• Electrical & Electronic Materials
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• v.10 no.3
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• pp.284-288
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• 1997

FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.

• Bulletin of the Korean Chemical Society
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• v.18 no.6
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• pp.588-594
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• 1997

Gelation time, gel structure and volatility of by-products during gelation of PZT sol-gel processing were investigated by FT-IR spectroscopy. FT-IR spectroscopic study was performed on PZT gels with the various H₂O contents (1, 2 and 3 mol) and the several types (HNO₃, NH₄OH) and amounts (0.1, 0.2 mol) of catalysts, monitoring temporal (0, 1, 3, 10 weeks, 3 months and 3 years) and thermal (100-700 ℃) changes of FT-IR spectra. The interpretation of temporal change of the spectra revealed two trends. One is under the condition of 1 mol H₂O, 1 mol H₂O+0.1 mol HNO₃, 3 mol H₂O and the other is for 1 mol H₂O+0.1 mol NH₄OH, 2 mol H₂O, 1 mol H₂O+0.2 mol HNO₃. The gel structures and the gelation times for these conditions were discussed in comparison with the reported results of SiO₂, and we suggested the reaction mechanisms for these structural characteristics. Thermal variation of FT-IR spectra was interpreted as the evolution processes of gel by investigating the evaporation of solvent and the decomposition of organic residues.

• Proceedings of the KSR Conference
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• 2008.06a
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• pp.2213-2217
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• 2008

The important factor is keeping the temperature condition in quantifying several toxic components in combustion gases. In case of not keeping the temperature as it was in combustion, the change of component and concentration of smoke gases was inevitable. To solve this problem, FT-IR spectroscopy with gas cell was applied. But, there is also a difficulty in quantitative analysis of specific toxic component because of water vapor. Thus, in this study, water vapor FT-IR spectra with different concentrations were obtained and applied them to quantitative analysis.

• Proceedings of the Materials Research Society of Korea Conference
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• 1992.05a
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• pp.68-69
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• 1992

• Journal of Korean Ophthalmic Optics Society
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• v.8 no.1
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• pp.17-22
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• 2003

The experimental FT-IR spectra and DTA curves of the $PbO-Bi_2O_3-B_2O_3-SiO_2$ glasses have been investigated. The composition ratio dependence of glass transition temperature showed that the structure of this glass system changes at 60 mol% $Bi_2O_3$. We have observed that the FT-IR spectra of the investigated samples with high bismuth content are dominated by bands associated to the structural units of the heaviest cation, $Bi^{3+}$ and the boron atoms in the treated samples are three and four coordinated even for very high $Bi_2O_3$ content. The low intensity of these non-bridging oxygen bands, for high PbO content glasses, can be attributed to the strong network-forming roles of PbO. The glasses absorption bands exhibited a greater change in intensities on crystallization.

• Atmosphere
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• v.25 no.4
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• pp.601-610
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• 2015

This study measured the emissivity spectra of 5 major rock-forming minerals using a Fourier Transform Infrared (FT-IR) spectrometer in the spectral region of $650{\sim}1400cm^{-1}$. The mineral samples are quartz, albite, bytownite, anorthite, and sandstone. We compared emissivity spectra measured in this study with spectra provided by Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) and Arizona State University (ASU). The spectral features of emissivity such as Reststrahlen Band (RB) and Christiansen Feature (CF) locations were compared. Results showed that both CF and RB locations of emissivity spectra measured in this study were similar to those from ASTER and ASU. In the case of quartz, the RB was occurred in the region of $700{\sim}850cm^{-1}$ and $1050{\sim}1250cm^{-1}$. The spectral position of emissivity peak was in good agreement with the location of ASTER and ASU. For plagioclase (albite, bytownite, and anorthite), the spectral location of CF was shifted toward larger wavenumber and the emissivity value was increased in the region of $870{\sim}1200cm^{-1}$ with Ca percentage. The CF of anorthite and bytownite was occurred at $1245.79cm^{-1}$, and that of albite was occurred at $1283.79cm^{-1}$. We also confirmed that emissivity feature of sandstone includes both emissivity features of quartz and calcite. However, there were some differences in the magnitude of emissivity and locations of RB and CF. These were due to the differences in measurement methods, and differences in particle size and temperature of samples.

• Analytical Science and Technology
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• v.5 no.4
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• pp.455-464
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• 1992

Using FT-IR, we determined the depth of silylated layers produced from various gas-phase-silylation conditions was proposed by using Fourier Transform Infrared (FT-IR) spectroscopic analysis. The depth of silylated layer was determined from absorbance measurments of the significant peaks (Si-O-ph, Si-C, Si-H) of FT-IR spectra with background spectrum subtraction method. And the results were compared with thickness measurments of SEM. The results were well agree with SEM. It found to be well suited for determining silylation process window.

• Bulletin of the Korean Chemical Society
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• v.23 no.12
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• pp.1729-1732
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• 2002

The LB71350,(3S, 4R)-Epoxy-(5S)-[[N-(1-methylethoxy)carbonyl]-3-(methylsulfonyl)-L-valinyl]amino]-N-[2-methyl-(1R)-[(phenyl)carbonylpropyl-6-phenylhexanamide, is a novel HIV protease inhibitor. Its equilibrium solubility at room temperature was less than $40{\mu}g/mL.$ It was speculated that the low aqueous solubility might be due to the high crystalline lattice energy resulting from intermolecular hydrogen bonds. The present study was carried out to learn the solid-state characteristics of LB71350 using analytical methods such as NMR, FT-IR and XRD. $^{13}C$ Solid-state NMR, solution NMR, and FT-IR spectra of the various solid forms of LB71350 were used to identify the conformation and structure of the solid forms. The chemical shifts of $^{13}C$ solid-state NMR spectra suggest that the crystalline form might have 3 intermolecular hydrogen bondings between monomers.

• Journal of Industrial Technology
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• v.27 no.B
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• pp.109-114
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• 2007

Humic substances generally comprise 30-50% of the dissolved organic carbon in water. They can affect water quality adversely in several ways and they are important from a water treatment perspective due to their role as precursors for the formation of chlorination by-products such as trihalomethanes. The objectives of this research are to investigate the characteristics of organic matter using raw water of Chuncheon area, to isolate the humic substance fractions from natural water samples, and characterize the extracted humic substances. Humic substances were fractionated according to "isolation of IHSS aquatic humic and fulvic acids" using XAD resin adsorption technique. Characteristics of humic substances were analyzed through DOC, $UV_{254}$, $SUVA_{254}$, FT-IR spectra, fluorescence analysis.

• Journal of the Optical Society of Korea
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• v.9 no.4
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• pp.151-156
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• 2005

A spatial-domain Fourier Transform (FT) infrared (IR) spectrometer coupled with a PtSi Schottky­barrier IR detector plane was developed in the spectral range of $2.0-2.5{\mu}m$ for noninvasive measurement of analyte concentrations in cell culture media during cell culture processing. A key optical component of the spectrometer is a Savart plate which is a birefringent polarizer generating coherent two rays for interfering. The spectral resolution of the spectrometer was determined as $71cm^{-1}$ (${\~}0.05{\mu}m$ at $2.5{\mu}m$). Clear IR fringe patterns were imaged on the IR detector plane. The feasibility of the spectrometer for our application was investigated by measuring absorbance spectra of glucose and fetal bovine serum (FBS) which are important compounds in cell culture media. Experiment results show that the spectral quality of glucose and FBS was comparable with the standard spectra acquired with a commercial FT-IR spectrometer, presenting the feasibility of the spectrometer to perform analyte measurement in cell culture media.