• Title/Summary/Keyword: FT-IR analysis

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The quantitative analysis of combustive gases on fire by remote passive open path FT-IR spectrometer (Passive open-path FT-IR spectrometer를 사용한 원거리 화재 연소 가스 정량 분석)

  • Cho, Nam Wook;Cho, Won Bo;Kim, Hyo Jin
    • Analytical Science and Technology
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    • v.26 no.2
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    • pp.120-124
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    • 2013
  • It was studied to analyze the $CO_2$, CO, $SO_2$ standard gases of combustion gases by the open path FT-IR spectrometer with passive mode for remote analysis of air pollutant and volcano gases without IR lamp. As result, it was confirmed to have good linearity with more than 0.9 as correlation coefficients on the calibration curve of $CO_2$, CO concentration by MLR method. But in the case of $SO_2$, because the correlation coefficients were 0.88, the linearity could be lower. Finally, the concentration of three gases was predicted on in-site fire experiment under the condition of quantitative analysis. It could measure high $CO_2$ concentration as predicted result, but didn't measure the CO and $SO_2$. According to the result, it was possible to measure the combustion gases to long distance by only open path FT-IR spectrometer without infrared lamp.

Role of FT-IR in Assessing Lubricant Degradation - A Study on Palm Oil Methyl Ester Blended Lubricant

  • Maleque, M.A.;Masjuki, H.H.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.351-352
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    • 2002
  • In this paper, studies were made on the palm oil methyl ester (POME) added lubricants using FT-IR for monitoring oil degradation. In order to assess the degradation characteristics of POME added lubricant by FT-IR, static oxidation test was conducted using three different blended lubricants (viz, zero percent POME, five percent POME and ten percent POME with mineral-based oil) for 280 hrs. The oxidation temperature was set at $140^{\circ}C$. FT-IR quantitative data indicate an increased in oxidation products which was formed from 10% POME added lubricants after 280 hrs of oxidation test. The 5% POME added lubricant and mineral-based lubricant (without POME) showed less oxidation product after the test. From the FT-IR spectrum analysis of the oxidized oils it could be concluded that 5% POME can improve the performance of mineral-based oil by forming protective films.

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Curing Reaction of Urea-formaldehyde Resin Using Real Time FT-IR Spectroscopy (실시간 FT-IR 분광분석법을 이용한 우레아-포름알데히드 수지의 경화반응)

  • Lee, Young-Kyu;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.13 no.2
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    • pp.85-88
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    • 2012
  • In this paper, the curing reaction of UF resins was investigated by a real time FT-IR method. The curing temperature range of the UF resin was $25{\sim}200^{\circ}C$. It was found that the reactions of UF resin at different temperatures resultedin resins with different cross-linked structures. A real time FT-IR spectroscopy can be considered as a good routine analytical tool for following the progress of UF resin curing.

Rapid discrimination system of Chinese cabbage (Brassica rapa) at metabolic level using Fourier transform infrared spectroscopy (FT-IR) based on multivariate analysis (배추 대사체 추출물의 FT-IR 스펙트럼 및 다변량 통계분석을 통한 계통 신속 식별 체계)

  • Ahn, Myung Suk;Lim, Chan Ju;Song, Seung Yeob;Min, Sung Ran;Lee, In Ho;Nou, Ill-Sup;Kim, Suk Weon
    • Journal of Plant Biotechnology
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    • v.43 no.3
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    • pp.383-390
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    • 2016
  • To determine whether FT-IR spectral analysis based on multivariate analysis could be used to discriminate Chinese cabbage breeding line at metabolic level, whole cell extracts of nine different breeding lines (three paternal, three maternal and three $F_1$ lines) were subjected to Fourier transform infrared spectroscopy (FT-IR). FT-IR spectral data of Chinese cabbage plants were analyzed by principal component analysis (PCA), partial least square discriminant analysis (PLS-DA), and hierarchical clustering analysis (HCA). The hierarchical dendrograms based on PLS-DA from two of three cross combinations showed that paternal, maternal, and their progeny $F_1$ lines samples were perfectly separated into three branches in breeding line dependent manner. However, a cross combination failed to fully discriminate them into three branches. Thus, hierarchical dendrograms based on PLS-DA of FT-IR spectral data of Chinese cabbage breeding lines could be used to represent the most probable chemotaxonomical relationship among maternal, paternal, and $F_1$ plants. Furthermore, these metabolic discrimination systems could be applied for rapid selection and classification of useful Chinese cabbage cultivars.

Establishment of rapid discrimination system of leguminous plants at metabolic level using FT-IR spectroscopy with multivariate analysis (FT-IR 스펙트럼 기반 다변량통계분석기법에 의한 두과작물의 대사체 수준 식별체계 확립)

  • Song, Seung-Yeob;Ha, Tae-Joung;Jang, Ki-Chang;Kim, In-Jung;Kim, Suk-Weon
    • Journal of Plant Biotechnology
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    • v.39 no.3
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    • pp.121-126
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    • 2012
  • To determine whether FT-IR spectroscopy combined with multivariate analysis for whole cell extracts can be used to discriminate major leguminous plant at metabolic level, seed extracts of six leguminous plants were subjected to Fourier transform infrared spectroscopy (FT-IR). FT-IR spectral data from seed extracts were analyzed by principal component analysis (PCA), partial least square discriminant analysis (PLS-DA) and hierarchical clustering analysis (HCA). The PCA could not fully discriminate six leguminous plants, however PLS-DA could successfully discriminate six leguminous plants. The hierarchical dendrogram based on PLS-DA separated the six leguminous plants into four branches. The first branch was consisted of all three Vigna species including Vigna radiata var. radiate, Vigna angularis var. angularis and Vigna unguiculata subsp. Unguiculata. Whereas Pisum sativum var. sativum, Glycine max L and Phaseolus vulgaris var. vulgaris were clustered into a separate branch respectively. The overall results showed that metabolic discrimination system were in accordance with known phylogenic taxonomy. Thus we suggested that the hierarchical dendrogram based on PLS-DA of FT-IR spectral data from seed extracts represented the most probable chemotaxonomical relationship between six leguminous plants.

Analysis of Multi-layered Thin Film Using ATR FT-IR and pyro-GC/MS (ATR FT-IR과 pyro-GC/MS를 이용한 다층박막필름의 분석)

  • Park, Sung Il;Lee, Jung-Hyun;Lee, Myung Cheon
    • Journal of Adhesion and Interface
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    • v.20 no.3
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    • pp.102-109
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    • 2019
  • The material constitution of multi-layered thin film coated on the PET base film was analyzed using ATR FT-IR and pyro GC/MS combination. The cross section of the film was acquired by cracking the film after dipping in liquid nitrogen and was observed using optical microscope. Total thickness of the coated film was $70{\mu}m$ and three layers were observed. Since each layers were too thin to analyze directly except the surface layer, analyzable area of each layers were exposed by using a proper solvent and were investigated using ATR FT-IR and pyro GC/MS. Results shows that three layers were commonly consisted of urethane-acrylate copolymers. Also, inorganic and/or metal inclusions detected by XPS and SEM-EDAX were exhibited by nano size $SiO_2$ particles in layer(1) and aluminum flakes in layer(2).

Surface Discharge Characteristics of Phenolic Resin Treated by Heat and Its Structure Analysis (열처리된 페놀수지 표면에서의 방전 특성과 구조분석)

  • Shong, Kil-Mok;Roh, Young-Su;Kwak, Hee-Ro
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.8
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    • pp.71-79
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    • 2006
  • For clearing the cause of firing due to the tacking on the surface of phenolic resin, this paper describes the analysis through a couple of methods ; FT-IR; DTA; photograph analysis, etc. Phenolic resin has been widely employed as a case of low voltage appliances. In the experiment it was confirmed that its surface was carbonized and graphitized by the external fire. In the FT-IR test a graphite specimen thermally treated at $150[^{\circ}C]$ showed the 2 different IR absorption peaks at $1,730[cm^{-1}]\;and\;1,680[cm^{-1}]$. In normal phenolic resin, the exothermic peak appeared at $450[^{\circ}C]$, while in graphite specimen, it appeared at $610[^{\circ}C]$ in DTA test. From the results, the electrical fire causes could be cleared and it is expected to protect the human life and property from the electrical fire by using the important data.

Study on the application of different water vapor spectra to quantify smoke gases with FT-IR (FT-IR을 이용한 연소가스 정량화에서 농도별 수분스펙트라 확보 및 적용연구)

  • Lee, Cheul-Kyu;Lee, Duck-Hee;Jung, Woo-Sung;Park, Ji-Young;Jung, Jong-Hak
    • Proceedings of the KSR Conference
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    • 2008.06a
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    • pp.2213-2217
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    • 2008
  • The important factor is keeping the temperature condition in quantifying several toxic components in combustion gases. In case of not keeping the temperature as it was in combustion, the change of component and concentration of smoke gases was inevitable. To solve this problem, FT-IR spectroscopy with gas cell was applied. But, there is also a difficulty in quantitative analysis of specific toxic component because of water vapor. Thus, in this study, water vapor FT-IR spectra with different concentrations were obtained and applied them to quantitative analysis.

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FT-IR analysis of flame resistant chemical mixture

  • Kim, Younsu;Seo, Jihyung;Choe, Yoong Kee;Sohn, Youngku;Kim, Jeongkwon
    • Analytical Science and Technology
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    • v.34 no.1
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    • pp.17-22
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    • 2021
  • In this study, flame retardant mixtures of decabromodiphenylethane (DBDPE) and Sb2O3 were analyzed using Fourier transform infrared (FT-IR) spectroscopy. The experimentally obtained wavenumbers of DBDPE and Sb2O3 were 1321 and 949 cm-1, respectively, whereas those obtained by theoretical calculation were 1370 and 818 cm-1, respectively. Strong correlation was observed between the mixing molar ratios and observed peak area ratios, suggesting that FT-IR analysis can be used to obtain relative amounts of the individual components of flame retardant mixture.