• Bulletin of the Korean Chemical Society
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• v.12 no.4
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• pp.406-410
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• 1991

Second order rate constants have been measured spectrophotometrically for reactions of 4-nitrophenyl substituted benzoates with various aryloxides and aryl benzoates with p-chlorophenoxide. The reactivity has exhibited significant dependences on the electronic nature of the substituent in the acyl moiety of the substrate and in the nucleophilic phenoxide, while the substituent in the leaving phenoxide has little influenced the reactivity. The Bronsted coefficient $\beta$ values so obtiained support that the present acyl transfer reaction proceeds via a stepwise mechanism in which the nucleophilic attack would be the rate-determining step. Interestingly, the magnitude of the $\betaacyl$ and $\beta$ nuc increases with increasing reactivity, implying that the reactivity selectivity principle is not operative in the present system. The failure of the reactivity selectivity principle is attributed to a change in transition state structure upon the substituent variation in the present acyl transfer reaction.

• International Journal of Reliability and Applications
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• v.2 no.2
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• pp.107-115
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• 2001

This paper considers some reliability indices, such as availability, average availability, reliability and steady state availability, of a redundant system with the function of switchover processing. We also derive the confidence limits for steady state availability of such system. The system, which is considered in this paper, consists of an active unit, a standby unit and a switchover device. In addition, the switchover processing is controlled by a control module. The effect of failure of the control module is taken into account to develop our reliability model for the redundant structure. Numerical examples are presented to illustrate our results.

• Computers and Concrete
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• v.8 no.4
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• pp.401-423
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• 2011

In this paper, a mesoscale model of concrete is presented, which considers particles, matrix material and the interfacial transition zone (ITZ) as separate constituents. Particles are represented as ellipsoides, generated according to a prescribed grading curve and placed randomly into the specimen. In this context, an efficient separation procedure is used. The nonlinear behavior is simulated with a cohesive interface model for the ITZ and a combined damage/plasticity model for the matrix material. The mesoscale model is used to simulate a compression and a tensile test. Furthermore, the influence of the particle distribution on the loaddisplacement curve is investigated.

• Nuclear Engineering and Technology
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• v.53 no.9
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• pp.2990-3002
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• 2021

The mechanical interaction between the fuel pellet and the cladding tube of a nuclear fuel rod is a very important for safety studies as this phenomenon could lead to fuel failure and release of radioactivity. To investigate the ductility of cladding tubes used in WWER type nuclear power plants, several mandrel tests were performed in the Centre for Energy Research (EK). This modified mandrel test was used to model the mechanical interaction between the fuel pellet and the cladding using a segmented tool. The tests were conducted at room temperature and at 300 ℃ with inactive as-received and hydrogenated cladding ring samples. The results show a gradual decrease in ductility as the hydrogen content increases, the ductile-brittle transition was seen above 1500 ppm hydrogen absorbed.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.41 no.5
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• pp.574-580
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• 2016

In this paper, we will introduce the system that can control multiple vehicles on the road through Single Board Computers and V2I (Vehicle-To-Infrastructure). Also, we will propose the group evasive maneuver decision algorithm, which plays a critical role in deciding whether the vehicles in the system have to conduct evasive maneuvers to avoid obstacles on the road. In order to test this system, we have utilized Wi-Fi and TCP/IP for establishing the communication between multiple vehicles and the relay server, and observed their driving states on the road with obstacles. During the experiments, we have discovered that our original decision algorithm possesses high failure rate when there is frequency interference in ISM (Industrial Scientific Medical) band. In order to reduce this failure rate, we have implemented the data transition detector. This paper will focus on how the use of data transition detector can affect the reliability of the system under the frequency interference of ISM band. If this technology is improved and applied in the field, we will effectively deal with such dangerous situations as multiple collision accidents through vehicle-to-vehicle communication or vehicle-to-infrastructure communication. Furthermore, this can be applied to the autonomous driving technologies. This can be used as the reference data for the development of the similar system.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.24 no.6 s.177
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• pp.1398-1407
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• 2000

The structural steels of power plant show the decrease of mechanical properties due to degradation such as temper embrittlement, creep damage and softening during long-term operation at high temper ature. The typical causes of material degradation damage are the creation and coarsening of carbides(M23C6, M6C) and the segregation of impurities(P, Sb and Sn) to grain boundary. It is also well known that material degradation induces the cleavage fracture and increases the ductile-brittle transition temperature of steels. So, it is very important to evaluate degradation damage to secure the reliable and efficient service condition and to prevent brittle failure in service. However, it would not be appropriate to sample a large test piece from in-service components. Therefore, it is necessary to develop a couple of new approaches to the non-destructive estimation technique which may be applicable to assessing the material degradation of the components with not to influence their essential strength. The purpose of this study is to propose and establish a new electrochemical technique for non-destructive evaluation of material degradation damage for Cr-Mo steels which is widely used in the high temperature structural components. And the electrochemical anodic polarization test results are compared with those of semi-nondestructive SP test.

• Journal of Korean Society of Steel Construction
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• v.11 no.1 s.38
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• pp.33-42
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• 1999

In the present study, crack initiation criteria, static failure and tensile mode fatigue behavior for a rail steel are evaluated to assure the railway vehicle's safety. The transverse fissure, which is the most critical damage in the rail, is initiated by the maximum shear stress and its location is subsurface. In addition, the possibility of transition from the shear mode to the mixed mode increases with increasing the length of subsurface crack. Because of the brittleness by the welding, the fracture toughness of the welded part is lower than of the base metal. For low ${\Delta}K$, the stage II fatigue crack growth rates of the welded part is slower than of the base metal but, for high ${\Delta}K$, this different behavior for fatigue crack growth rate is nearly diminished. These trends are more remarkable for low stress ratio, R=0.1. It is believed that this behavior is caused by the change of the microstructure which that of the welded part is coarser than of base metal.

• Journal of Science and Technology Studies
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• v.8 no.2
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• pp.57-81
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• 2008

This paper reviewed outline of Strategic Niche Management(SNM) and its usefulness and limits as policy tool. SNM is based on Multi Level Perspective(MLP) that traces technological innovation and makes transition of lock-in socio-technical system. This approach is one of systematical then traditional one, market failure approach. SNM had get a attention not only as a analytical frame of technological development, but also tool of radical innovation, although its limits of theoretical and empirical immaturity. SNM could provide a new perspective to analysis and action within urgent needs of alternative innovation policy for aging society, news energy policy for sustainable and disaster policy in danger society.

• The Journal of Korean Academy of Prosthodontics
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• v.29 no.2
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• pp.67-84
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• 1991

This study was carried out to investiagate the residual stress caused by the mismatch of thermal expansion and the bond failure resistance of alloy-porcelain specimens. The thermal expansions of alloys and porcelains were measured by using a straight push-rod dilatometer. Porcelain glass transition temperatures, thermal expansion coefficients, and thermal compatibility indices were derived from length-versus-temperature curves. Strain gauges were used to experimentally determine the Young's moduli of porcelains, the residual stresses of porcelain surface, and tensile bond strengths of the specimens of simulated porcelain metal crown. The obtained results were as follows: 1. The coefficients of thermal expansion for alloys were the minimum of $13.53\mu/^{\circ}C$ and the maximum of $20.11\mu/^{\circ}C$ in the range of $100\sim600^{\circ}C$ and those for porcelains were the minimum of $7.72\mu/^{\circ}C$ and the maximum of $31.24\mu/^{\circ}C$ in the range of $100\sim500^{\circ}C$. 2. The glass transition temperature of porcelains exhibited the same value without my relation to the healing rate, and the thermal disharmony of porcelain and alloy was more affected by porcelains than by the alloys. 3. The Young's moduli of body porcelains were larger than those of opaque porcelains(P<0.01) 4. It seemed that the residual stresses of porcelain surfaces in the porcelainalloy systems were more affected by porcelains than by alleys. 5. The bond strengths of the procelain-base metal alloy systems were larger than those of the porcelain-precious metal alloy systems. The fracture strengths of porcelain surfaces showed significant difference between porcelains (P<0.05).

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.7
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• pp.1064-1072
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• 2001

It is very important to evaluate material degradation like temper and carbide embrittlements to secure the reliable and efficient operational conditions and to prevent brittle failure in service. The extent of material deterioration can be accurately evaluated by mechanical test such as impact test or creep test. But it is almost impossible to sample a large specimen from in-service plants. Thus, the material degradation evaluation by a non-destructive method is earnestly required. Recently the non-destructive test technique which uses the grain boundary etching characteristics owing to the variation of material structures has been proposed. However the program for material degradation evaluation using the grain boundary etching method(GEM) in Windows 98 domain doesnt be developed now. The aims of this paper are to develop the program and to complete the new master curve equations for the evaluation of material degradation on in-serviced high temperature components.