• Title/Summary/Keyword: Fe-As-S system

Search Result 411, Processing Time 0.029 seconds

Themochemical Cycles for Hydrogen Production from Water (열화학적 수소 제조 기술)

  • Kim J.W.;Park C.S.;Hwang G.J.;Bae K.K.
    • Journal of Energy Engineering
    • /
    • v.15 no.2 s.46
    • /
    • pp.107-117
    • /
    • 2006
  • The status of water splitting thermochemical cycle for hydrogen production was reviewed in this article. Mass production of hydrogen could be possible using the thermochemical process which is similar to the concept of conventional chemical reaction system if the high temperature heat source is available. The mediators (chemicals and reagents) should be used to split chemically stable water, and should be recycled in a closed cycle in order to be environmentally acceptable. Though there is no process to reach commercial stage, IS cycle, two-step cycles based on metallic oxide such as ZnO/Zn, $Fe_3O_4/FeO$ and the associated cycles are attracted due to their possibilities of application. Development of materials for high temperature and/or corrosive conditions during thermochemical process is still important topic in some thermochemical processes.

Experimental Verification of the Decomposition of Y2O3 in Fe-Based ODS Alloys During Mechanical Alloying Process

  • Byun, Jong Min;Park, Chun Woong;Kim, Young Do
    • Metals and materials international
    • /
    • v.24 no.6
    • /
    • pp.1309-1314
    • /
    • 2018
  • In this study, we investigated the state of $Y_2O_3$, as a major additive element in Fe-based ODS alloys, during mechanical alloying (MA) processes by thermodynamic approaches and experimental verification. For this purpose, we introduced $Ti_2O_3$ that formed different reaction products depending on the state of $Y_2O_3$ into the Fe-based ODS alloys. In addition, the reaction products of $Ti_2O_3$, Y, and $Y_2O_3$ powders were predicted approximately based on their formation enthalpy. The experimental results relating to the formation of Y-based complex oxides revealed that $YTiO_3$ and $Y_2Ti_2O_7$ were formed when $Ti_2O_3$ reacted with Y; in contrast, only $Y_2Ti_2O_7$ was detected during the reaction between $Ti_2O_3$ and $Y_2O_3$. In the alloy of $Fe-Cr-Y_2O_3$ with $Ti_2O_3$, $YTiO_3$ (formed by the reaction of $Ti_2O_3$ with Y) was detected after the MA and heat treatment processes were complete, even though $Y_2O_3$ was present in the system. Using these results, it was proved that $Y_2O_3$ decomposed into monoatomic Y and O during the MA process.

Manufacturing of Fe-Mn-Al-C Based Low Mn Lightweight Steel Via Direct Energy Deposition (Direct energy deposition 공정을 이용한 Fe-Mn-Al-C계 저망간 경량철강 제조)

  • Ko, Kwang Kyu;Son, Han Sol;Jung, Cha Hee;Bae, Hyo Ju;Park, Eun Hye;Kim, Jung Gi;Choi, Hyunjoo;Seol, Jae Bok
    • Journal of Powder Materials
    • /
    • v.29 no.4
    • /
    • pp.320-324
    • /
    • 2022
  • Lightweight steel is a crucial material that is being actively studied because of increased carbon emissions, tightening regulations regarding fuel efficiency, and the emergence of UAM, all of which have been recently labeled as global issues. Hence, new strategies concerning the thickness and size reduction of steel are required. In this study, we manufacture lightweight steel of the Fe-Mn-Al-C system, which has been recently studied using the DED process. By using 2.8 wt.% low-Mn lightweight steel, we attempt to solve the challenge of joining steel parts with a large amount of Mn. Among the various process variables, the laser scan power is set at 600 and 800 W, and the laser scan speed is fixed at 16.67 mm/s before the experiments. Several pores and cracks are observed under both conditions, and negligibly small pores of approximately 0.5 ㎛ are observed.

Lubrication Performance Analysis of a Spiral Groove Dry Gas Seal for a High-Speed Flying Object (고속비행체용 스파이럴 그루브 드라이 가스 시일의 윤활 성능해석)

  • Lee An Sung;Kim Jun Ho
    • Tribology and Lubricants
    • /
    • v.21 no.1
    • /
    • pp.8-15
    • /
    • 2005
  • In this study a general Galerkin FE lubrication analysis method is utilized to analyze the complex lubrication performance of a spiral groove seal, which is being designed and developed for a high-speed flying object application operating at a high-speed of over 50,000 rpm. As at the equilibrium seal clearance the axial stiffness of the seal is predicted to have almost such a constant high value of $1.04\times10^8\;N/m$ regardless of a rotating speed, the seal is expected to maintain a stable thickness of lubrication film under a certain external excitation acting. Also, as even at an ultra high-speed of 80,000 rpm the axial damping of the seal is shown to have a rotatively high value of 5,775 N-s/m, the dynamic stability of the seal system at the axial degree of freedom is assured well enough.

Validation of a smart structural concept for wing-flap camber morphing

  • Pecora, Rosario;Amoroso, Francesco;Amendola, Gianluca;Concilio, Antonio
    • Smart Structures and Systems
    • /
    • v.14 no.4
    • /
    • pp.659-678
    • /
    • 2014
  • The study is aimed at investigating the feasibility of a high TRL solution for a wing flap segment characterized by morphable camber airfoil and properly tailored to be implemented on a real-scale regional transportation aircraft. On the base of specific aerodynamic requirements in terms of target airfoil shapes and related external loads, the structural layout of the device was preliminarily defined. Advanced FE analyses were then carried out in order to properly size the load-carrying structure and the embedded actuation system. A full scale limited span prototype was finally manufactured and tested to: ${\bullet}$ demonstrate the morphing capability of the conceived structural layout; ${\bullet}$ demonstrate the capability of the morphing structure to withstand static loads representative of the limit aerodynamic pressures expected in service; ${\bullet}$ characterize the dynamic behavior of the morphing structure through the identification of the most significant normal modes. Obtained results showed high correlation levels with respect to numerical expectations thus proving the compliance of the device with the design requirements as well as the goodness of modeling approaches implemented during the design phase.

Discrimination of Ginseng Habitat by Using Instrumental Analysis Techniques

  • Sohn H. J.;Lee S. K.;Cho B. G.;Kim S. J.;Lee N. Y.;Choi D. S.;Jeong M. S.;Bae H. R.;Yang J. W.
    • Proceedings of the Ginseng society Conference
    • /
    • 2002.10a
    • /
    • pp.238-252
    • /
    • 2002
  • In order to screen out indicators for the discrimination of ginseng habitat, some physical and chemical characteristics of Korean red ginsengs (94 kinds) and Chinese red ginsengs (50 kinds) were analyzed by using a rheometer, an electronic nose system, a combined technique of solid phase micro-extraction (SPME) and gas chromatograph equipped with an electron capture detector (GC/ECD), an X-ray fluorescence spectrometer (XRF), an inductively coupled plasma mass spectrometer (ICP/MS), a near infrared spectrometer (NIRs) and high performance liquid chromatography equipped with evaporative light scattering detector (HPLC/ELSD). The results are summarized as follows: (i) The rhizome strengths of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. (ii) The electronic nose patterns of Korean red ginsengs were significantly different from those of Chinese red ginsengs. (iii) Some unidentified peaks were detected not in the headspace of Korean red ginsengs but in the headspace of Chinese red ginsengs when the headspace volatiles prepared by the SPME technique were analyzed by GC/ECD. (iv) Either the content ratios of K to Ca or Mn to Fe were significantly different between Korean red ginsengs and Chinese red ginsengs. (v) The reflectance ratios of NIRs wavenumbers such as $904\;cm^{-1}\;to\;1088\;cm^{-1}$ for Korean red ginsengs were significantly different from those for Chinese red ginsengs. (vi) The content ratios of ginsenoside-Rg to ginsenoside-Re of Korean red ginsengs were significantly higher than those of Chinese red ginsengs. These results indicate that the rhizome strength, the electronic nose pattern, the occurrence of ECD-sensitive headspace volatile components, the content ratios of K to Ca and Mn to Fe, the NIRs pattern and the content ratio of ginsenoside-Rg to -Re may be indicators for the discrimination of ginseng habitat.

  • PDF

Bending analysis of smart functionally graded plate using the state-space approach

  • Niloufar Salmanpour;Jafar Rouzegar;Farhad Abad;Saeid Lotfian
    • Steel and Composite Structures
    • /
    • v.52 no.5
    • /
    • pp.525-541
    • /
    • 2024
  • This study uses the state-space approach to study the bending behavior of Levy-type functionally graded (FG) plates sandwiched between two piezoelectric layers. The coupled governing equations are obtained using Hamilton's principle and Maxwell's equation based on the efficient four-variable refined plate theory. The partial differential equations (PDEs) are converted using Levy's solution technique to ordinary differential equations (ODEs). In the context of the state-space method, the higher-order ODEs are simplified to a system of first-order equations and then solved. The results are compared with those reported in available references and those obtained from Abaqus FE simulations, and good agreements between results confirm the accuracy and efficiency of the approach. Also, the effect of different parameters such as power-law index, aspect ratio, type of boundary conditions, thickness-to-side ratio, and piezoelectric thickness are studied.

Study on the control technique for the heat transportation system using metal hydride (수소저장합금을 이용한 열수송시스템 제어기술 연구)

  • Sim, K.S.;Kim, J.W.;Kim, J.D.;Myung, K.S.
    • Journal of Hydrogen and New Energy
    • /
    • v.11 no.1
    • /
    • pp.43-49
    • /
    • 2000
  • The heat transportation from a complex of industry to a rural area needs more efficient method because the distance between them is usually more than 10km. Conventional heat transportation using steam or hot water via pipe line has limits in transportation distance (about 3~5 km) because of the heat loss and frictional loss in the pipe line. Metal hydride can absorb or discharge hydrogen through exothermic or endothermic reaction. After releasing hydrogen from metal hydride by means of the waste heat from industry, we can transport this hydrogen to urban area via pipe line. In urban areas, other metal alloy reacts with this hydrogen to form metal hydride and produces heat for heating. Cool heat is also obtained if it is possible to use metal hydride with low reaction temperature. Therefore, metal hydride can be used as a media for transportation and storage of heat. $MmNi_{4.5}Al_{0.5}Zr_{0.003}$, $LaNi_5$, $Zr_{0.9}Ti_{0.1}Cr_{0.6}Fe_{1.4}$, $MmNi_{4.7}Al_{0.1}Fe_{0.1}V_{0.1}$ alloys were selected for this purpose and the properties of those metal hydrides were discussed. The design and control techniques were proposed and discussed for this heat transportation system using metal hydride.

  • PDF

Monitoring the water absorption in GFRE pipes via an electrical capacitance sensors

  • Altabey, Wael A.;Noori, Mohammad
    • Advances in aircraft and spacecraft science
    • /
    • v.5 no.4
    • /
    • pp.499-513
    • /
    • 2018
  • One of the major problems in glass fiber reinforced epoxy (GFRE) composite pipes is the durability under water absorption. This condition is generally recognized to cause degradations in strength and mechanical properties. Therefore, there is a need for an intelligent system for detecting the absorption rate and computing the mass of water absorption (M%) as a function of absorption time (t). The present work represents a new non-destructive evaluation (NDE) technique for detecting the water absorption rate by evaluating the dielectric properties of glass fiber and epoxy resin composite pipes subjected to internal hydrostatic pressure at room temperature. The variation in the dielectric signatures is employed to design an electrical capacitance sensor (ECS) with high sensitivity to detect such defects. ECS consists of twelve electrodes mounted on the outer surface of the pipe. Radius-electrode ratio is defined as the ratio of inner and outer radius of pipe. A finite element (FE) simulation model is developed to measure the capacitance values and node potential distribution of ECS electrodes on the basis of water absorption rate in the pipe material as a function of absorption time. The arrangements for positioning12-electrode sensor parameters such as capacitance, capacitance change and change rate of capacitance are analyzed by ANSYS and MATLAB to plot the mass of water absorption curve against absorption time (t). An analytical model based on a Fickian diffusion model is conducted to predict the saturation level of water absorption ($M_S$) from the obtained mass of water absorption curve. The FE results are in excellent agreement with the analytical results and experimental results available in the literature, thus, validating the accuracy and reliability of the proposed expert system.

Advanced P-Channel Poly-Si TFTs for SOG

  • Park, Seong-Jin;Kang, Sang-Hoon;Ku, Yu-Mi;Choi, Jong-Hyun;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2004.08a
    • /
    • pp.1019-1022
    • /
    • 2004
  • High performance p-ch poly-Si TFTs with excellent stability were developed. By using a frequency doubled DPSS CW laser, the a-Si on glass could be crystallized into one dimensional single crystalline silicon named as a sequential lateral crystallization (SLC) region. We fabricated p-ch TFTs on SLC region and the typical characteristic values of the TFTs were $u_{fe}$ = 180 $cm^2$/Vs, $V_{th}$ = -3 V, S.S. = 0.5 V/dec, and $I_{off}$ = 1 pA/um@ $V_d$ = -10V. It is found that the TFTs are very stable after bias stresses such as negative and positive gate biases, hot carrier bias and high current bias. These results indicate that the poly-Si in SLC region is suitable for system on glass (SOG) application.

  • PDF