• Title/Summary/Keyword: Fe-6.5Si

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Co-deposition of Si Particles During Electrodeposition of Fe in Sulfate Solution (황산철 도금액 중 Si 입자의 공석 특성)

  • Moon Sung-Mo;Lee Sang-Yeal;Lee Kyu-Hwan;Chang Do-Yon
    • Journal of the Korean institute of surface engineering
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    • v.37 no.6
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    • pp.319-325
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    • 2004
  • Fe thin films containing Si particles were prepared on metallic substrates by electrodeposition method in sulfate solutions and the content of codeposited Si particles in the films was investigated as a function of applied current density, the content of Si particels in the solution, solution pH, solution temperature and concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film was not dependent on the applied current density, solution pH and solution temperature, while it was dependent on the content of Si particles in the solution and the concentration of $FeSO_4$$7H_2$O in the solution. The amount of Si codeposited in the film increased with increasing content of Si particles in the solution but reached a maximum value of about 6 wt% when the content of Si particles in the solution exceeds 100 g/l. On the other hand, the content of Si codeposited in the film increased up to about 17 wt% with decreasing concentration of $FeSO_4$$7H_2$O in the solution. These results would be applied to the fabrication of very thin Fe-6.5 wt% Si sheets for electrical applications.

Microstructure and Wear Behaviour of Rapidly Solidified Al-20Si-5Fe-zPb(x=2, 4, 6wt.%) Alloys (급속응고 Al-20Si-5Fe-xPb(x=2, 4, 6 wt.%) 합금의 미세조직과 마모거동)

  • 김택수
    • Journal of Powder Materials
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    • v.6 no.1
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    • pp.96-102
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    • 1999
  • The effect of Pb addition on microstructure and wear resistance was studied in rapidly solidified Al-20Si-5Fe-xPb(x=2, 4, 6 wt.%) alloys. The R/S Al-20Si-5Fe-xPb (x=2, 4, 6 wt.%) alloys showed a fine and homogeneous microstructure and an improved wear property compared with Al-20Si-5Fe alloy, while no significant change in UTS (Ultimate Tensile Strength) was shown. Contribution of the dispersoids on the wear property was discussed by showing the plastic deformation layers formed during wear track.

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Structural and Magnetic Properties of Fe-Diluted Si Alloy Films by Pulsed-Laser Deposition (펄스레이저 증착법에 의한 Fe 희석된 Si 합금의 구조 및 자기 물성 연구)

  • Suh, Joo-Young;Lee, Kyung-Su;Pak, Sang-Woo;Kim, Eun-Kyu
    • Journal of the Korean Vacuum Society
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    • v.21 no.5
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    • pp.258-263
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    • 2012
  • Fe-diluted Si alloys grown on p-type Si (100) substrates by pulsed-laser deposition method were studied for structural, electrical, and magnetic properties. The X-ray diffraction patterns for these alloy samples showed a few of peaks with cubic structures such as FeSi, $Fe_3Si$, and $Fe_4Si$. The Fe-composition in alloys are confirmed as Fe atomic percent about 1.25~6.49 % from energy dispersive spectroscopy measurement. The resistivity as a function of the reciprocal temperature was indicated an exponential increase with two activation energies of 5.21 and 7.79 meV. The maximum value of the magnetization at 10 K was about 100 emu/cc, and the ferromagnetism was also observed until 350 K from total magnetization as a function of temperature with applied magnetic field of 3,000 Oe.

The Effects of Si and Mo on the Structures and Mechanical Properties in High Si Spheroidal Graphite Cast Iron (고 Si 구상흑연주철의 조직과 기계적성질에 미치는 Si과 Mo의 영향)

  • Kim, Jong-Yeon;Ra, Hyung-Yong
    • Journal of Korea Foundry Society
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    • v.10 no.3
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    • pp.225-234
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    • 1990
  • Spheroidal graphite cast irons which are Fe-3%C-(4-6)%Si-(0-0.5)%Mo were studied to improve not only heat resistance but also mechanical properties. With increasing Mo content, the graphitization was decreased and carbide volume fraction was increased. The graphite spheroidization ratio was not decreased in Fe-3%C-6%Si-Mo system cast iron with increasing Mo content, but that was decreased in Fe-3%C-4%Si-Mo system and Fe-3%C-5%Si-Mo system cast irons. Hardness was increased with the Si and Mo contents. At constant Si content, tensile strength was increased with increasing Mo content, but that was decreased at 6%Si. In the experiment of oxidation, weight gain was decreased as the Si and/or Mo content increased, but increased at 1.5%Mo content.

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High-Strain-Rate Deformation of Fe-6.5wt.%Si Alloys using a Split Hopkinson Pressure Bar Technique (홉킨슨 압력봉법을 이용한 Fe-6.5wt.%Si 합금의 고변형률속도 거동)

  • Yoon, Young-Ki;Yoon, Hi-Seak;Umakoshi, Yukichi;Yasuda, Hiroyuki Y.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.25 no.7
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    • pp.1073-1081
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    • 2001
  • Many researches have published numerous papers about the high-strain-rate obtained from Split Hopkinson Pressure Bar(SHPB) tests. And 6.5wt%Si steel is widely known as an excellent magnetic material because its magnetostriction is nearly zero. Single crystals are prepared by the Floating Zone(FZ) method, which melts the alloy by the use of a high temperature electron beam in a pure argon gas condition. In this paper, the fracture behavior of the poly crystals and single crystals (DO$_3$phase) of Fe-6.5wt%Si alloy by SHPB test is observed. The comparison of high-strain-rate results with static results was done. Obtained main results are as follows: (1) Fe-6.5wt%Si alloy has higher strength at high-strain-rate tensile. SHPB results of polycrystal are twice as high as static results. (2) From the fractography, the cleavage steps are remarkably reduced in the SHPB test compared with the static test.

Effect of Annealing on the Mechanical properties of Fe-6.5wt% Si Alloy (Fe-6.5wt% Si 합금의 역학 특성에 미치는 어닐링 효과)

  • Yun, Yeong-Gi;Yun, Hui-Seok;Hong, Seong-Gil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.12
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    • pp.2909-2916
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    • 2000
  • 6.5wt% Si steel is widely known as an excellent magnetic material because its magnetostriction is nearly zero. The AX magnetic properties as magnetostriction of 6.5% Si steel were evaluated and compared with those of conventional 3% Si steel sheet. In this paper, the fracture behavior of the poly crystals and single crystals of Fe-6.5wt%Si alloy has been observed. Single crystals were prepared by Floating Zone(FZ) method, which melts the alloy by the use of high temperature electron beam in pure argon gas condition. And the single crystals were annealed at 500$^{\circ}C$ and 700$^{\circ}C$ respectively and tensile tested at room temperature. According to the result, B2 phase has more good elongation than DO$_3$ phase. It was also found that the fracture surfaces of the single crystals have hairline facets in same direction, and the facets change the direction according to the single crystal phase.

Dynamic Compaction of Mechanochemically Alloyed Fe-Si Nano Powders by Magnetic Pulsed Pressure (기계화학적 합금화된 나노 Fe-6.5Si 분말의 자기 펄스압에 의한 동적성형)

  • Lee, G.-H.;Rhee, C.-K.;Kim, W.-W.;Yun, J.-W.;Lee, K.-S.
    • Journal of Powder Materials
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    • v.12 no.1
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    • pp.24-29
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    • 2005
  • Nano Fe-6.5wt%Si powders have been synthesized by mechano-chemical process (MCP) for an application of soft magnetic core. Owing to hard and brittle characteristics of Fe-6.5Si nano powders having large surface area, it is very difficult to reach high density more than 70% of theoretical density (~7.4 g/$cm_3$) by cold compaction. To overcome such problem a magnetic pulsed compaction (MPC), which is one of dynamic compaction techniques, was applied. The green density was achieved about 78% (~5.8 g/$cm_3$) by MPC at room temperature.

Switching Characteristics of Magnetic Tunnel Junction with Amorphous CoFeSiB Free Layer (비정질 CoFeSiB 자유층을 갖는 자기터널접합의 스위칭 특성)

  • Hwang, J.Y.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.16 no.6
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    • pp.276-278
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    • 2006
  • The switching characteristics of magnetic tunnel junctions (MTJs) comprising amorphous ferromagnetic CoFeSiB free layer have been investigated. CoFeSiB was used for the free layer to enhance the switching characteristics. The typical junction structure was $Si/SiO_{2}/Ta$ 45/Ru 9.5/IrMn 10/CoFe $7/AlO_{x}/CoFeSiB\;(t)/Ru\;60\;(in\;nm)$. CoFeSiB has low saturation magnetization ($M_{s}$) of $560\;emu/cm^{3}$ and high anisotropy constant ($K_{u}$) of $2800\;erg/cm^{3}$. These properties caused low coercivity ($H_{c}$) and high sensitivity in MTJs, and it also confirmed in submicrometer-sized elements by micromagnetic simulation based on the Landau-Lisfschitz-Gilbert equation. By increasing CoFeSiB free layer thickness, the switching characteristics became worse due to increase of the demagnetization field.

Preparation and Characterization of P-Type Thermoelectric $\beta-FeSi_2$ Containing Dispersed Si Phase(l)-Microstructural Evolution with Processing Conditions- (Si 분산 조직의 p형 $\beta-FeSi_2$ 열전재의 제조 및 특성(l)-제조 조건에 따른 미세조직의 변화-)

  • Min, Byeong-Gyu;Kim, Il-Ho;Lee, Dong-Hui
    • Korean Journal of Materials Research
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    • v.8 no.7
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    • pp.584-590
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    • 1998
  • The microstructures of finely distributed Si-phases in $\beta$-$FeSi_2$ thermoelectric matrix, were produced by heat-treating the melt-cast ingots of single $\alpha$-$Fe_2Si_5$ phase at 730~85$0^{\circ}C$ for 4~20 hours, or by resistance-hot-pressing the mechanically alloyed powders ordinarily consisting of $\varepsilon$-FeSi and Si phases at 760~85$0^{\circ}C$ for 10 minutes of composition. $(Fe_{0.98}Mn_{0.02})_xSi_2(x{\leq$}1) The size and interspacing of dispersed Si-phases were able to control within a range of 0.05~0.27$\mu\textrm{m}$ and 0.2~0.6$\mu\textrm{m}$ by variations of heat treatment temperature and sintering temperature as well as the composition. respectively. The dispersion of Si- phases was expected to be effective for the reduction of thermal conductivity responsible for the increment of thermoelectric figure of merit.

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