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http://dx.doi.org/10.9713/kcer.2013.51.1.35

NaBH4 Hydrolysis Reaction Using Co-P-B Catalyst Supported on FeCrAlloy  

Hwang, Byungchan (Department of Chemical Engineering, Sunchon National University)
Jo, Ara (Department of Chemical Engineering, Sunchon National University)
Sin, Sukjae (Fuel Cell Research Center, Korea Institute of Science and Technology)
Choi, Daeki (Fuel Cell Research Center, Korea Institute of Science and Technology)
Nam, Sukwoo (Fuel Cell Research Center, Korea Institute of Science and Technology)
Park, Kwonpil (Department of Chemical Engineering, Sunchon National University)
Publication Information
Korean Chemical Engineering Research / v.51, no.1, 2013 , pp. 35-41 More about this Journal
Abstract
Properties of $NaBH_4$ hydrolysis reaction using Co-P-B/FeCrAlloy catalyst and the catalyst durability were studied. Co-P-B/FeCrAlloy catalyst showed low activation energy such as 25.2 kJ/mol in 5 wt% $NaBH_4$ solution, which was similar that of noble metal catalyst. The activation energy increased as the $NaBH_4$ concentration increased. Formation of gel at high concentration of $NaBH_4$ seriously affected hydrogen evolution rate and the catalyst durability. The catalyst loss decreased as reaction temperature increased due to lower gel formation when the concentration of $NaBH_4$ was over 20 wt%. Considering hydrogen generation rate and durability of catalyst, the catalyst supported with FeCrAlloy heat-treated at $1,000^{\circ}C$ without ultra vibration during dipping and calcination after catalyst dipping was best catalyst. To use catalyst more than three times in 25 wt% $NaBH_4$ solution, it should be reacted at higher temperature than $60^{\circ}C$.
Keywords
Sodium Borohydride; Durability; Catalyst; Co-P-B; Hydrolysis; FeCrAlloy; Fuel Cell;
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Times Cited By KSCI : 2  (Citation Analysis)
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