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Themochemical Cycles for Hydrogen Production from Water  

Kim J.W. (Hydrogen Energy R&D Center, Hydrogen Energy Research Group)
Park C.S. (KIER)
Hwang G.J. (KIER)
Bae K.K. (KIER)
Publication Information
Journal of Energy Engineering / v.15, no.2, 2006 , pp. 107-117 More about this Journal
Abstract
The status of water splitting thermochemical cycle for hydrogen production was reviewed in this article. Mass production of hydrogen could be possible using the thermochemical process which is similar to the concept of conventional chemical reaction system if the high temperature heat source is available. The mediators (chemicals and reagents) should be used to split chemically stable water, and should be recycled in a closed cycle in order to be environmentally acceptable. Though there is no process to reach commercial stage, IS cycle, two-step cycles based on metallic oxide such as ZnO/Zn, $Fe_3O_4/FeO$ and the associated cycles are attracted due to their possibilities of application. Development of materials for high temperature and/or corrosive conditions during thermochemical process is still important topic in some thermochemical processes.
Keywords
Thermochemical cycle; Redox; Solar concentrator; HTGR (high temperature gas cooled reactor); Metal oxide;
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