• Bulletin of the Korean Chemical Society
• /
• v.27 no.6
• /
• pp.853-856
• /
• 2006

Dion-Jacobson phases $CsCa_2Nb_2FeO_9$ and $CsCa_2Nb_2AlO_9$ were reinvestigated by the Rietveld analysis of powder X-ray diffraction (XRD) method, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). These nominal compounds, previously known as the oxygen-deficient layered perovskites with the sequences of $NbO_6-MO_4-NbO_6$ in tripled slab, in fact, were mixed phases of n = 3 Dion-Jacobson phases and impurities such as $Ca_2NbFeO_6$ and $Ca_3Al_2O_6$. The difference of morphology and chemical in-homogeneity between Dion-Jacobson phases and impurities could be clearly identified by scanning electron microscopy with energy-dispersive X-ray spectroscopy. The chemical composition of $CsCa_2Nb_2FeO_9$ was calculated into $Cs_{0.59}Ca_{2.64}Nb_{2.92}Fe_{0.81}$ in small agglomerate crystals and $Cs_{0.95}Ca_{1.97}Nb_{3.08}Fe_{0.15}$ in long plate-like crystals.

• Applied Chemistry for Engineering
• /
• v.4 no.4
• /
• pp.692-700
• /
• 1993

Corrosivities and catalytic activities of platinum-transition metal alloy catalyses loaded on carbon substrate and were studied by electrochemical method using a unit cell. And the analysis of Pt-alloy catalyst was conducted by x-ray diffractometer. Among the catalysts, the Pt-Mo/carbon, Pt-Fe-Co/carbon and Pt-Fe/carbon catalyst showed more excellent cathodic current densities than others. It was found that most of cathodic current density for the Pt-Mo/carbon electrode was $120mA/cm^2$. The current density of the Pt-Fe-Co/carbon was much higher than that of Pt/carbon, reaching $200mA/cm^2$.

• Journal of the Korean Magnetics Society
• /
• v.8 no.3
• /
• pp.125-130
• /
• 1998

13Cr-1.5Nb-Fe alloy powder was fabricated by water atomization method, and ring-shape specimen of this composition was fabricated by oil press, and then sintered in the vacuum furnace. Powder shape, size distribution, composition (C, N, O, S) analysis and saturation magnetization of as-prepared 13Cr-1.5Nb-Fe alloy powder were investigated. Ac permeability and power loss was measured after forming and sintering process. Saturation magnetization and contents of oxygen of the alloy powder is160 emu/g and about 6000 ppm, respectively. 50 % volume fraction indicate particle size of 70$\mu$m. The ac permeability of sintered specimen increases with increasing sintering temperature and forming pressure. The power loss is 107 W/cc at sintering temperature of 1200 $^{\circ}C$, 12 ton/$\textrm{cm}^2$ forming pressure, and 20 KHz. It is the lowest among the prepared specimen.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
• /
• v.5 no.1
• /
• pp.19-27
• /
• 2007

Combined method of extraction chromatography and liquid scintillation analysis was established for determinating $^{55}Fe\;and\;^{63}Ni$ radioactivity in solid samples. Activated concrete wastes generated from dismantling KRR-2 were analysed. The sequential separation including precipitation and extraction chromatography resulted in the above 90% chemical recoveries of Fe. Above 62% recoveries of Ni were obtained by this procedure exception to 43.6 and 46.5% recoveries. The seperation and counting procedure was also confirmed with spiked samples of known quantity. The measured and spiked quantity were agreed with the 3.7% and 0.7% variations in the $^{55}Fe\;and\;^{63}Ni$ experiments, respectively. The radioactivities of $^{55}Fe$ in the dismantled concretes are shown from below MDA to maximum 362 Bq/g. The radioactivities of $^{63}Ni$ in all concrete samples are below MDA. The $^{63}Ni$ doesn't exist in dismantled concretes from KRR-2. The radioactivity of $^{55}Fe$ is decreased rapidly as the sampling depth is increased from the concrete surface.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2007.05a
• /
• pp.891-896
• /
• 2007

Noise radiated from the powertrain is an important factor of the vehicle interior noise. In this paper, Finite Element(FE) model and Boundary Element(BE) models were created. The FE model was updated by doing a correlation between experimental modal analysis(EMA) values and finite element analysis(FEA) values. Main bearing forces were calculated using a running modal data. The forced vibration analysis was simulated using the software MSC/NASTRAN, and the radiated noise was predicted using the software LMS/VIRTUAL.LAB.

• Nuclear Engineering and Technology
• /
• v.54 no.2
• /
• pp.732-740
• /
• 2022

A piping system stress analysis need to be re-performed for structural integrity assessment after reinforcement of a pipe with significant wall thinning. For efficient stress analysis, a one-dimensional beam element for the wall-thinned pipe with reinforcement needs to be developed. To develop the beam element, this work presents analytical equations for elastic stiffness of the wall-thinned pipe with reinforcement are analytically derived for axial tension, bending and torsion. Comparison with finite element (FE) analysis results using detailed three-dimensional solid models for wall-thinned pipe with reinforcement shows good agreement. Implementation of the proposed solutions into commercial FE programs is explained.

• Analytical Science and Technology
• /
• v.17 no.4
• /
• pp.308-314
• /
• 2004

When the polymer was used for the guard raw materials of electronic device, the content of U, Th and their daughter nuclides were known as a factor of soft error. Because emitted alpha ray could be caused of mis-operation. And ionic impurities such as Cl, Fe, Na could shorten the device life-time. For the analysis of trace impurities in the polymer, neutron activation analysis(NAA) and ICP/AES have been studied. To improve the accuracy and sensitivity of the trace and ultratrace metallic impurities in the epoxy and phenol polymer, sample pretreatment method and optimum analytical condition of NAA were developed. Using the above method, U, Th and other 23 trace impurity elements were analyzed.

• Journal of the Korean Society for Precision Engineering
• /
• v.25 no.7
• /
• pp.55-63
• /
• 2008

Fine blanking is a process of press shearing which makes it possible to produce the thick sheet metal of the finished surface and the close dimensional accuracy over the whole material thickness in the single blanking operation. In this paper, a plate holder of automotive seat recliner is manufactured by FCF(Flow Control Forming) method using the conventional mechanical press instead of the fine blanking press. Main processes for manufacturing of the plate holder by FCF method are embossing, half blanking and trimming processes. Optimal clearance, stripper force and counter force to increase the dimensional accuracy of the plate holder have been investigated by FE-analysis. As a result of FE-analysis, the clearance for both embossing and half blanking processes was -2%t and the forces of stripper and counter were 25ton and 15ton, respectively. After manufacturing the plate holder by FCF method, the measured dimensional characteristics have been compared with the required specifications as the final product. Although the dimensional accuracy of the plate holder manufactured by FCF method was a little inferior to that by fine blanking process, it was satisfactory in a general sense.

• Journal of the Korean Ceramic Society
• /
• v.49 no.3
• /
• pp.205-215
• /
• 2012

It has been studied the crystal and block structures of the hexagonal ferrites with M, W, Y and Z types prepared by various coprecipitation-oxidation method. The structures have been refined with a Rietveld analysis of the powder X-ray diffraction pattern with high precision ($R_{WP}$ <0.09, $R_I$ <0.03). The density difference between the S-blocks was proportioned to the cobalt contents in hexagonal ferrites, but that between the R or T-blocks was relatively small. Compared with the blocks and cation-oxygen polyhedra in BaM ($BaFe_{12}O_{19}$), those were bulky to the normal direction for the c-axis in $Co_2W$ ($BaCo_2Fe_{16}O_{27}$) and to the parallel direction for the c-axis in $Co_2Y$ ($Ba_2Co_2Fe_{12}O_{22}$) and $Co_2Z$ ($Ba_3Co_2Fe_{24}O_{41}$). The S-blocks of $Co_2W$, $Co_2Y$, and $Co_2Z$ were unstable and distorted. Because the T-block of $Co_2Z$ was unstable, the T-block was decomposed into the Ba-rich phase and $Co_2W$ at high temperatures above $1200^{\circ}C$. A standard powder X-ray diffraction pattern for $Co_2Z$ was proposed as well.

• Journal of the Korean Society for Precision Engineering
• /
• v.30 no.5
• /
• pp.552-558
• /
• 2013

In recent years the interest on flexible display has been increasing as a future display due to its bendable characteristics. An ITO(indium tin oxide) layer, which is part of a flexible display, can be broken easily while bending because it is made of brittle materials. This brittle property can cause the malfunction of flexible display. To analyze fracture characteristics of ITO layer, bending test was conducted commonly. However, it is not possible to know specific phenomena on bended ITO layer by simple bending test only. Accordingly, in this study, the FE(finite element) model is developed similarly to a real flexible display to analyze stress distribution of flexible display under bending condition, especially on ITO layer. To validate FE model, actual bending test was conducted and the test results were compared with the simulation results by measuring reaction forces during bending. By using the developed model, FE analysis about the effect of design parameter (Thickness & Young's Modulus of BL) on ITO Layer was performed. By explained FE analysis above, this research draws a conclusion of reliable design guide of flexible display, especially on ITO layer.