• Korea-Australia Rheology Journal
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• 제19권4호
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• pp.227-232
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• 2007

The use of various shearing apparatuses to study the phase behavior of poly(styrene-b-isoprene) diblock copolymer micelles is described. A DMTA rheometer was modified so that one can apply oscillatory shear and obtain the scattering pattern along the shear gradient direction. A cone and plate shear cell was designed to access scattering along the shear vorticity direction, and both oscillatory and steady shear can be applied. The most popular way to employ steady shear on relatively low viscosity fluids is to use a Couette cell, because a high shear rate can be readily achieved without disturbing the sample by overflow. In this work, oscillatory shear was used to obtain a single crystal-like scattering pattern, and thereby to examine the mechanism of the thermotropic transition between face-centered cubic (fcc) and body-centered cubic (bcc) lattices. By applying the steady shear, the response of the fcc lattices to various shear rates is discussed.

• Macromolecular Research
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• 제16권1호
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• pp.51-56
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• 2008

Spherical micelles of poly(styrene-b-isoprene) (SI) diblock copolymers in selective solvents have been reported to pack onto either face-centered cubic (fcc) or body-centered cubic (bcc) lattices. The selection rule for fcc and bcc lattices has been understood in terms of the intermicellar potentials, and they have been quantified using the ratio of the corona layer thickness to the core radius, $L/R_c$, as suggested by McConnell and Gast. In order to test the validity of the McConnell-Gast criterion, this study compared the $L/R_c$ values from various solutions i.e. nine SI copolymers in several different selective solvents. The McConnell-Gast criterion was not found to be a determining factor, even though it could explain the fcc/bcc selection qualitatively. From the phase diagrams, the transition between fcc and bcc phases was also considered as a function of concentration and temperature, and their physical mechanisms are discussed based on the recent mean-field calculation reported by Grason.

• 공업화학
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• 제20권6호
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• pp.646-652
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• 2009

본 연구는 표면에 액체 막이 입혀진 구 입자를 지나는 기체의 흐름이 구 입자에 작용하는 항력을 결정하는 3상계 문제를 다룬다. 기체 흐름의 관성은 무시할 정도로 작으며, 구 입자의 표면에서 액체는 중력에 의해 흐르고 액체 막이 기체 흐름에 영향을 받지 않는 경우를 고려한다. SC (simple cubic), BCC (body centered cubic), FCC (face centered cubic) 각 배열의 구 입자들에 대해 외란 기법(perturbation method)과 멀티폴 전개(multipole expansion) 방법을 이용하여 입자들의 수력학적 상호 작용을 계산하고 궁극적으로 액체 막과 액체의 흐름이 기체 흐름에 미치는 영향을 수치적으로 결정한다. 근사적인 방법으로 액체 막의 효과에 구하고 이를 엄밀한 계산 값들과 비교한 결과, 대체로 일치함을 보인다.

• 한국산학기술학회논문지
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• 제22권6호
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• pp.19-26
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• 2021

격자 구조체는 강도 및 강성, 초경량 및 에너지 흡수 능력 등의 우수성을 가지고 있어서 전방위 산업에서 주목을 받고 있으나, 다양한 장점에도 불구하고 복잡한 형상에 따른 제조 공정의 어려움으로, 현재까지 광범위한 상용화 및 사용은 제한되고 있다. 한편 적층 제조는 전통적인 제조 방법으로는 불가능한 복잡한 기하학적 형상 제조가 가능한 기술로써, 격자 구조체 제조를 위한 최적 기술로 주목을 받고 있다. 본 연구에서는 3차원 좌표 방법으로 단위 셀을 형성하고, 단위셀의 바운더리 박스 크기 및 스트럿 반경에 따른 상대 밀도의 관계식을 도출하였다. 본 연구에서는 Simple Cubic(SC), Body-Centered Cubic(BCC) 및 Face-Centered Cubic(FCC)을 모델링 소프트웨어를 사용하여 상대 밀도 맞춤형 구조체를 설계하였다. 본 연구에서 제안한 상대 밀도 산출식 정확도는 SC, BCC 및 FCC에서 98.3 %, 98.6 % 및 96.2%의 신뢰성을 확보하였다. 격자 구조체를 대상으로 시뮬레이션 수행 결과, 동일한 셀 배열 조건에서는 상대 밀도가 커짐에 따라 항복 하중이 커지고, 동일 배열 조건에서는 SC, BCC, FCC 순으로 압축 항복 하중이 작아지는 결과가 나타났다. 최종적으로 20 mm × 20 mm × 20 mm 크기의 구조체는 SC 단위 셀을 3×3×3 배열로 구성하는 것이 압축 하중에 대한 구조적 최적화가 가능한 것으로 나타났다.

• 한국정보처리학회논문지
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• 제7권3호
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• pp.872-878
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• 2000

In this paper a computer programming for the expression of nearest neighbor atoms in face-centered cubic (FCC) and body-centered cubic (BCC) crystals was suggested as one of the approaches to understand each of the crystal structure. By using this computer programming the distance values between a reference atom and the nearest neighbor atoms, and the numbers of the nearest neighbor atoms were calculated ane compared for the FCC and BCC crystals. In this algorithm, the positions of the atoms in a crystal were defined as two categories: the corner atoms and face- or body-centered atoms, and considered respectively. For the same order of nearest neighbor atoms except the second order ones the distance values form the reference atom were smaller in the FCC crystals than those in the BCC. Also, the numbers of he first and third nearest neighbor atoms n the FCC crystals were larger than those in the BCC. This difference was explained by the comparison of each atomic packing ratio of the FCC and BCC crystals. The algorithm used in this programming can also be expanded to the analysis of other crystal structures.

• 한국진공학회지
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• 제11권1호
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• pp.59-67
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• 2002

본 연구에서는 분자동력학 시뮬레이션을 이용하여 구리 나노와이어의 구조적 특성에 관하여 연구하였다. 매우 가는 구리 나노와이어의 구조는 면심입방격자 구조와는 다른 원통형 다중 껍질 구조를 가지며 상온에서 안정한 구조를 유지하였다. 원통형 다중껍질 나노기둥 및 나노와이어 확장 변형에 따른 장력의 변화에 관한 연구에서 오각형 NLC(needle-like crystal) 구조가 관찰되었다. 오각형 NLC 나노와이어 구조의 특성은 기본구성단위가 면심입방격자 구조이므로 안정된 구조라는 것을 연구하였다.

• Bulletin of the Korean Chemical Society
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• 제14권1호
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• pp.63-71
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• 1993

By use of cluster orbitals, analytic solutions of finite face-centered cubic clusters are obtained. Taking interactions between up to the second nearest neighbors into account, the forms of all the elements of the Hamiltonian matrix are found explicitly within Huckel approximation. By adopting $D_{2k}$ point group to the cluster, the matrix is simplified. We assume that the cluster orbitals can mix together only when their state indices are indentical. It is then possible to calculate various physical properties of face-centered cubic metal clusters and example are shown for palladium clusters. The results show that density of states and projected density of states are similar, qualitatively, with those obtained by extended Huckel calculation.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2009년도 제38회 동계학술대회 초록집
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• pp.403-403
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• 2010

The Pt-Ni alloy is an electro-catalyst of interest in the low temperature direct methanol fuel cells(DMFCs). It has been already reported that the Pt-Ni alloy catalysts may even have enhanced activity compared to pure platinum catalyst, depending on how the surfaces are prepared. The order-disorder transition in bimetallic alloy such as $\beta$-CuZn, Cu3Au, and CuAu have been investigated greatly by x-ray diffraction. After annealing the bimetallic alloy, the crystal structure changes as observed in the order-disorder transition of Cu3Au which changes from the face centered cubic to a simple cubic structure. Pt-Ni bimetallic alloy has been already reported to have the face centered cubic structure. However, in nano-scale Pt-Ni bimetallic alloy crystals the crystal structures changes to a simple cubic structure. In this experiment, we have studied the order-disorder transition in Pt-Ni bimetallic nanocrystals. Pt/Ni thin films were deposited on sapphire(0001) substrates by e-beam evaporator and then Pt-Ni alloy were formed by RTA at 500, 600, and $700^{\circ}C$ in a vacuum environment and Pt-Ni nano particles were formed by RTA at $1059^{\circ}C$ in a vacuum environment. We measured the structure of Pt-Ni bimetallic alloy films using synchrotron x-ray diffraction and SEM.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 춘계학술대회논문집A
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• pp.148-152
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• 2000

The aluminum alloy 6061-T6 has been successfully used in structural applications especially the pressure vessel of the Advanced Neutron Source research reactor. And aluminum alloys, including 6061-T6, have a face-centered-cubic crystals structure. Under normal circumstances face-centered-cubic crystal structures do not exhibit cleavage fractures even at very lo9w temperatures. In aluminum-based structures, plates frequently find use as connecting links. Mechanical fasteners are often utilized in instances where ease of application, familiarity with fabrication processes, and severe dynamic loading are of concern. Plates frequently find use as connecting elements in structures built from aluminum alloys. Many structural elements employ mechanical fasteners. Twenty and twenty aluminum alloy 6061-T6 plates, representing four different bolt patterns, were mechanically deformed. And variable materials such as A1 6061-T6, Al 2024-T3, Carbon/Epoxy, Glass/Epoxy Composite and Woven fiber composite, are used as patch materials. From this experiment, it has been shown that the strength of patch-repaired specimens is different with the patch materials.

• 한국재료학회지
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• 제10권12호
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• pp.831-837
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• 2000

고분자전해질형 연료전지에서 촉매의 활성을 증가시키기 위하여 기존에 사용되고 있는 백금과 전이금속인 chromium, nickel과의 합금을 제조하였다. XRD를 이용하여 합금의 구조가 $33^{\circ}$에서 superlattice line을 가지고 있는 것으로 보아 face centered cubic 구조를 가진 ordered alloy로 이루어졌다는 것을 알 수 있었다. 열처리 온도가 증가할수록 합금의 입자 크기는 증가하였으며, 결정 격자 상수는 감소하였다. 전지성능테스트, cyclic voltammogram 등을 통하여 mass activity, specific activity, Tafel slope, 개회로 전압을 측정한 결과, 합금촉매의 활성이 순수한 백금촉매보다 크게 향상되었음을 알 수 있었다.