• 한국분말재료학회지
• /
• 제13권3호
• /
• pp.178-186
• /
• 2006

The effect of use of $H_2O$ as PCA(process control agent) to prevent the carbon contamination during mechanical alloying process and the precipitation behavior in Ni-20Cr-20Fe-5Nb bulk alloy after aging were investigated. NbC and $Cr_2O_3$ were formed during mechanical alloying and consolidation processes in the Ni-20Cr-20Fe-5Nb alloy in which methanol($CH_3OH$) was added as PCA. Formation of NbC in this alloy decreased the amount of Nb dissolved in the Ni matrix. The use of $H_2O$ as PCA in Ni-20Cr-20Fe-5Nb alloy prevented the formation of NbC and increased the hardness. The increase of hardness in this alloy was attributed to the increased amount of Nb dissolved in the Ni matrix. After aging treatment for 20 hours at $600^{\circ}C\;and\;720^{\circ}C$ of Ni-20Cr-20Fe-5Nb bulk alloy in which $H_2O$ added as PCA, ${\gamma}"$$(Ni_3Nb,\;tetragonal)\;and\;{\delta}\;(Ni_3Nb,\;orthorhombic)$ precipitates were formed, respectively. The precipitation temperatures of ${\gamma}"$ and ${\delta}$ in this bulk alloy were lower than those in commercial IN 718 alloy. It seemed that the lower precipitation temperatures for ${\gamma}"$ and ${\delta}$ in this bulk alloy than in commercial IN 718 alloy were due to severe plastic deformation during mechanical alloying.

• 한국재료학회지
• /
• 제25권8호
• /
• pp.391-397
• /
• 2015

NiO catalysts/$Al_2O_3$/FeCrAl alloy foam for hydrogen production was prepared using atomic layer deposition (ALD) and subsequent dip-coating methods. FeCrAl alloy foam and $Al_2O_3$ inter-layer were used as catalyst supports. To improve the dispersion and stability of NiO catalysts, an $Al_2O_3$ inter-layer was introduced and their thickness was systematically controlled to 0, 20, 50 and 80 nm using an ALD technique. The structural, chemical bonding and morphological properties (including dispersion) of the NiO catalysts/$Al_2O_3$/FeCrAl alloy foam were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, field-emission scanning electron microscopy and scanning electron microscopy-energy dispersive spectroscopy. In particular, to evaluate the stability of the NiO catalysts grown on $Al_2O_3$/FeCrAl alloy foam, chronoamperometry tests were performed and then the ingredient amounts of electrolytes were analyzed via inductively coupled plasma spectrometer. We found that the introduction of $Al_2O_3$ inter-layer improved the dispersion and stability of the NiO catalysts on the supports. Thus, when an $Al_2O_3$ inter-layer with a 80 nm thickness was grown between the FeCrAl alloy foam and the NiO catalysts, it indicated improved dispersion and stability of the NiO catalysts compared to the other samples. The performance improvement can be explained by optimum thickness of $Al_2O_3$ inter-layer resulting from the role of a passivation layer.

• 한국표면공학회지
• /
• 제50권5호
• /
• pp.386-391
• /
• 2017

Two kinds of steels whose compositions were Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) were centrifugally cast, and oxidized at $900^{\circ}C$ for 50-350 h in order to find the effect of sulfur on the high-temperature oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) alloys. These alloys formed oxide scales that consisted primarily of $Cr_2O_3$ as the major oxide and $Cr_2MnO_4$ as the minor one through preferential oxidation of Cr and Mn. They additionally formed $SiO_2$ particles around the scale/alloy interface as well as inside the matrices. The high affinity of Mn with S led to the formation of scattered MnS inclusions particularly in the 0.35S-containing cast alloy. Sulfur was harmful to the oxidation resistance, because it deteriorated the scale/alloy adherence so as to accerelate the adherence and compactness of the formed scales.

• 한국분말재료학회지
• /
• 제28권4호
• /
• pp.336-341
• /
• 2021

In this study, a nanocrystalline FeNiCrMoMnSiC alloy was fabricated, and its austenite stability, microstructure, and mechanical properties were investigated. A sintered FeNiCrMoMnSiC alloy sample with nanosized crystal was obtained by high-energy ball milling and spark plasma sintering. The sintering behavior was investigated by measuring the displacement according to the temperature of the sintered body. Through microstructural analysis, it was confirmed that a compact sintered body with few pores was produced, and cementite was formed. The stability of the austenite phase in the sintered samples was evaluated by X-ray diffraction analysis and electron backscatter diffraction. Results revealed a measured value of 51.6% and that the alloy had seven times more austenite stability than AISI 4340 wrought steel. The hardness of the sintered alloy was 60.4 HRC, which was up to 2.4 times higher than that of wrought steel.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2007년도 춘계학술대회A
• /
• pp.262-267
• /
• 2007

In this paper, we study about wear properties for the metal matrix composites fabricated by low pressure infiltration process. Metal fiber preform reinforced aluminum alloy composite were fabricated by low pressure casting process under 0.4MPa. Infiltration condition was changed the pressure infiltration time of 1 s, 2 s and 5 s under a constant pressure of 0.4MPa. The molten alloy completely infiltrated the FeCrSi metal perform regardless of the increase in the pressure acceleration time. However, the infiltration time at the pressure acceleration time of 1s was shorter than at the pressure acceleration time of 2s or 5s. The FeCrSi/A366.0 composite was investigated the porosity. The porosity is reducing as the pressure acceleration time compared with the pressure acceleration time of 2s and 5s. The FeCrSi/A366.0 composites were investigated the wear resistance. FeCrSi/A366.0 composite at pressure acceleration time of 1s has excellent wear resistance.

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2000년도 춘계학술발표회 초록집
• /
• pp.22-22
• /
• 2000

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 1996년도 춘계연구발표회 논문개요집
• /
• pp.34-35
• /
• 1996

• 한국표면공학회지
• /
• 제21권4호
• /
• pp.176-182
• /
• 1988

Effects of Cr, Ni and W on the anodic polarization behavior were investigated for Fe-Cr-Ni-W alloys in deaerated 1N HCI solution. Surface films formed on the polarization were analysed using AES, SEM and EDAX. A higerconcentration of tungten was found in the surface oxide film compared to the matrix. It played an importanet role on incresing the stability of the passive film. The presence of an adequate amount of Cr was essential to increase the pitting resistance of the alloys in acid chloride media. Under 12 wt%cr,alloys containing 6wt%W did not exhidit any passivity at all. The main role of Ni was to control the microstructure rather than to modify the corrosion resistance. In 23 cr-14Ni-^W alloy, the duplex microstructure of ferrite($\delta$-phase) in an austenic matrix was developed. The reson why proferred pitting appeared in austenite and ferrite/austenite interface was that ferrite had more amount of Cr and W than austenite.

• Corrosion Science and Technology
• /
• 제13권1호
• /
• pp.1-5
• /
• 2014

A low carbon steel, Fe-2.25%Cr steel (ASTM T22), and Fe-2.25%Cr-1.6%W steel (ASTM T23) were aluminized by hot dipping into molten Al baths. After hot-dipping, a thin Al-rich topcoat and a thick alloy layer formed on the surface. The topcoat consisted primarily of a thin Al layer that contained a small amount of Fe, whereas the alloy layer consisted of Al-Fe intermetallics such as $Al_5Fe_2$ and AlFe. Cr, Mo, and W in T22 and T23 steels reduced the thickness of the topcoat and the alloy layer, and flattened the reaction front of the aluminized layer, when compared to the low carbon steel.

• Korean Chemical Engineering Research
• /
• 제51권1호
• /
• pp.35-41
• /
• 2013

Co-P-B/FeCrAlloy 촉매의 $NaBH_4$ 가수분해 특성과 내구성에 대해 연구하였다. 5 wt% $NaBH_4$ 농도에서 활성화 에너지가 25.2 kJ/mol로 귀금속 촉매와 비슷했고, $NaBH_4$ 농도가 증가할수록 활성화 에너지가 증가하였다. 20 wt% 이상의 $NaBH_4$ 농도에서 겔 형성이 수소발생과 촉매 내구성에 많은 영향을 줬다. $NaBH_4$ 농도가 높을 때 반응온도가 높을수록 겔 형성이 안 되므로 촉매 손실률이 낮았다. 수소발생과 촉매 내구성을 모두 고려했을 때 담지체를 $1,000^{\circ}C$에서 열처리하고, 초음파 진동없이 촉매를 담지하고, 촉매 담지 후 소성한 촉매가 우수하였다. 25 wt% $NaBH_4$에서는 촉매를 3회 이상 재사용하기 위해서는 $60^{\circ}C$ 이상의 온도에서 반응시켜야 함을 보였다.