals were autopsied and carried out blood test and biochemical tests and histopathological examination. We used PRISTIMA (Toxicology data management system) to confirm the system and to have confidence of the raw data. Results : No death and particular clinical presentation including weight change and change of feed rate was observed. Relationship between dose, gender and response was also not significantly changed in hematologic examination, biochemical examination of blood and blood coagulation time. The histopathologic lesions caused by the test substance did not appear. Conclusions : NOAEL(No Observable Adverse Effect Level) of 3-Methylpentane is more than 4,540 ppm in male group and female group and the Ministry of Employment and Labor Guidance Announcement No. 2013-37(criteria for the classification marks and Safety of Chemicals) Specific target organ toxicity(repeated exposure) was determined with a substance that is not the separator material.

Effect of Screw Configurations and Process Parameters on Characteristics of Wheat Bran Extrudates (스크류 조합과 공정변수 조절에 따른 밀기울 압출물의 특성)

  • Kim, Chong-Tai;Hwang, Jae-Kwan;Cho, Sung-Ja;Kim, Chul-Jin;Kim, Hae-Sung
    • Korean Journal of Food Science and Technology
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    • v.28 no.1
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    • pp.169-178
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    • 1996
  • Target parameters such as water solubility index (WSI), intrinsic viscosity (IV), water holding capacity (WHC), oil holding capacity (OHC), soluble dietary fiber (SDF) and microstructure were investigated on three different screw configurations during twin-screw extrusion of wheat bran. WSI of raw wheat bran (RWB) was 13.7%, while that of extrudates ranged $16.3{\sim}23.2%$ when extruded using screw configurations with 5 reverse screw elements (RSE). It was found that the moisture content of RWB greatly affected WSI of extrudates. IV of wheat bran extrudates increased from 10.6 ml/g of RWB to $37.86{\sim}44.37\;ml/g$ of extrudates extruded using 3, 4 and 5 RSE, whose trend was highly related to the moisture content of RWB and the extrusion pressure. Multiplication of IV and soluble solid (SS) content exhibited good correlation $(R^2=0.85)$ with specific mechanical energy (SME). The results suggested that SS and molecular size are an important factor governed by the SME in solubilization of wheat bran. WHC increased with increasing feed rate and moisture content, while OHC decreased. SDF increased from 2.68% of RWB to $4.32{\sim}6.48%$ of extruded wheat bran, indicating the significant breakdown of cell wall components. Microstructure of the extrudates showed the distinct patterns of degradation and solubilization of cell wall structure, depending on the moisture content of RWB.

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Effects Diets Containing Some Red Ginseng Extracts in Rats (홍삼 함유 식품의 백쥐 사육 효과)

  • Kim, Hyong-Soo;Choi, Hyun-Ju;Lee, Hee-Ja
    • Korean Journal of Food Science and Technology
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    • v.12 no.2
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    • pp.103-108
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    • 1980
  • To study the effects of diets containing red Ginseng, rats were fed diets containing various amounts of red Ginseng for 10 weeks. The Ginseng diets were 600 mg of red Ginseng extract concentration, 1,200 mg of red Ginseng powder, 6,000 mg of red Ginseng tea, 3,000 mg of red Ginseng extract concentration, 6,000 mg of red Ginseng extract concentration, 12,000 mg of red Ginseng extract concentration per Kg of diet, and control. As results, growth rate, feed efficiency ratio, organ weight, and hematocrit value showed no statistically significant differences between red Ginseng fed animals and the controls. Serum cholesterol level and GPT were slightly lower in the experimental animals than those in the controls. These differences, however, were not statistically significant. Serum GOT activities for all experimental animals showed no statistically significant except for Group fed with 6,000 mg of red Ginseng extract concentration per Kg diet. This Group revealed significantly lower GOT activities than those of the controls statistically. No abnormalities of liver, spleen, and kidney were observed in the experimental animals.

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