• Title/Summary/Keyword: Fe-59

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Behaviors of the interface cracks during an Al-Fe dissimilar joining (Al-Fe 이종재료 접합 계면에서의 크랙 거동)

  • Gang Nam-Hyeon;Kim Cheol-Hui;Kim Jun-Gi;Lee Chang-U
    • Proceedings of the KWS Conference
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    • 2006.05a
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    • pp.59-61
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    • 2006
  • The $CO_2$ laser cladding was conducted on an AC2B alloy with feeding Fe-based powders. A powder feeding rate (PFR) and a travel velocity were related with the cracks adjacent to the Fe/Al interface. Preheating temperature was varied to study the interface crack. Preheating to $250^{\circ}C$ during the laser cladding suppressed the interface crack ratio (ICR). The ICR was limited for the single pass clad and the reciprocating test for the slide wear was conducted on an overlay cladding experiment. Comparing with no overlap overlay, the overlay clad with 50% overlap showed better wear resistance.

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Large Barkhausen Effects by Annealing of CoFeSiB Amorphous Ribbon (CoFeSiB 아몰퍼스리본의 열처리에 의한 대바크하우젠 효과)

  • 임재근;강재덕;정병두;신용진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.59-72
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    • 1999
  • In this thesis, we measured the Barkhausen effect of CoFeSiB amorphous ribbon and then investigated its possibility to be used as a sensor material. We used a sample of composition $($Fe_{0.06}$$Co_{0.94}$)_${0.79}$$Si_{2.1}$$B_{18.9}$ with a thickness 12[pm1, width 2.5[rnml and length 5[cm], which was fabricated by a single roll method. In order to improve magnetic characteristics of the sample, we had carried on annealing in the magnetic field and in none magnetic field. And, experimented results to the magnetic characteristics show that the ribbon has large Barkhausen jump even in weak magnetic field below 0.5[0el. From the results, we confirmed that the sample can be used as an magnetic sensor material.

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Reinvestigation of Dion-Jacobson Phases CsCa2Nb2MO9 (M = Fe and Al)

  • Hong, Young-Sik
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.853-856
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    • 2006
  • Dion-Jacobson phases $CsCa_2Nb_2FeO_9$ and $CsCa_2Nb_2AlO_9$ were reinvestigated by the Rietveld analysis of powder X-ray diffraction (XRD) method, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). These nominal compounds, previously known as the oxygen-deficient layered perovskites with the sequences of $NbO_6-MO_4-NbO_6$ in tripled slab, in fact, were mixed phases of n = 3 Dion-Jacobson phases and impurities such as $Ca_2NbFeO_6$ and $Ca_3Al_2O_6$. The difference of morphology and chemical in-homogeneity between Dion-Jacobson phases and impurities could be clearly identified by scanning electron microscopy with energy-dispersive X-ray spectroscopy. The chemical composition of $CsCa_2Nb_2FeO_9$ was calculated into $Cs_{0.59}Ca_{2.64}Nb_{2.92}Fe_{0.81}$ in small agglomerate crystals and $Cs_{0.95}Ca_{1.97}Nb_{3.08}Fe_{0.15}$ in long plate-like crystals.

Peculiar Features in the Emission Lines of Symbiotic Stars AG Draconis and UV Aurigae

  • Kim, Soo Hyun;Yoon, Tae Seog;Oh, Hyung-il
    • The Bulletin of The Korean Astronomical Society
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    • v.43 no.2
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    • pp.59.3-59.3
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    • 2018
  • 공생별 AG Dra와 UV Aur에 대해 지난 10여년간 보현산천문대 1.8m망원경과 고분산 에셀 분광기 BOES(BOao Echelle Spectrograph)로 분광관측을 수행해 왔다. 최근 2017년 11월 - 2018년 6월 관측에서, AG Dra의 Fe II 방출선과 UV Aur $H{\alpha}$ 방출선이 예년과 다른 변화 모습을 보이고 있음을 찾아내었다. 이에 대한 변화 원인을 공전주기, 밝기 변화 또는 다른 이유와 연관지어 설명하고자 한다.

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Occurrence and Chemical Composition of Ti-bearing Minerals from Samgwang Au-ag Deposit, Republic of Korea (삼광 금-은 광상에서 산출되는 함 티타늄 광물들의 산상 및 화학조성)

  • Yoo, Bong Chul
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.3
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    • pp.195-214
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    • 2020
  • The Samgwang Au-Ag deposit has been one of the largest deposits in Korea. The deposit consists of eight lens-shaped quartz veins which filled fractures along fault zones in Precambrian metasedimentary rock, which feature suggest that it is an orogenic-type deposit. The Ti-bearing minerals occur in wallrock (titanite, ilmenite and rutile) and laminated quartz vein (rutile). They occur minerals including biotite, muscovite, chlorite, white mica, monazite, zircon, apatite in wallrock and white mica, chlorite, arsenopyrite in laminated quartz vein. Chemical composition of titanite has maximum vaules of 3.94 wt.% (Al2O3), 0.49 wt.% (FeO), 0.52 wt.% (Nb2O5), 0.46 wt.% (Y2O3) and 0.43 wt.% (V2O5). Titanite with 0.06~0.14 (Fe/Al ratio) and 0.06~0.15 (XAl (=Al/Al+Fe3++Ti)) corresponds with metamorphic origin and low-Al variety. Chemical composition of ilmenite has maximum values of 0.07 wt.% (ZrO2), 0.12 wt.% (HfO2), 0.26 wt.% (Nb2O5), 0.04 wt.% (Sb2O5), 0.13 wt.% (Ta2O5), 2.62 wt.% (As2O5), 0.29 wt.% (V2O5), 0.12 wt.% (Al2O3) and 1.59 wt.% (ZnO). Chemical composition of rutile in wallrock and laminated quartz vein has maximum values of 0.35 wt.%, 0.65 wt.% (HfO2), 2.52 wt.%, 0.19 wt.% (WO3), 1.28 wt.%, 1.71 wt.% (Nb2O3), 0.03 wt.%, 0.07 wt.% (Sb2O3), 0.28 wt.%, 0.21 wt.% (As2O5), 0.68 wt.%, 0.70 wt.% (V2O3), 0.48 wt.%, 0.59 wt.% (Cr2O3), 0.70 wt.%, 1.90 wt.% (Al2O3) and 4.76 wt.%, 3.17 wt.% (FeO), respectively. Rutile in laminated quartz vein is higher contents (HfO2, Nb2O3, As2O5, Cr2O3, Al2O3 and FeO) and lower content (WO3) than rutile in wallrock. The substitutions of rutile in wallrock and laminated quatz vein are as followed : rutile in wallrock [(Fe3+, Al3+, Cr3+) + Hf4+ + (W5+, As5+, Nb5+) ⟵⟶ 2Ti4+ + V4+, 2Fe2+ + (Al3+, Cr3+) + Hf4+ + (W5+, As5+, Nb5+) ⟵⟶ 2Ti4+ + 2V4+], rutile in laminated quartz vein [(Fe3+, Al3+) + As5+ ⟵⟶ Ti4+ + V4+, (Fe3+, Al3+) + As5+ ⟵⟶ Ti4+ + Hf4+, 4(Fe3+, Al3+) ⟵⟶ Ti4+ + (W5+, Nb5+) + Cr3+], respectively. Based on these data, titanite, ilmenite and rutile in wallrock were formed by resolution and reconcentration of cations (W5+, Nb5+, As5+, Hf4+, V4+, Cr3+, Al3+, Fe3+, Fe2+) in minerals of wallrock during regional metamorphism. And then rutile in laminated quartz vein was formed by reconcentration of cations (Nb5+, As5+, Hf4+, Cr3+, Al3+, Fe3+, Fe2+) in alteration minerals (white mica, chlorite) and Ti-bearing minerals reaction between hydrothermal fluid originated during ductile shear and Ti-bearing minerals (titanite, ilmenite and rutile) in wallrock.

Spatial Distributions of Alloying Elements Obtained from Atom Probe Tomography of the Amorphous Ribbon Fe75C11Si2B8Cr4

  • Shin, Jinkyung;Yi, Seonghoon;Pradeep, Konda Gokuldoss;Choi, Pyuck-Pa;Raabe, Dierk
    • Korean Journal of Materials Research
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    • v.23 no.3
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    • pp.190-193
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    • 2013
  • Spatial distributions of alloying elements of an Fe-based amorphous ribbon with a nominal composition of $Fe_{75}C_{11}Si_2B_8Cr_4$ were analyzed through the atom probe tomography method. The amorphous ribbon was prepared through the melt spinning method. The macroscopic amorphous natures were confirmed using an X-ray diffractometer (XRD) and a differential scanning calorimeter (DSC). Atom Probe (Cameca LEAP 3000X HR) analyses were carried out in pulsed voltage mode at a specimen base temperature of about 60 K, a pulse to base voltage ratio of 15 %, and a pulse frequency of 200 kHz. The target detection rate was set to 5 ions per 1000 pulses. Based on a statistical analyses of the data obtained from the volume of $59{\times}59{\times}33nm^3$, homogeneous distributions of alloying elements in nano-scales were concluded. Even with high carbon and strong carbide forming element contents, nano-scale segregation zones of alloying elements were not detected within the Fe-based amorphous ribbon. However, the existence of small sub-nanometer scale clusters due to short range ordering cannot be completely excluded.

Studies on the Development of Photoreceptor in the Nonchromatophore Organisms(I) - Light-Induced Mitochondrial ATPase in the L. edodes(Berk) Sing -­ (무흡광색소 식물의 감광수용체 개발 연구(I) - 표고버섯 중의 광감응성 mitochondrial ATPase -)

  • Min, Tae-Jin;Cho, Suck-Woo;Park, Sang-Shin
    • The Korean Journal of Mycology
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    • v.15 no.4
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    • pp.217-223
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    • 1987
  • Mitochondria in the L. edodes was purified by linear sucrose density gradient centrifugation. The mitochondrial ATPase activity was investigated by various wavelength illumination for 30 min at dark state. The mitochondrial ATPase activity was stimulated 1.6 fold by 680 nm illumination compared with dark control group. The mitochondrial ATPase activity of different light illumination time at 680 nm was stimulated 2.3 fold at 5 minutes compared with dark control group. Its optimum pH and temperature were found to be 7.5 and $59^{\circ}C$ after illumination for 5 minutes at 680 nm. The mitochondrial ATPase activity was activated by 5 mmol $Fe^{3+}$, 0.1 mmol $Fe^{2+}$, 0.1 mmol $Mg^{2+}$, 0.5 mmol $K^{+}$, and 0.1 mmol $Ca^{2+}$ ion. But, the enzyme was inhibited by 5 mmol $Na^{+}$ ion.

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Diverse Chemo-Dynamical Properties of Nitrogen-Rich Stars Identified from Low-Resolution Spectra

  • Changmin Kim;Young Sun Lee;Timothy C. Beers;Young Kwang Kim
    • Journal of The Korean Astronomical Society
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    • v.56 no.1
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    • pp.59-73
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    • 2023
  • The second generation of stars in the globular clusters (GCs) of the Milky Way (MW) exhibit unusually high N, Na, or Al, compared to typical Galactic halo stars at similar metallicities. The halo field stars enhanced with such elements are believed to have originated in disrupted GCs or escaped from existing GCs. We identify such stars in the metallicity range -3.0 < [Fe/H] < 0.0 from a sample of ~36,800 giant stars observed in the Sloan Digital Sky Survey and Large Sky Area Multi-Object Fiber Spectroscopic Telescope survey, and present their dynamical properties. The N-rich population (NRP) and N-normal population (NNP) among our giant sample do not exhibit similarities in either in their metallicity distribution function (MDF) or dynamical properties. We find that, even though the MDF of the NRP looks similar to that of the MW's GCs in the range of [Fe/H] < -1.0, our analysis of the dynamical properties does not indicate similarities between them in the same metallicity range, implying that the escaped members from existing GCs may account for a small fraction of our N-rich stars, or the orbits of the present GCs have been altered by the dynamical friction of the MW. We also find a significant increase in the fraction of N-rich stars in the halo field in the very metal-poor (VMP; [Fe/H] < -2.0) regime, comprising up to ~20% of the fraction of the N-rich stars below [Fe/H] = -2.5, hinting that partially or fully destroyed VMP GCs may have in some degree contributed to the Galactic halo. A more detailed dynamical analysis of the NRP reveals that our sample of N-rich stars do not share a single common origin. Although a substantial fraction of the N-rich stars seem to originate from the GCs formed in situ, more than 60% of them are not associated with those of typical Galactic populations, but probably have extragalactic origins associated with Gaia Sausage/Enceladus, Sequoia, and Sagittarius dwarf galaxies, as well as with presently unrecognized progenitors.

Chemistry and Rietveld Structure Refinement of Nb-rich Perovskite, $Ca_2NbFe^{3+}O_6$ (네오비움 페롭스카이트($Ca_2NbFe^{3+}O_6$)의 화학조성 및 리트벨트 구조분석 연구)

  • ;Frank C. Hawthorne
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.59-68
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    • 2002
  • Chemical analyses and Rietveld structural refinement with powder X-ray diffraction data were done for Nb-rich perovskite, named latrappite ($Ca_2NbFe^{3+}O_6$)from the Oka, Quebec, Canada. Latrappite is shown to be a member of a continuous solid solution of $CaTiO_3-NaNbO_3-Ca_2NbFe^{3+}O_6$ and approximately $(Ca_{1.5}Na_{0.4})\;(Nb_{0.1}Ti_{0.6}Fe_{0.4})O_6$ in composition. The crystal structure of latrappite, determined by Rietveld refinement, is similar to that of perovskite ($CaTiO_3$). It differs in that replacement of Ti by Nb and $Fe^{3+}$ results in greater distortion and tilting of the $TiO_6$ framework octahedra relative to $CaTiO_3$. Revised unit-cell parameters of latrappite are a=5.4474(4), b=5.5264(4), c=7.7519(5) ${\AA},\;V=233.4(3){\AA}^3$ space group Pbnm.