• 대한금속재료학회지
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• 제50권7호
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• pp.477-485
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• 2012

The effect of aging heat treatment on microstructure evolution of the Ti-6Al-4Fe-0.25Si alloy with an initial microstructure of an elongated alpha was investigated. Aging treatments of the samples were carried out at $550^{\circ}C$ for up to 100 hours. The microstructure of the 5 hours heat-treated sample consisted of alpha grains, beta matrix and some TiFe intermetallic compounds that were precipitated from the beta matrix. Increasing the aging time to 10 hours, most of the beta matrix was decomposed to very fine alpha grains (${\sim}0.5{\mu}m$) and TiFe, and thus the volume fraction of the beta matrix was significantly decreased. EBSD analysis revealed that newly formed tertiary-alpha-grains in the vicinity of TiFe had high angle boundaries with respect to the primary and secondary alpha grains. As a result of these phase transformations during aging, the fraction of the alpha/alpha grain boundary was increased while that of the alpha/beta phase boundary was decreased.

• 한국주조공학회지
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• 제36권6호
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• pp.202-207
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• 2016

The effects of Fe and Si additions on the microstructures and mechanical properties of aluminum bronze have been investigated. In a bar-type specimen cast in a die mold, the addition of Fe promoted the dendritic solidification of the ${\alpha}$ phase. The hardness values increased slightly in the Fe-added specimen with heat treatment, while these values was increased significantly in the specimens with Si or with combined additions of Fe and Si. When a centrifugal casting bush with combined addition of Fe and Si was heat treated, the FeSi compound within the matrix was finely dispersed, and was observed to be the origin of cup-cone type conical dimple failure in the tensile fracture surface. The mechanical properties of the heat treated centrifugal casting bushes, whose nominal alloy compositions were (Cu-7.0Al-0.8Fe-3.0Si)wt%, exhibited tensile strength of $703-781N/mm^2$, elongation of 6.6-11.7% and hardness of Hv 222.6-249.2. These high values of strength and elongation were attributed to the strengthening of the matrix due to the combined addition of Fe and Si, and to precipitation of fine the FeSi compound.

• 한국재료학회지
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• 제18권3호
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• pp.143-147
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• 2008

Fe compounds in scoria as distributed in the south-western area of Jeju Island were investigated using X-ray fluorescence spectroscopy, X-ray diffractometry, and $^{57}Fe$ $M{\ddot{o}}ssbauer$ spectroscopy. The samples were prepared from four parasite volcanoes. It was found that these samples are typical basalt comprised of $SiO_2$, $Al_2O_3$, Fe, and silicate minerals. The $M{\ddot{o}}ssbauer$ spectra showed doublets for olivine, pyroxene, and ilmenite as well as sextets for hematite and magnetite. The valence state of Fe is chiefly a 3+ charge state with a slight 2+ charge state. It is expected that these results will add to the body of information related to the formation mechanisms of Jeju Island.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.325-325
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• 2006

Cationic polymerization of isobutyl vinyl ether using various metal halides was examined in toluene in the presence of an added base at $0^{\circ}C$. In conjunction with an appropriate weak base such as ethyl acetate or 1,4-dioxane, all metal halides but $FeBr_{3}\;and\;GaCl_{3}$ led to living cationic polymerization. The polymerization rates varied as follows: $FeBr_{3},\;GaCl_{3}\;>\;FeCl_{3}\;>\;SnCl_{4}\;>\;InCl_{3}\;>\;ZnCl_{2}\;>>\;AlCl_{3},\;HfCl_{4},\;ZrCl_{4}\;>\;EtAlCl_{2},\;BiCl_{3},\;TiCl4\;>>\;SiCl_{4}\;>\;GeCl_{4}$. This order partially corresponds to that of the equilibrium constant in the formation of a carbocation from a chloroalkane in the presence of a carbonyl compound. With extremely active Lewis acids, such as $FeBr_{3}\;and\;GaCl_{3}$, the use of a stronger base, THF, was required to achieve living polymerization.

• 열처리공학회지
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• 제16권1호
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• pp.2-9
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• 2003

The aluminum alloy which is light and has excellent thermal conductivity and iron base alloy that is remarkable heat-resistece and wear resistence properties were bonded together. The bond was created between a stationary and a rotating member by using the frictional heat generated between them while subjected to high normal forces on the interface of Al alloy and iron base alloy. The microstructure of the bonded interface of friction welding and the strength in the bonded interface formed under various bonding conditions were examined through TEM, SEM with EDX and triple bending test. In interface of bonding materials formed after various heat treatment, bonding strength was substantially different, resulting from formation of intermetallic compound or softening during annealing.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2001년도 전력전자학술대회 논문집
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• pp.368-371
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• 2001

In this paper, the experiment and simulation results of the Boost converter for PFC(power factor correction) using metal powder inductor are presented. The metal powder inductor used in the experiment was composed of Ni-Fe-Mo, Ni-Fe, Fe-Si-Al compound respectively The performance of the 500w class PFC rectifier with the average current mode control and the 300W class PFC rectifier with the variable frequency control, are evaluated.

• 소성∙가공
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• 제30권1호
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• pp.5-15
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• 2021

The effects of heat treatments (T6 and T73) on the microstructure, mechanical properties, and high cycle fatigue behavior of modified AA7075 alloys were investigated. A modified 7075 alloy was manufactured using modified-Mg (Mg-Al2Ca) instead of the conventional element Mg. Based on the microstructure, the average grain size was 4.5 ㎛ (T6) and 5.2 ㎛ (T73). Regardless of heat treatment, the modified AA7075 alloys consisted of Al matrix containing homogeneously distributed Al2CuMg and MgZn2 phases with reduced Fe-intermetallic compound. Room temperature tensile tests showed that the properties of modified 7075-T6 (Y.S.: 622MPa, T.S: 675MPa, elongation: 15.4%) were superior to those of T73 alloy (Y.S.: 492MPa, T.S: 548MPa, elongation: 12.8%). Experimental data show that the fatigue life of T6 was 400 MPa, about 64% of its yield strength. However, the fatigue life of T73 alloy was 330 MPa and 67%. Irrespective of the stress level, all crack initiation points were located on the specimen surface, and no inclusions acting as stress concentrators were seen. Superior mechanical properties and high cycle fatigue behavior of modified AA7075-T6 alloy are attributed to the fine grains and homogeneous distribution of small second phases such as MgZn2 and Al2CuMg, in addition to reduced Fe-intermetallic compounds.

• 한국분말재료학회지
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• 제22권3호
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• pp.175-180
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• 2015

In this study, ternary compound Max Phase $Ti_2AlC$ material was mixed by 3D ball milling as a function of ball milling time. More than 99.5 wt% pure $Ti_2AlC$ was synthesized by using spark plasma sintering method at 1000, 1100, 1200, and $1300^{\circ}C$ for 60 min. The material characteristics of synthesized samples were examined with relative density, hardness, and electrical conductivity as a function of sintering temperature. The phase composition of bulk was identified by X-ray diffraction. On the basis of FE-SEM result, a terraced structures which consists of several laminated layers were observed. And $Ti_2AlC$ bulk material obtained a vickers hardness of 5.1 GPa at the sintering temperature of $1100^{\circ}C$.

• 한국표면공학회지
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• 제34권3호
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• pp.206-214
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• 2001

The purpose of this study is to determine the effects of Ni on precipitate formation in a Ni added galvanizing bath, which has various Ni content from 0.03wt.% to 0.5wt.%. The addition of hi in the Ni containing galvanizing bath resulted in the formation of Al-Ni intermetallic compounds such as $Al_3$$Ni_2$ and $Al_2$Ni, which make up most of the top precipitates. At 0.07wt.%Ni, Al-Ni intermetallic compound formed sensitively with small amount of Al addition. By analysing the reaction thickness of galvanized steel, it was found that Ni addition in a Zn-0.18w1.%Al bath tended to suppress the formation of Fe-Zn intermetallic compounds but the formation of these compounds increased with increasing Ni concentration above 0.1wt.%.

• Journal of Welding and Joining
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• 제23권5호
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• pp.61-68
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• 2005

Dissimilar joining of Al 6013-T4 alloys and austenite stainless steel was carried out using friction stir welding technique. Microstructures near the weld zone and mechanical properties of the joint have been investigated. Microstructures in the stainless steel side were composed of the heat affected zone and the plastically deformed zone, while those in the Al alloy side were composed of the recrystallized zone including stainless steel particles, the thermo-mechanically affected zone and the heat affected zone. TEM micrographs revealed that the interface region was composed of the mixed layers of elongated stainless steel and ultra-fine grained Al alloy with lamella structure and intermetallic compound layer. Thickness of the intermetallic layer was approximately 300nm and was identified as the A14Fe with hexagonal close packed structure. Mechanical properties, such as tensile and fatigue strengths were lower than those of 6013 Al alloy base metal, because tool inserting location was deviated to Al alloy from the butt line, which resulted in the lack of the stirring.