• Title/Summary/Keyword: Fe excess addition

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A Study on Development of Insert Metal for Liquid Phase Diffusion Bonding of Fe Base Heat Resistance Alloy (Fe 기내열합금의 액상확상접합용 삽입금속의 개발에 관한 연구)

  • 강정윤;김인배;이상래
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.147-156
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    • 1995
  • The change of microstructure in the bonded interlayer and tensile properties of joints were studied for liquid phase diffusion bonding using STS-310 and Incoloy-825 as base metal and base metal+B alloy as insert inetal. Main experimental results obtained in this study are as follows. 1) The optimum amount of B addition into the insert metal was found to be about 4mass%. 2) When isothermal solidification was completed, the microstructure in the bonded interlayer was the same with that of the base metal because of the grain boundary migration in the bonded interlayer. 3) All of the tensile specimen fractured at base metal and joints bonded at optimum condition exhibited tensile properties in excess of base metal requirements. 4) It was determined that fine car-borides and bordes such as M$_{23}$(C,B)$_{6}$, Cr$_{2}$B, and CrB in STS-310S and TiB in Incoloy-825 exist at the grain boundary around bonded interlayer. These precipitates almost disappeared after homogenizing treatment at 1373K for 86.4ks.s.

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The Effect of Mn on Microstructural Change in 93W-5.6Ni-1.4Fe Heavy Alloy (텅스텐 중합금에 Mn 첨가에 따른 미세조직)

  • 김은표
    • Journal of Powder Materials
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    • v.5 no.1
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    • pp.35-41
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    • 1998
  • The effect of Mn on the densification and the microstructural change in W heavy alley was investigated with adopting the improved Mn-adding method. In order to avoid the pore formation problems associated with Mn powder mixing to the other constituent powders, Mn was added afterwards to the sintered heavy alloy; Mn powder was spread homogeneously on the surface of the sintered heavy alloy compact, and this Mn powder contained specimen was resintered at the same sintering temperature. As expected, the resintered specimen showed the pore free microstructure because Mn was reduced separately from the other constituent elements. It was also founded that W grains grew rapidly at the initial stage of resintering treatment due to the activated reprecipitation of the excess W atoms substituted by Mn atoms, but the growth rate of W grains was slowly lowered with the prolonged sintering time, especially, compared to the Mn free heavy alloy. Such a retardation of grain growth should be attributed to the decreased W solubility in the Mn contented matrix phase. Furthermore, Mn addition resulted in the decrease of contiguity by improving the wetting between matrix phase and W grain.

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Identification and Characterization of External Copper Responsive Genes of Deinococcus radiodurans (DNA Microarry를 이용한 Deinococcus radiodurans의 구리이온 특이 반응 유전자 탐색 및 특성 분석)

  • Joe, Min-Ho;Lim, Sang-Yong;Jung, Sun-Wook;Song, Du-Sub;Choi, Young-Ji;Kim, Dong-Ho
    • Korean Journal of Microbiology
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    • v.44 no.3
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    • pp.169-177
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    • 2008
  • Global gene expression of Deinococcus radiodurans, a highly radiation resistant bacterium, in response to excess copper was analyzed by using oligonucleotide microarray chip. Among 3,187 open reading frames of D. radiodurans, seventy genes showed a statistically significant expression ratio of at least 2-fold changes under growth conditions of excess copper; 64 genes were induced and 6 genes were reduced. Especially, two operons ($DRB0014{\sim}DRB0017$ and $DRB0125{\sim}DRB0121$) presumably involved in the iron transport and utilization were the most highly induced genes by excess copper. A quantitative real-time PCR assay revealed that DRB00l4 and DRB0125 are highly transcribed responding to excess copper and 2,2'-dipyridyl, an iron chelator. In addition, the transcription of both genes was not changed by excess iron and bathocuproine disulphonate, a copper chelator. These results suggested that the copper metabolism may be closely connected with the iron transport and utilization in D. radiodurans. However, the disruption of each gene, DRB00l4 and DRB0125, did not affect the copper and radiation resistance, the most well-known character of this organism.

Catalytic Reduction of Nitric Oxide by Carbon Monoxide over Perovskite-Type Oxide (페롭스카이트형 산화물에서 일산화탄소에 의한 질소산화물의 환원반응)

  • Moon, Haeng-Chul;Sun, Chang-Bong;Lee, Gun-Dae;Ahn, Byuong-Hyun;Lim, Kwon-Taek;Hong, Seong-Soo
    • Applied Chemistry for Engineering
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    • v.10 no.3
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    • pp.407-414
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    • 1999
  • We have studied the reduction of NO by CO over perovskite-type oxides prepared by malic and method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxides. In the $LaCoO_3$ type catalyst, the partial substitution of Sr into A site enhanced the catalytic activity on the conversion of NO at less than $350^{\circ}C$. In the $La_{0.6}Sr_{0.4}Co_{1-x}Fe_xO_3$ catalyst, the partial substitution of Fe or Mn into B site enhanced the conversion of NO, but excess amount of Fe decreased the conversion of NO. In addition, $La_{0.6}Sr_{0.4}Co_{0.8}Fe_{0.2}O_3$ mixed with $SnO_2$ or $MnO_2$ showed the synergy effect on the reduction of NO. The introduction of water into reactants feed decreased the catalytic activity but the deactivation was shown to be reversible. The introduction of $SO_2$ into reactants feed also decreased the catalytic activity.

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Nonstoichiometric Effects in the Leakage Current and Electrical Properties of Bismuth Ferrite Ceramics

  • Woo, Jeong Wook;Baek, SeungBong;Song, Tae Kwon;Lee, Myang Hwan;Rahman, Jamil Ur;Kim, Won-Jeong;Sung, Yeon Soo;Kim, Myong-Ho;Lee, Soonil
    • Journal of the Korean Ceramic Society
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    • v.54 no.4
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    • pp.323-330
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    • 2017
  • To understand the defect chemistry of multiferroic $BiFeO_3-based$ systems, we synthesized nonstoichiometric $Bi_{1+x}FeO_{3{\pm}{\delta}}$ ceramics by conventional solid-state reaction method and studied their structural, dielectric and high-temperature charge transport properties. Incorporation of an excess amount of $Bi_2O_3$ lowered the Bi deficiency in $BiFeO_3$. Polarization versus electric field (P-E) hysteresis loop and dielectric properties were found to be improved by the $Bi_2O_3$ addition. To better understand the defect effects on the multiferroic properties, the high temperature equilibrium electrical conductivity was measured under various oxygen partial pressures ($pO_2{^{\prime}}s$). The charge transport behavior was also examined through thermopower measurement. It was found that the oxygen vacancies contribute to high ionic conduction, showing $pO_2$ independency, and the electronic carrier is electron (n-type) in air and Ar gas atmospheres.

Vanadium Leaching Behavior from Domestic Vanadium Bearing Titanomagnetite Ore through CaO Roasting (국내산 함바나듐 티탄자철광으로부터 CaO 배소를 통한 바나듐 침출거동)

  • Shin, Dong Ju;Joo, Sung-Ho;Lee, Dongseok;Jeon, Ho-Seok;Shin, Shun Myung
    • Resources Recycling
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    • v.30 no.4
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    • pp.27-34
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    • 2021
  • In this study, the leaching behavior of vanadium (V) was investigated through CaO roasting and sulfuric acid leaching from domestic V-bearing titanomagnetite (VTM). Changes in the phase according to the amount of CaO added and roasting temperature were analyzed. Regardless of the roasting conditions, perovskite (CaTiO3) was preferred to form. When the CaO content was increased, the calcium ferrite (CaFeOx) phase was formed; otherwise, ferrite (Fe2O3) was preferred. After CaO was roasted, leaching was performed for 6 h with 1M sulfuric acid at 50℃ and a 10% solid-liquid ratio. Results of leaching revealed that when the roasted product was sintered, V was not sufficiently oxidized, and the leaching efficiency decreased. In addition, when the roasting temperature was low, the leaching efficiency of V decreased due to the influence of unreacted excess CaO. To lower the leaching efficiency of iron and titanium in VTM concentrates, suppressing the formation of CaTiO3 and CaFeOx was necessary by minimizing the amount of CaO added. Consequently, a leaching efficiency of 86% V, 4.3% Fe, and 6.5% Ti was obtained when the roasted product of 1150℃ and 10 wt% CaO was leached.

UBV I CCD PHOTOMETRY OF THE OLD OPEN CLUSTER NGC 1193

  • Kyeong, Jae-Mann;Kim, Sang-Chul;Hiriart, David;Sung, Eon-Chang
    • Journal of The Korean Astronomical Society
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    • v.41 no.6
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    • pp.147-155
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    • 2008
  • We present UBV I photometry of the old open cluster NGC 1193. Color-magnitude diagrams (CMDs) of this cluster show a well defined main sequence and a sparse red giant branch. For the inner region of r < 50", three blue straggler candidates are newly found in addition to the objects Kaluzny (1988) already found. The color-color diagrams show that the reddening value toward NGC 1193 is E(B - V ) = $0.19{\pm}0.04$. From the ultraviolet excess measurement, we derived the metallicity to be [Fe/H]= $-0.45{\pm}0.12$. A distance modulus of ${(m\;-\;M)}_0$ = $13.3{\pm}0.15$ is obtained from zero age main sequence fitting with the empirically calibrated Hyades isochrone of Pinsonneault et al. (2004). CMD comparison with the Padova isochrones by Bertelli et al. (1994) gives an age of log t = $9.7{\pm}0.1$.

Antioxidant and Neuroprotective Effects of Hesperidin and its Aglycone Hesperetin

  • Cho, Jung-Sook
    • Archives of Pharmacal Research
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    • v.29 no.8
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    • pp.699-706
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    • 2006
  • The present study evaluated antioxidant and neuroprotective activities of hesperidin, a flavanone mainly isolated from citrus fruits, and its aglycone hesperetin using cell-free bioassay system and primary cultured rat cortical cells. Both hesperidin and hesperetin exhibited similar patterns of 1,1-diphenyl-2-picrylhydrazyl radical scavenging activities. While hesperidin was inactive, hesperetin was found to be a potent antioxidant, inhibiting lipid peroxidation initiated in rat brain homogenates by $Fe^{2+}$ and L-ascorbic acid. In consistence with these findings, hesperetin protected primary cultured cortical cells against the oxidative neuronal damage induced by $H_2O_2$ or xanthine and xanthine oxidase. In addition, it was shown to attenuate the excitotoxic neuronal damage induced by excess glutamate in the cortical cultures. When the excitotoxicity was induced by the glutamate receptor subtype-selective ligands, only the N-methyl-D-aspartic acid-induced toxicity was selectively and markedly inhibited by hesperetin. Furthermore, hesperetin protected cultured cells against the $A_{{\beta}(25-35)}-induced$ neuronal damage. Hesperidin, however, exerted minimal or no protective effects on the neuronal damage tested in this study. Taken together, these results demonstrate potent antioxidant and neuroprotective effects of hesperetin, implying its potential role in protecting neurons against various types of insults associated with many neurodegenerative diseases.

Analysis of Radioactive Characterization in the Medical Linear Accelerator Shielding Wall Using Monte Carlo Method (몬테칼로법을 이용한 의료용 선형가속기 차폐벽의 방사화 특성 분석)

  • Lee, Dong-Yeon;Park, Eun-Tae
    • The Journal of the Korea Contents Association
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    • v.16 no.10
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    • pp.758-765
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    • 2016
  • This study analyzed for the radioactive shielding wall, which shields the medical linear accelerator. This allows to evaluate the level of waste with respect to the shield wall, which accounts for more than half of the cost of dismantling later linac facility. In addition, by analyzing the waste processing method according we discuss the way to obtain the benefits in terms of dismantling cost. Results of the simulate, the amount sufficient to screen the amount of neutron radiation occurring in the shielding wall linac was measured. And neutron activation analysis results were analyzed nuclides more than about 20. This analysis was in excess of that, $^{24}Na$, $^{45}Ca$, $^{59}Fe$ nucleus paper deregulation concentration. The value is reduced is greater the deeper the depth of the shielding wall concentration. Based on this, three specific areas (E, F, G) was estimated to be impossible to landfill or recycling. The rest area was estimated to be buried or recycled if possible more than a predetermined depth.

Numerical study on the effect of viscoelasticity on pressure drop and film thickness for a droplet flow in a confined microchannel

  • Chung, Chang-Kwon;Kim, Ju-Min;Ahn, Kyung-Hyun;Lee, Seung-Jong
    • Korea-Australia Rheology Journal
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    • v.21 no.1
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    • pp.59-69
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    • 2009
  • The prediction of pressure drop for a droplet flow in a confined micro channel is presented using FE-FTM (Finite Element - Front Tracking Method). A single droplet is passing through 5:1:5 contraction - straight narrow channel - expansion flow domain. The pressure drop is investigated especially when the droplet flows in the straight narrow channel. We explore the effects of droplet size, capillary number (Ca), viscosity ratio ($\chi$) between droplet and medium, and fluid elasticity represented by the Oldroyd-B constitutive model on the excess pressure drop (${\Delta}p^+$) against single phase flow. The tightly fitted droplets in the narrow channel are mainly considered in the range of $0.001{\leq}Ca{\leq}1$ and $0.01{\leq}{\chi}{\leq}100$. In Newtonian droplet/Newtonian medium, two characteristic features are observed. First, an approximate relation ${\Delta}p^+{\sim}{\chi}$ observed for ${\chi}{\geq}1$. The excess pressure drop necessary for droplet flow is roughly proportional to $\chi$. Second, ${\Delta}p^+$ seems inversely proportional to Ca, which is represented as ${\Delta}p^+{\sim}Ca^m$ with negative m irrespective of $\chi$. In addition, we observe that the film thickness (${\delta}_f$) between droplet interface and channel wall decreases with decreasing Ca, showing ${\delta}_f{\sim}Ca^n$ Can with positive n independent of $\chi$. Consequently, the excess pressure drop (${\Delta}p^+$) is strongly dependent on the film thickness (${\delta}_f$). The droplets larger than the channel width show enhancement of ${\Delta}p^+$, whereas the smaller droplets show no significant change in ${\Delta}p^+$. Also, the droplet deformation in the narrow channel is affected by the flow history of the contraction flow at the entrance region, but rather surprisingly ${\Delta}p^+$ is not affected by this flow history. Instead, ${\Delta}p^+$ is more dependent on ${\delta}_f$ irrespective of the droplet shape. As for the effect of fluid elasticity, an increase in ${\delta}_f$ induced by the normal stress difference in viscoelastic medium results in a drastic reduction of ${\Delta}p^+$.